Inorganic complex antimicrobials containing zincium-rare earth as well as preparation method and application thereof
An inorganic composite, antibacterial agent technology, applied in the field of antibacterial materials, can solve the problems of unsatisfactory antibacterial activity, high addition amount, affecting the appearance of materials and products, etc., and achieves low cost, improved antibacterial activity, and good color stability.
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Embodiment 1
[0027] Contains 0.14mol / l zinc nitrate and 3.2×10 in 100ml -2 mol / l cerium nitrate [Ce(NO 3 ) 3 ], add montmorillonite (100mmol / 100g cation exchange capacity) 10.0g, stir and react at 80°C for 5 hours, then filter, wash, and dry in sequence, then roast at 500°C for 3 hours, and finally supercharge Finely crushed to a white powder with an average particle size of less than 5 microns to obtain an inorganic composite antibacterial agent with a zinc loading of 8.0 wt % and a cerium loading of 4.0 wt %. The test results are shown in Table 1.
Embodiment 2
[0029] Contains 0.10mol / l zinc acetate and 1.6×10 in 100ml -2 mol / l cerium acetate [Ce(AC) 3 ], add montmorillonite (100mmol / 100g cation exchange capacity) 10.0g, stir and react at 60°C for 7 hours, then filter, wash, and dry in sequence, then roast at 600°C for 2 hours, and finally supercharge Finely crushed to a white powder with an average particle size of less than 5 microns to obtain an inorganic composite antibacterial agent with a zinc loading of 6.0 wt % and a cerium loading of 2.0 wt %. The test results are shown in Table 1.
Embodiment 3
[0031] Contains 0.12mol / l zinc nitrate and 2.4×10 in 100ml -2 mol / l cerium nitrate [Ce(NO 3 ) 3 ], add montmorillonite (100mmol / 100g cation exchange capacity) 10.0g, stir and react at 70°C for 6 hours, then filter, wash, and dry in sequence, then roast at 400°C for 4 hours, and finally supercharge Finely crushed to a white powder with an average particle size of less than 5 microns to obtain an inorganic composite antibacterial agent with a zinc loading of 7.1wt% and a cerium loading of 2.8wt%. The test results are shown in Table 1.
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