Single-component self-crosslink emulsion adhesive for dry type composite film and preparation method thereof
A self-crosslinking emulsion, one-component technology, applied in the direction of adhesive types, chemical instruments and methods, ester copolymer adhesives, etc., can solve the problems of poor aging resistance, high-speed coating, and low holding force and other problems, to achieve the effect of excellent aging resistance, broad application market and high stability
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Embodiment 1
[0044] In a 1000ml four-necked bottle equipped with a stirrer, condenser, nitrogen protection and feeding device, add 160g of deionized water, 1.0g of sodium dodecylbenzenesulfonate, and 2.0g of nonylphenol polyoxyethylene (20) ether , and sodium bicarbonate 1.5g, potassium persulfate (KPS) 0.8g and heat up. 75.0 g of methyl methacrylate, 208.5 g of butyl acrylate, 6.0 g of acrylic acid, and 4.5 g of vinyltrimethoxysilane were mixed. Dissolve 9.0g of N-methylolacrylamide, 1.0g of sodium dodecylbenzenesulfonate, and 2.0g of nonylphenol polyoxyethylene (20) ether in 100.0g of deionized water, and slowly add the above monomer mixture A pre-emulsion is formed. First add about 1 / 10 of the pre-emulsion to the reaction bottle, and react at 70°C for 0.5 hours. Then KPS 1.6g was dissolved in 40g deionized water, and the pre-emulsion was added dropwise synchronously for 4.5 hours. Finally, the temperature was raised to 90°C and the reaction was carried out for 1.5 hours. Cool to belo...
Embodiment 2
[0046]In a 1000ml four-necked bottle equipped with a stirrer, condenser, nitrogen protection and feeding device, add 160g of deionized water, 1.0g of sodium dodecylbenzenesulfonate, and 2.0g of nonylphenol polyoxyethylene (20) ether , and sodium bicarbonate 1.5g, potassium persulfate (KPS) 0.8g and heat up. 75.0 g of styrene, 208.5 g of butyl acrylate, 6.0 g of acrylic acid, and 4.5 g of vinyltrimethoxysilane were mixed. Dissolve 9.0g of N-methylolacrylamide, 1.0g of sodium dodecylbenzenesulfonate, and 2.0g of nonylphenol polyoxyethylene (20) ether in 100.0g of deionized water, and slowly add the above monomer mixture A pre-emulsion is formed. First add about 1 / 10 of the pre-emulsion to the four-necked bottle, and react at 70°C for 0.5 hours. Then KPS 1.6g was dissolved in 40g deionized water, and the pre-emulsion was added dropwise synchronously for 4.5 hours. Finally, the temperature was raised to 90°C and the reaction was carried out for 1.5 hours. Cool to below 50°C, ad...
Embodiment 3
[0048] In a 1000ml four-necked bottle equipped with a stirrer, condenser, nitrogen protection and feeding device, add 160g of deionized water, 1.0g of sodium dodecylbenzenesulfonate, and 2.0g of nonylphenol polyoxyethylene (20) ether , and sodium bicarbonate 1.5g, potassium persulfate (KPS) 0.8g and heat up. 75.0 g of styrene, 208.5 g of butyl acrylate, 6.0 g of acrylic acid, and 4.5 g of methacryloxypropyltriisopropoxysilane were mixed. Dissolve 9.0g of N-methylolacrylamide, 1.0g of sodium dodecylbenzenesulfonate, and 2.0g of nonylphenol polyoxyethylene (20) ether in 100.0g of deionized water, and slowly add the above monomer mixture A pre-emulsion is formed. First add about 1 / 10 of the pre-emulsion to the four-necked bottle, react at 70°C for 0.5 hours, then dissolve 1.6g of KPS in 40g of deionized water, and add it dropwise with the pre-emulsion simultaneously for 4.5 hours. Finally, the temperature was raised to 90° C., and the reaction was carried out for 1.5 hours. Co...
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