Image forming apparatus, image forming method and process cartridge
An image and developing device technology, applied in corona discharge device, electric recording process applying charge pattern, electric recording process applying charge pattern, etc., can solve the problem of excessive crushing, poor storage, and poor productivity And other issues
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[0611] Hereinafter, examples of the present invention will be described, but the present invention is not limited in any way by the following examples.
[0612] In the following examples and comparative examples, "softening point of polyester resin", "glass transition temperature (Tg) of polyester resin", "softening point of rosin", "acid value of polyester resin and rosin" "The hydroxyl value of the polyester resin", the "content of the low molecular weight component with a molecular weight of 500 or less", the "SP value of the rosin", and the "modification degree of (meth)acrylic acid of the rosin" were measured by the following methods.
[0613]
[0614] Using a flow tester (manufactured by Shimadzu Corporation, CFT-500D), 1 g of each polyester-based binder resin as a sample is heated at a temperature increase rate of 6°C / min, while a plunger provides a load of 1.96 MPa, It was extruded from a nozzle with a diameter of 1 mm and a length of 1 mm to create a curve of the plunger...
Synthetic example 1
[0644] —The refining of rosin —
[0645] 1,000g of tall oil rosin was put into a 2000mL distillation flask equipped with a fractionating tube, reflux condenser and receiving vessel, and distilled under a reduced pressure of 1kPa, and distilled components at 195°C to 250°C were collected as the main fraction . Hereinafter, the tall oil rosin used for purification is regarded as unrefined rosin, and the rosin collected as the main fraction is regarded as refined rosin.
[0646] Using a coffee pulverizer (National MK-61M), each 20 g of rosin was pulverized for 5 seconds, and 0.5 g of the substance passed through a sieve with an aperture of 1 mm was measured and put into a vial (20 mL) for headspace. Headspace gas was sampled, and the impurities in unrefined rosin and refined rosin were analyzed by the headspace GC-MS method in the following manner. The results are shown in Table 1A.
[0647]
[0648] A. Headspace sampler (manufactured by Agilent, HP7694)
[0649] ·Sample temperature...
Synthetic example 2
[0680] —Synthesis of Acrylic Modified Rosin A—
[0681] 6084g (18mol) of refined rosin (SP value: 76.8°C) and 907.9g (12.6mol) of acrylic acid were added to a 10L flask equipped with a fractionating tube, reflux condenser and receiving vessel, and the temperature was changed from within 8 hours The temperature was raised from 160°C to 220°C and reacted at 220°C for 2 hours, followed by distillation under reduced pressure of 5.3 kPa to obtain acrylic modified rosin A. The SP value of the obtained acrylic modified rosin A was 110.4°C, and the degree of acrylic acid modification was 100.
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