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New process for separating metal fiber copper protective layer by catalytic ammonia leaching method

A technology for copper protective layer and metal separation, which is applied in the field of separation of metal fiber copper protective layer by catalytic ammonia immersion method, can solve the problems of long electrolysis process, difficult acid mist treatment, and metal fiber quality degradation, and achieve high added value of recovery and easy Effect of recycling and improving reaction speed

Inactive Publication Date: 2008-01-16
常州市裕和金属材料有限公司
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AI Technical Summary

Problems solved by technology

At present, the process methods for treating metal fiber copper protective layer include electrolysis and nitric acid method. The electrolysis method has a large investment and high cost, and the acid mist generated is difficult to handle. The generated nitrogen oxide and other gases are difficult to cure, the treatment cost is high, and the degree of environmental protection is poor
Furthermore, electrolysis and nitric acid can be used to dissolve and recycle the copper protective film, but these two methods have a certain impact on the physical and chemical properties of the metal fiber, resulting in a decline in the quality of the metal fiber
But at present, there is no good process method that can make up for the shortcomings of the electrolysis method and the nitric acid method. Therefore, what process method to use to treat the metal fiber copper protective layer has always been a major problem that plagues the metal fiber manufacturing industry.

Method used

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  • New process for separating metal fiber copper protective layer by catalytic ammonia leaching method

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Embodiment Construction

[0010] The present invention will be described in further detail below by way of examples.

[0011] As shown in Figure 1, the embodiment that implements the new process of separation metal fiber copper protective layer of catalytic ammonia leaching method of the present invention is as follows:

[0012] Use the principle of high-speed water jetting in the system to inhale oxygen in the air, so that the fluid is atomized at the nozzle by high-speed and high-pressure effects, so that the oxygen in the inhaled air can be dissolved at a high speed, and then evenly pass through the screen, and the metal fiber protective layer copper Electrochemical reaction occurs to oxidize it, and then add carbonized ammonia water to make the metal fiber copper protective layer complex in the carbonized ammonia water medium at a high speed to form copper carbonate ammonium complex, and then use its own circulation system to send the solution into the thermal decomposition tank for heating , by he...

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Abstract

A catalysis ammonia leaching process for separating copper protective layer on metal fiber, which contains 1, oxidizing copper protective layer by reacting with oxygen in air through electrochemical reaction, adding carbonized ammonia for high speed complexing copper layer to producing copper carbonate ammonia complex, 2, heating produced copper carbonate ammonia complex to separating hydrous copper oxide or basic copper carbonate and carbonized ammonia gas, 3, cooling carbonized ammonia gas into carbonized ammonia, and circular acting to copper protective layer. Said invention has advantages of low cost, environment protection and high productivity.

Description

technical field [0001] The invention relates to a new process for separating the metal fiber copper protective layer by a catalytic ammonia leaching method. The metal fiber copper involved in the invention is mainly used in the fields of aerospace, chemical industry, electronics, textiles and the like. Background technique [0002] As a high-tech product, metal fiber is widely used in many fields such as aerospace, chemical industry, electronics, textiles, etc. This kind of application is developing into more fields with the advancement of technology. For example, people are currently applying it in the field of clothing as anti-static clothing, in the chemical industry as metal filters, in the industrial field as pipeline equipment, in the military field as body armor, and so on. The metal fiber is composed of nickel-chromium-aluminum and other alloys. In the process of producing metal fiber, it needs to be protected by 60% electrolytic copper before it can be drawn into a ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23F1/00C23F1/18
Inventor 王水平丁四宜
Owner 常州市裕和金属材料有限公司
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