Cleaning compositions comprising alkoxylated polyalkyleneimines and sulfonate group-containing copolymers

a technology of alkyleneimines and copolymers, which is applied in the field of cleaning compositions, can solve the problems of significant reduction in cleaning performance, ineffective surfactant for soil/stain removal, and scum that further soils the fabric surface, and achieves the effect of improving cleaning performance and maintaining whiteness

Inactive Publication Date: 2016-03-31
THE PROCTER & GAMBLE COMPANY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0007]The present invention relates to a cleaning composition, preferably a laundry detergent composition and more preferably a liquid laundry detergent composition, which contains one or more alkoxylated polyalkyleneimines in combination with a sulfonate group-containing copolymer. It is a surprising and unexpected discovery of the present invention that when a sulfonate group-containing copolymer is combined with one or more alkoxylated polyalkyleneimines in a cleaning composition, the resulting cleaning composition exhibits significant improvement in its cleaning performance, more specifically its whiteness maintenance benefit, in comparison with compositions containing either the sulfonate group-containing copolymer alone or the one or more alkoxylated polyalkyleneimines alone.

Problems solved by technology

For example, the wash water used with detergents or cleaning compositions may contain various metal ions (e.g., calcium or magnsium ions) that can chemically combine with surfactants in the wash to form insoluble precipitates, which not only render the surfactant ineffective for soil / stain remval, but also form scums that further soil the fabric surface.
Therefore, water with a higher concentration of metal ions (i.e., hard water) presents a particularly challenging wash condition.
This brings additional challenges because re-used wash water tends to have harder (i.e., high concentrations of metal ions) and increased levels of soil contaminants, and elimination of phosphate and / or zeolite builder and reduction of total surfactant content in the detergent or cleaning compositions may lead to significant reduction in the cleaning performance.

Method used

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  • Cleaning compositions comprising alkoxylated polyalkyleneimines and sulfonate group-containing copolymers
  • Cleaning compositions comprising alkoxylated polyalkyleneimines and sulfonate group-containing copolymers
  • Cleaning compositions comprising alkoxylated polyalkyleneimines and sulfonate group-containing copolymers

Examples

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examples

[0177]Hereinafter, the present invention is described in more detail based on examples. All percentages are by weight unless otherwise specified.

A. Exemplary Alkoxylated Polyalkyleneimines

[0178]Following is a list of exemplary alkoxylated polyalkyleneimines that can be used for practicing the present invention:

TABLE 2MWPEIEO #PO #Formula(Daltons)(b)(c)PEI Polymer 1(PEI)5000(EO)7500070PEI Polymer 2(PEI)5000(EO)9.9 (PO)3.550009.93.5PEI Polymer 3(PEI)5000(EO)9.9 (PO)15.550009.915.5PEI Polymer 4(PEI)600(EO)10 (PO)7600107PEI Polymer 5(PEI)5000(EO)10 (PO)75000107PEI Polymer 6(PEI)600(EO)20600200PEI Polymer 7(PEI)1600(EO)201600200PEI Polymer 8(PEI)600(EO)24 (PO)166002416PEI Polymer 9(PEI)600(EO)24 (PO)246002424PEI Polymer 10(PEI)600(EO)30(PO)5600305

B. Exemplary Sulfonate Group-Containing Copolymers

[0179]Following is a list of exemplary sulfonate group-containing copolymers (“S Copolymers”) that can be used for practicing the present invention:

TABLE 3Proportion of StructuralIPN / Units (% by ...

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Abstract

A cleaning composition containing an alkoxylated polyalkyleneimine and a sulfonate group-containing copolymer is provided, which exhibits significant improved whiteness maintenance benefit when used to treat fabrics.

Description

FIELD OF THE INVENTION[0001]The present invention is in the field of cleaning compositions.BACKGROUND OF THE INVENTION[0002]An important purpose of detergents and / or cleaning compositions is to remove soils and stains from fabrics to achieve consumer perceivable cleaning benefit. The ability of a particular detergent or cleaning composition to remove soils and stains is determined not only by the surfactant activity level in the composition, but also by many others factors.[0003]For example, the wash water used with detergents or cleaning compositions may contain various metal ions (e.g., calcium or magnsium ions) that can chemically combine with surfactants in the wash to form insoluble precipitates, which not only render the surfactant ineffective for soil / stain remval, but also form scums that further soil the fabric surface. Therefore, water with a higher concentration of metal ions (i.e., hard water) presents a particularly challenging wash condition. This challenge is further ...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C11D3/00C11D3/37C11D17/04
CPCC11D3/0036C11D17/043C11D3/3723C11D3/378
Inventor WANG, XIAOLIZHAI, XIANLINGQIN, PENGLIU, XIAOYANSMERZNAK, MARK, ALLENSTENGER, PATRICK, CHRISTOPHERLUI, BONNY, KAYDEPA, PRAVEEN, KUMARSHEAROUSE, WILLIAM, COFFINVOSTERS, STACEY, LEEHILER, RACHEL, MARIEHEMMI, AKIKOMIZOGUCHI, HIROTAKAMATSUMOTO, RIKA
Owner THE PROCTER & GAMBLE COMPANY
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