Electro-optical security element
a technology of optical security element and optical shielding, applied in the field of optical shielding element, can solve the problems of low luminescence obtained under given excitation conditions, high cost of production of core/shell structure, etc., and achieve the effects of increasing the diversity of selection, increasing the security against counterfeiting, and low cos
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example 1
Preparation of Usable Polycarbonate Derivatives
example 1.1
Preparation of a First Polycarbonate Derivative
[0092]183.3 g (0.80 mol) of bisphenol A (2,2-bis-(4-hydroxyphenyl) propane, 61.1 g (0.20 mol) of 1,1-bis-(4-hydroxyphenyl)-3,3,5-trimethyl cyclohexane, 336.6 g (6 moles of KOH and 2,700 g of water were dissolved in an inert atmosphere with stirring). Then a solution of 1.88 g of phenol in 2,500 ml of methylene chloride was added. Into the well-stirred solution, 198 g (2 mol) phosgene were introduced at pH 13 to 14 and 21 to 25° C. Then 1 ml of ethyl piperidine was added and stirred for another 45 min. The bisphenolate-free aqueous phase was separated, and the organic phase was washed, after acidification with phosphoric acid, with water until neutral and freed from solvent.
[0093]The polycarbonate derivative exhibited a relative solution viscosity of 1.255.
example 1.2
Preparation of a Second Polycarbonate Derivative
[0094]Analogously to Example 1.1, a mixture of 127.1 g (0.56 mol) of bisphenol A and 137.7 g (0.44 mol) of 1,1-bis-(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane was reacted to polycarbonate.
[0095]The polycarbonate derivative exhibited a relative solution viscosity of 1.263.
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