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Dark neutral gray glass composition with low transmittance, and glass formed therefrom

a technology of neutral gray and low transmittance, which is applied in the direction of windows, transportation and packaging, vehicle components, etc., can solve the problems of low visibility in motor vehicles, inability to provide privacy function, and heat conductivity drop, and achieve low color purity, effective function, and excellent absorption of visible light

Active Publication Date: 2014-09-04
KCC GLASS CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The present invention is a dark, neutral gray-colored, low-transmittance glass composition that has excellent absorption of visible light, solar energy, and UV rays. This glass can be used for privacy protection, cooling load reduction, and UV blocking in cars, buildings, and interiors. The glass has low color purity, suggesting a relative ratio of colorant ingredients and limiting the use of excessive colorant ingredients. The composition of the glass can harmonize with various car, building, and interior colors, optimizing their aesthetic appearance. The patent text explains the composition of the glass in detail.

Problems solved by technology

As compared with general soda-lime glass, colored glass can lower the visibility in motor vehicles because of its low visible light transmittance (LTA) and can reduce heat absorption into motor vehicles because of its low solar energy transmittance (Te).
However, this composition has a visible light transmittance (LTA) of about 25 to 30% as measured for a reference thickness of 4mm and thus is not suitable for providing the function of privacy protection which is an important function of gray glass applied for sunroof or rear privacy glass.
However, since the above composition has a high content of total Fe2O3, Fe2+ is inevitably generated and this causes problems such as heat conductivity decrease, fuel cost increase, temperature decrease in the bottom of a melting furnace, melting quality degradation, etc.
In addition, Cr used in this composition is known as a poorly soluble material and as its amount increases, non-molten materials are generated and non-uniform color is caused thereby.
Accordingly, if this element is used, there is a difficulty in production of glass with high color uniformity.
Furthermore, the use of excessive Fe2O3, CoO and Se increases color purity, and thus it is not suitable for harmonizing with various colors of buildings and interiors.
However, in case of containing Ni like this, it may exist as NiS during the glass-melting procedure and NiS is known to cause glass breakage by volume expansion after the glass-tempering procedure.
Concretely, dark, neutral gray-colored, low-transmittance glass is mainly used for motor vehicles and since a glass for motor vehicles must be tempered, the use of Ni increases the possibility of glass breakage.
That is, Ni is an element which is required to be limited in its use in glass compositions for motor vehicles.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment Construction

1 TO 9 AND COMPARATIVE EXAMPLES 1 TO 6

[0049]By using as the raw materials, silica, feldspar, limestone, dolomite, soda ash, sodium sulfate, iron oxide, cobalt oxide, selenium, cokes, etc., the base glass (soda-lime glass composition) having the ingredients and amounts described in the following Table 2 and the colorants having the ingredients and amounts described in the following Tables 3 to 5 were prepared. Based on 100 parts by weight of the above base glass, the colorants having the ingredients and amounts described in the following Tables 3 to 5 were added and melted to prepare the sample glasses of the Examples and Comparative Examples.

[0050]The sample glasses for the chemical analysis and optical characteristics evaluation of the glass compositions in the present invention were prepared by using a Pt-10% Rh crucible in a gas furnace and an electric furnace. The raw material batch as weighed on a 500 g basis was melted in a gas furnace at 1450° C. for 1 hour and subjected to r...

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PUM

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Abstract

The present invention relates to a dark neutral gray glass composition with a low transmittance, and a glass formed therefrom, and more specifically, to a dark neutral gray glass composition with a low transmittance and a low color purity, wherein an appropriate amount of Fe2O3, CoO and Se are used as a colorant component, and the FeO content in Fe2O3 and the CoO and Se relative content are delimited by a predetermined range, so as to lower the transmittance of visible rays, solar energy and ultraviolet rays and color purity, thereby protecting privacy in a vehicle, a building and the like, enabling harmony among the various colors thereof, and protecting an interior material and people from ultraviolet rays, and to a glass formed therefrom.

Description

TECHNICAL FIELD[0001]The present invention relates to a dark, neutral gray-colored, low-transmittance glass composition and a glass formed therefrom, and more specifically, a dark, neutral gray-colored, low-transmittance glass composition with low color purity and a glass formed therefrom, wherein Fe2O3, CoO and Se are used as colorant ingredients in appropriate amounts and the FeO content in the Fe2O3 and the relative amount of CoO to Se are restricted within specific ranges, by which the transmittances of visible light, solar energy and ultraviolet rays and color purity can be lowered so as to protect privacy in motor vehicles, buildings, etc., harmonize with the various colors thereof, and protect interior material and people from ultraviolet rays.BACKGROUND ART[0002]Although the use of colored glass is not especially limited, it can be applied for privacy glass or the sun roof of car safety glass and building glass, etc. As compared with general soda-lime glass, colored glass ca...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C03C4/02C03C3/087
CPCC03C3/087C03C4/02C03C4/08C03C4/082C03C4/085B60J1/00C03C3/085
Inventor LEE, YUN HEEKIM, YONG YILIM, JAE CHUNG
Owner KCC GLASS CORP
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