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Austenitic stainless steel

a technology of stainless steel and stainless steel, applied in the field of austenitic stainless steel, can solve the problems of cracking and weld heat affected zones, and achieve the effects of improving high temperature strength, excellent cracking resistance, and high strength

Inactive Publication Date: 2010-02-11
NIPPON STEEL CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The present invention aims to provide an austenitic stainless steel with excellent resistance to cracking in the welded portion after a long period of use at high temperatures. The invention proposes a solution to prevent cracking by restricting the contents of grain boundary-embrittling elements, specifically P, S, Sn, Sb, Pb, Zn and As, within specific ranges. The invention also discusses the microstructure and mechanisms of cracking in the welded portion after a long period of use at high temperatures and proposes measures to prevent such cracking.

Problems solved by technology

While these austenitic stainless heat resistant steels are generally used at high temperatures after welding fabrication, they encounter the problem of an occurrence of cracking in the weld heat affected zone (hereinafter referred to as “HAZ”) after a long period of use at high temperatures.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0139]Austenitic stainless steels A1, A2, B1 and B2 having the chemical compositions shown in Tables 1 and 2 were melted using an electric furnace and cast to form ingots. Each ingot was hot worked by a hot forging and a hot rolling, and then, was subjected to a heat treatment comprising heating at 1200 C., followed by water cooling and, thereafter subjected to machining to produce steel plates having a thickness of 20 mm, a width of 50 mm and a length of 100 mm.

[0140]The steels A1 and A2 shown in Tables 1 and 2 are steels having chemical compositions which fall within the range regulated by the present invention. On the other hand, the steels B1 and B2 are steels of comparative examples in which the values of the parameters P1 and P2 are out of the ranges regulated by the present invention.

TABLE 1Chemical composition (% by mass) The balance: Fe and impuritiesSteelCSiMnCuNiCrMoCosol. AlBNNbVTiSPA10.070.240.802.798.9318.950.310.150.0020.00470.120.5000.0720.0030.00200.031A20.060.381.1...

example 2

[0149]Austenitic stainless steels A3 to A13, B3 and B4 having the chemical compositions shown in Tables 4 and 5 were melted using an electric furnace and cast to form ingots. Each ingot was hot worked by a hot forging and a hot rolling, and then, was subjected to a heat treatment comprising heating at 1200° C., followed by water cooling and, thereafter subjected to machining to produce steel plates having a thickness of 20 mm, a width of 50 mm and a length of 100 mm.

[0150]The steels A3 to A13 shown in Tables 4 and 5 are steels having chemical compositions which fall within the range regulated by the present invention. On the other hand, the steels B3 and B4 are steels of comparative examples in which the value of the parameter P1 is out of the ranges regulated by the present invention.

TABLE 4Chemical composition (% by mass) The balance: Fe and impuritiesSteelCSiMnCuNiCrMoCosol. AlBNNbVTiSPA30.080.230.802.909.3318.54——0.003—0.100.5000.0750.0030.00100.026A40.080.230.742.888.8718.070.2...

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Abstract

An austenitic stainless steel, which comprises by mass %, C: 0.04 to 0.18%, Si≦1.5%, Mn≦2.0%, Ni: 6 to 30%, Cr: 15 to 30%, N: 0.03 to 0.35%, sol. Al≦0.03% and further contains one or more elements selected from Nb≦1.0%, V≦0.5% and Ti≦0.5%, with the balance being Fe and impurities, and among the impurities P≦0.04%, S≦0.03%, Sn≦0.1%, As≦0.01%, Zn≦0.01%, Pb≦0.01% and Sb≦0.01%, and satisfy the conditions P1=S+{(P+Sn) / 2}+{(As+Zn+Pb+Sb) / 5}≦0.06 and 0.2≦P2=Nb+2(V+Ti)≦1.7−10×P1 has high strength and excellent resistance to cracking due to grain boundary embrittlement in the welded portion during the use at high temperatures. Therefore, the said steel can be suitably used as materials for constructing machines and equipment, such as power plant boilers, which are to be used at high temperatures for a long period of time.

Description

TECHNICAL FIELD[0001]The present invention relates to an austenitic stainless steel. More particularly, the present invention relates to a high strength austenitic stainless heat resistant steel which is to be used in constructing high temperature machines and equipment, such as power plant boilers, and is excellent in resistance to cracking at weld heat affected zone due to grain boundary embrittlement during use at high temperatures.BACKGROUND ART[0002]In recent years, the operation conditions for power plant boilers and the like have become higher temperature and higher pressure ones on a worldwide scale in consideration of environmental deterioration. Therefore, these austenitic stainless heat resistant steels which are to be used as materials for superheater tubes and reheater tubes are required to have increased high temperature strength.[0003]In such a technological background, various austenitic stainless steels have been disclosed.[0004]For example, the Patent Document 1 di...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C22C38/60C22C38/42C22C38/44C22C38/46C22C38/48C22C38/50C22C38/54
CPCC22C38/001C22C38/02C22C38/04C22C38/06C22C38/54C22C38/48C22C38/50C22C38/52C22C38/46C22C38/008C22C38/60
Inventor HIRATA, HIROYUKIOGAWA, KAZUHIROOSUKI, TAKAHIROOKADA, HIROKAZUSEMBA, HIROYUKI
Owner NIPPON STEEL CORP
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