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Smoking article and smoking article filter

a filter and smoking article technology, applied in the field of improved filters, can solve the problems of ineffective removal or reduction of gas phase constituents of mainstream smoke, limited commercial acceptance of carbon filters, and unpleasant taste of carbon-filtered cigarettes

Inactive Publication Date: 2009-03-05
ZAWADZKI MICHAEL A +4
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0013]The foregoing and other objectives are achieved according to the invention by providing a filter containing a suitable amount of an adsorbent, preferably activated carbon, and an off-taste suppressant in association with the adsorbent. The adsorbent is capable of trapping and thereby reducing the amount of at least one allegedly undesirable gas phase constituent of mainstream smoke. The off-taste suppressant significantly reduces the characteristic off-taste stemming from the activity of the adsorbent. The composition and amount of off-taste suppressant applied to the adsorbent should be selected to maximize gas phase removal while at the same time minimizing, preferably substantially eliminating, off-taste stemming from adsorbent activity.
[0017]The filters of the present invention are capable of reducing one or more of the allegedly undesirable volatile components of mainstream cigarette smoke including, but not limited to, aldehydes such as formaldehyde, acetaldehyde, acrolein, propionaldehyde and crotonaldehyde.

Problems solved by technology

Most commercially available cigarettes have filters which are designed to reduce particulate matter but are ineffective to remove or reduce gas phase constituents of mainstream smoke.
The commercial acceptance of carbon filters, however, has been limited by the “off-taste” of the mainstream smoke characteristic of such filters.
The smoke from carbon-filtered cigarettes is perceived as having a taste that has been described as unpleasant, astringent, bitter and drying.
However, the presence of flavorants tends to reduce the capacity of the adsorbent to remove the undesirable gas phase constituents.
Flavorants applied as a coating to an adsorbent reduce its gas removal efficiency by decreasing the number of active sites for adsorption.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

examples 1-10

[0066]In Examples 1-7 and 10, the lengths of the filter cavities provided are estimated based on the approximate density of the treated activated carbon samples. In a fully loaded condition there will be approximately 25 mg of treated activated carbon per millimeter of cavity length.

[0067]Cigarettes designated as ventilated in the following Examples contained a circumferential row of perforations somewhere along the length of the filter cavity between its upstream and downstream ends.

example 1

[0068]Activated coconut carbon was treated with various materials as listed in Table 1. For all samples listed in this example, PCB (20×50 mesh) activated coconut carbon supplied by Calgon Carbon Corporation (Pittsburgh, Pa.) was used.

TABLE 1ApplicationApplicationMaterial #TreatmentSource **(% wt / total wt)(mmole / gram carbon)1-1Glucosamine hydrochlorideCat #G220-6; Aldrich20.01.161-2Glucose monohydrateCat #49158; Fluka18.71.161-3Lactose monohydrateCat #61339; Fluka29.51.161-4Maltose monohydrateCat #63419; Fluka29.51.161-5SorbitolCat #S375-5; Aldrich4.11.161-6MannitolCat #M-9647; Sigma17.21.141-7FructoseCat #15760; Riedel-de Haën17.21.151-8InositolCat #I6652; Aldrich17.21.161-9Tapioca DextrinCrystal Tex 627; National Starch20.0—1-10ErythritolCat #E-7500; Sigma12.61.181-11Calorie Free Sweetener *Great Value Brand; WallMart18.7—1-12SucroseCat #84097; Fluka28.21.151-13Chitosan oligosaccharide lactateCat #52,368-2; Aldrich16.9—1-14MaltodextrinLodex-10; Mother Murphy's19.9—1-15Hydroxypropy...

example 2

[0072]The following test was conducted to determine the efficacy of various amino acids as off-taste suppressants for use in the present invention. Activated coconut carbon was treated with various materials as listed in Table 3. For all samples listed in this example, PCB (20×50 mesh) activated coconut carbon supplied by Calgon Carbon Corporation (Pittsburgh, Pa.) was used.

TABLE 3ApplicationApplicationMaterial #TreatmentSource *(% wt / total wt)(mmole / gram carbon)2-1AsparagineCat #A9,300-3; Aldrich8.490.702-2GlutamineCat #G-3126; Sigma9.450.712-3GlycineCat #G620-1; Aldrich4.840.68* Aldrich = Aldrich Chemical Company (Millwaukee, WI); Sigma Chemical Company (Millwaukee, WI).

[0073]The activated carbon was treated according to the following general procedure. Each treatment material listed in Table 3 was dissolved in water. Then the resulting solution was applied to the untreated carbon. Sufficient treatment material was added to the water to yield the final application as listed in Tab...

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PUM

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Abstract

Improved filters useful for tobacco products, such as cigarettes, and novel cigarettes having such filters are disclosed. The filters include adsorbents such as activated carbon which reduce amounts of one or more gas phase constituents of mainstream tobacco smoke. The adsorbents are treated with off-taste suppressants which reduce the off-taste associated with adsorbent containing filters and substantially restore the taste normally associated with tobacco smoke.

Description

[0001]This is a divisional application of U.S. Ser. No. 10 / 442,357 filed May 20, 2003 to which priority under 35 U.S.C. § 120 is claimed.FIELD OF THE INVENTION[0002]The present invention relates generally to improved filters useful for tobacco products, particularly cigarettes, and to novel cigarettes having such filters. More specifically, the invention relates to filters containing adsorbents which reduce one or more allegedly undesirable gas phase constituents normally found in mainstream tobacco cigarette smoke.BACKGROUND OF THE INVENTION[0003]Typically, cigarettes are comprised of a paper-wrapped cylindrical rod of cut tobacco filler, alone or combined with other tobacco or non-tobacco substances, and a filter attached at the mouth or buccal end of the rod. On combustion, the smoke passing through the filter, commonly referred to as “mainstream” smoke, contains particulate matter, e.g. tar, and gas or volatile phase constituents. The gas phase of mainstream cigarette smoke cont...

Claims

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Application Information

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IPC IPC(8): A24D3/04A24D3/06A24D3/12A24D3/14A24D3/16
CPCA24D3/12A24D3/163A24D3/14
Inventor ZAWADZKI, MICHAEL A.RUDD, A. BRENTBARRETT, KENNETH D.JESSUP, TERRY D.DEATON, WILLIAM R.
Owner ZAWADZKI MICHAEL A
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