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Method for forming multilayer release liners and liners formed thereby

a technology of release liners and release liners, which is applied in the field of multi-layer release liners and their methods, can solve the problems of stringent restrictions on solvent recovery, increase the cost of end product adhesive construction, so as to improve the optimization of the coating process

Inactive Publication Date: 2005-05-12
AVERY DENNISON CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The present invention provides a method for creating multilayer release liners that are efficient and cost-effective. This is achieved by simultaneously coating a support layer and a release layer onto a substrate, which eliminates separate coating steps and saves time and money. The method also allows for precise control of the interface between the two layers, resulting in a stable and two-dimensional flow that improves the quality of the finished product. The method uses a dual die coating system that achieves a stable, two-dimensional flow by controlling the interface of the flow at its upstream most position, which is referred to as the separating streamline or separating line. This line is defined as the cross-web line where the topmost streamline of the bottom layer first meets the bottommost streamline of the top layer. The method also includes a curtain coating technique that achieves a stable, two-dimensional flow by allowing for a higher quality window for the full production coating operation. Overall, the method provides an efficient and cost-effective way to create multilayer release liners with improved properties.

Problems solved by technology

However, use of these high quality papers increases the cost of the end product adhesive construction, because such papers are typically much more expensive than regular open papers.
Growing concern over the environment has imposed stringent restrictions regarding recovery of the solvent used in applying the solvent based silicone to the high-holdout backing paper or other materials.
When applied to porous low cost papers, such as machine finished (MF) or machine glazed (MG) papers, these materials soak into the paper (penetrate the paper surface) to give ineffective coverage of the paper fibers unless excessively high quantities of expensive silicone are used.
Ineffective coverage of the paper fibers provides unsuitable release liners for PSA applications, especially where high speed convertibility is an essential performance feature.
However, there are several drawbacks to this prior art process.
First, additional costs are incurred because the prior art methods require two coating steps.
Otherwise, there is a potential for undesirable intermixing or destruction of the respective layers.
Second, because two separate coating steps are required, more time is needed for the overall formation of the release liner.

Method used

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  • Method for forming multilayer release liners and liners formed thereby
  • Method for forming multilayer release liners and liners formed thereby
  • Method for forming multilayer release liners and liners formed thereby

Examples

Experimental program
Comparison scheme
Effect test

examples

[0068] The release properties of the liners of Examples 1-22 were quantified using two methods, the 90° peel release force and the 180° peel release profile. The 90° peel release force was measured on a TLMI Lab Master instrument in the liner off mode, at a rate of 7.62 m / min, and results were measured in cN / 25 mm. The 180° release profile was generated by measuring the peel release force on an Instrumentors ZPE-1000 High Rate Peel Tester at rates of 10, 30, 100, 200, and 300 m / min. in the liner off mode, and results were measured in cN / 25 mm. Protocols for performing the tests are as follows:

90% Peel Release Force

[0069] This test method allows the end user to determine the force required to separate the release backing form the pressure sensitive adhesive coated face material. The release force is defined as the force required to separate a pressure sensitive adhesive coated material from its release surface (or vice versa) at an angle of 90° and a jaw separation rate of 7.62 m p...

examples 1 and 2

[0077] Examples 1 and 2 compare the relative release properties of release surface formed from a coating having 100% silicone solids to a release surface formed from a coating having 40% silicone solids. In each case, the silicone containing layer was coated on a release Support layer (RSL), where the RSL comprised a filler material coated on paper.

[0078] Example 1 consists of a General Electric silicone release layer coated on synthetic SBR as a RSL support layer, which in turn was coated on AT-70 paper. The top layer was prepared by mixing GE 1111-11-259 (62.7g), GE 1192-05-117 (3.3 g), and water (34.0 g). Because no solids other than silicone were coated to form the release layer, the release layer of Example 1 is formed from 100% silicone solids. The bottom RSL layer is 33% solid synthetic SBR filler. The coating was applied to AT-70 paper using a dual die at coating speed of 200 m / min, and cured at 160° C. for 4 seconds to produce the finished liner. The coat weight is 1.5 g / m...

examples 3-6

[0081] Examples 3-6 consist of Wacker silicone as a release layer coated on Air Products Airflex 465 as a RSL, which was coated on either Data-70 or Willamette paper. The top layer was prepared by mixing Wacker 38197 VP (66.0 g). Wacker crosslinker V20 (3.5 g), 10% solution of 3M Fluorad fluorochemical surfactant FC-129 (0.7 g), 1% aqueous Cellosize Hydroxyethyl Cellulose QP-100 MH (7.5 g), and water (22.3 g). The bottom RSL layer was prepared by mixing Air Products Airflex 465 (52.3 g) and water (47.7 g). The coating was applied to Data-70 or Willamette papers using a dual die at a coating speed of 400 nm / min, and cured at 170° C. for 3 seconds to produce the finished liners. The coat weight is 1.0 g / m2 silicone on 5.0 g / m2 RSL. These release liners were coated with S-2000 emulsion pressure-sensitive adhesive or S-2045 hot melt adhesives (Avery Dennison Corporation) to produce the PSA constructions of Examples 3-6.

[0082] The release properties of these liners were quantified using...

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PUM

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Abstract

Disclosed herein is a multilayer silicone release surface comprising a backing, a support layer on the backing, and a silicone layer of the support layer. The various layers of the multilayer release surface are deposited substantially simultaneously, as for example by a dual die or using curtain coating techniques.

Description

CROSS-REFERENCE TO RELATED APPLICATIONS [0001] This application is a divisional of U.S. patent application Ser. No. 09 / 918,652, filed Mar. 22, 2000, which is a continuation-in-part of U.S. patent applicatin Ser. No. 09 / 389,167, filed Sep. 2, 1999, which is a continuation of U.S. patent application Ser. No. 08 / 616,859, filed Mar. 16, 1996, now issued as U.S. Pat. No. 5,962,075, which is a continuation-in-part of U.S. patent application Ser. No. 08 / 483,509, filed Jun. 7, 1995, now issued as U.S. Pat. No. 5,728,430, the entirety of each of which are incorporated by reference as if fully set forth herein.FIELD OF THE INVENTION [0002] The present invention generally relates to release surfaces of the type used with pressure-sensitive adhesive (PSA) constructions. More particularly, the present invention relates to multilayer release liners and their methods of manufacture. BACKGROUND OF THE INVENTION [0003] A pressure-sensitive adhesive construction, such as a label, generally comprises ...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): B05C5/02B05C9/06C09J7/02D21H19/32D21H27/00G03C1/74
CPCB05C5/0254B05C9/06C09J7/0232G03C1/74C09J2483/005D21H19/32D21H27/001C09J2203/334C09J7/403
Inventor SU, WEN-CHENSARTOR, LUIGITSAI, KUOLIHSHIH, FRANK YEN-JERMEYER, DANIELHUFF, STEPHENPOTJER, BERT R.GUO, HONGJIEVAN ZANTEN, AADKETTENIS, ARNOUD H.KRAY, WILLIAMHULME, ADRIANJANSEN, ALEXANDERDORDICK, ROBERT
Owner AVERY DENNISON CORP
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