Dielectric paste for spacer layer of multilayer ceramic electronic component
A dielectric and butyral technology, applied in the field of dielectric paste, can solve problems such as deformation and delamination of laminates, and achieve the effect of preventing defects
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Embodiment 1
[0125] Preparation of Dielectric Paste for Forming Ceramic Green Sheets
[0126] 1.48 parts by weight of (BaCa)SiO 3 , 1.01 parts by weight Y 2 o 3 , 0.72 parts by weight of MgCO 3 , 0.13 parts by weight of MnO and 0.045 parts by weight of V 2 o 5 Mixing is performed, thereby preparing additive powder.
[0127] 159.3 parts by weight of ethyl cellulose and 0.93 parts by weight of a polyethylene glycol system dispersant were added to 100 parts by weight of the prepared additive powder to prepare a slurry, and the additive contained in the slurry was pulverized.
[0128] When the additives contained in the slurry need to be pulverized, 11.2 grams of slurry and 450 grams of ZrO with a diameter of 2 mm 2 The beads were charged into a polyethylene container with an inner volume of 250 cc, and the polyethylene container was rotated at a peripheral speed of 45 m / min for sixteen hours, thereby pulverizing the additive powder to prepare an additive slurry.
[0129] The median par...
Embodiment 2
[0216] Electrode layers and spacer layers were formed on ceramic green sheets in the same manner as in Working Example 1, except that terpinel oxyethanol was used instead of dihydroterpinel oxyethanol as a solvent for preparing a conductive paste for forming electrode layers and Solvent for preparing the dielectric paste used to form the spacer layer. Then, the surfaces of the electrode layer and the spacer layer were observed at four hundred magnifications by using a metallographic microscope. As a result, it was found that the surfaces of the electrode layer and the spacer layer were free from cracks and wrinkles.
[0217] In addition, fifty ceramic green chips were fabricated in the same manner as in Working Example 1. Then, the side of each ceramic green chip that had been subjected to the baking treatment and annealing treatment was polished, and the polished surface of the ceramic green chip was observed using an optical microscope. As a result, voids were not observed...
Embodiment 3
[0220] Electrode layers and spacer layers were formed on ceramic green sheets in the same manner as in Working Example 1, except that d-dihydrocarveol was used instead of dihydroterpineloxyethanol as a solvent for preparing a conductive paste for electrode layer formation and solvents for preparing the dielectric paste used to form the spacer layer. Then, the surfaces of the electrode layer and the spacer layer were observed at four hundred magnifications by using a metallographic microscope. As a result, it was found that the surfaces of the electrode layer and the spacer layer were free from cracks and wrinkles.
[0221] In addition, fifty ceramic green chips were fabricated in the same manner as in Working Example 1. Then, the side of each ceramic green chip that had been subjected to the baking treatment and annealing treatment was polished, and the polished surface of the ceramic green chip was observed using an optical microscope. As a result, voids were not observed i...
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