Method for cleansing and reclaiming waste fluid of alcohol made from molasses
A technology for molasses alcohol waste liquid and residual liquid, applied in the direction of oxidized water/sewage treatment, etc., can solve problems such as hindering waste liquid treatment, purification and reuse, and achieve the effect of reducing treatment costs and thoroughly controlling the environment.
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Embodiment 1
[0015] Molasses alcohol waste liquid (COD concentration 150000mg / L) is separated by centrifuge to obtain dry water-insoluble matter with a weight of 6.8g / L waste liquid, and the remaining liquid is separated by ultrafiltration to separate water-soluble macromolecules, and separated by bipolar membrane electrodialysis , calcium plasma and mixed acid, the COD concentration of the remaining liquid is 100000mg / L, and the remaining liquid is kept at room temperature, pH=9, and oxygen flow rate of 0.14m per liter. 3 Under the condition of / h, after being oxidized by ozone for 30 minutes, it is reused in alcohol production to replace clear water to dilute molasses, and the amount of purified waste liquid to replace dilute clear water is 75%. The recycling process is as follows:
[0016] ① Molasses (70-90°Bx) → clarification tank (add purification waste liquid, nutrient salt) → about 55°Bx sugar solution → supply ②③ as raw material;
Embodiment 2
[0020] Molasses alcohol waste liquid (COD concentration 95000mg / L) is separated by centrifuge to obtain dry water-insoluble matter with a weight of 2.6g / L waste liquid. Potassium hydrogen (see patent application number: 02128100.9), the COD concentration of the purified waste liquid is 65000 mg / L, and the remaining liquid is oxidized by ferromanganese carbon micro-electric field at 80 ° C, pH = 4.5, and air is properly blown in. After hours, it is used back in alcohol production instead of water to dilute molasses. The technical process of reuse is the same as that in Embodiment 1, and the amount of purified waste liquid replacing diluted clear water is 95%.
Embodiment 4
[0022] Molasses alcohol waste liquid (COD concentration 130000mg / L) is separated by centrifuge to obtain dry water insoluble matter with a weight of 4.5g / L waste liquid. Potassium hydrogen, the COD concentration of the remaining liquid is 85000mg / L, and the remaining liquid is at 70°C, pH=3.5, and the oxygen flow rate is 0.08m 3 Under the condition of / h, after 60 minutes of ozone oxidation, it will be used in alcohol production instead of water to dilute molasses. The technical process of reuse is the same as that in Embodiment 1, and the amount of purified waste liquid replacing diluted clear water is 85%.
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