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Process for hjydrogenation refining petroleum wax

A technology for hydrorefining and petroleum wax, which is applied in petroleum wax refining and other directions, can solve the problems of not being able to obtain desulfurization, denitrification and aromatic saturation effects at the same time, and failing to fully and effectively improve the stability of refined products.

Inactive Publication Date: 2003-11-26
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Both of the above two inventions use a single-reactor single-catalyst hydrofining method, and their common disadvantage is that they cannot obtain the best desulfurization and denitrogenation and aromatics saturation effects at the same time, and fail to effectively improve the stability of refined products.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment Construction

[0017] The scheme and effect of the present invention are specifically described below through examples.

[0018] The paraffin wax raw materials used in the examples and comparative examples of the present invention are Daqing crude oil No. 58 deoiled wax and Daqing crude oil No. 66 deoiled wax, and the microcrystalline wax raw material used is Nanyang crude oil No. 80 microcrystalline wax. The properties of raw material wax are shown in Table 1.

[0019] The properties of the Mo-Ni catalysts used in the examples and comparative examples of the present invention are MoO 3 18.9%, NiO4.2%, specific surface area 262m 2 / g, pore volume 0.56ml / g, the nature of the W-Ni catalyst used is WO 3 29.8%, NiO 4.5%, specific surface area 232m 2 / g, pore volume 0.48ml / g.

[0020] In the embodiment of the present invention, two kinds of catalysts are packed in equal volumes.

[0021] In Example 1, Example 2 and Example 3 of the present invention, the temperature of the refined product ...

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PUM

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Abstract

The petroleum wax hydrofining process is one process in single reactor with two kinds of graded and filled catalyst. Under hydrofining condition, the petroleum wax is first contacted with Mo-Ni catalyst, the refined product is then mixed with cold hydrogen and the mixture is finally contacted with W-Ni catalyst to obtain refined product with low S and N content and low fused ring arene content. The product has obviously improved stability. The said petroleum wax material includes paraffin and microcrystalline wax, and petroleum wax product of the present invention may be used in food product,medicine and cosmetics.

Description

1. Technical field [0001] The invention relates to a petroleum wax hydrofinishing method, in particular to a hydrofinishing method using a single reactor and two kinds of catalysts graded packing. Said petroleum wax in the present invention includes paraffin wax and microcrystalline wax. 2. Background technology [0002] Petroleum wax is an important chemical raw material. The petroleum wax separated from petroleum fractions must be refined to remove a small amount of sulfur nitrogen compounds and condensed ring aromatics. The petroleum wax used in food, medicine and cosmetics must be deeply Refined in order to be harmless to the human body. [0003] Petroleum wax hydrofining is a process in which petroleum wax is refined under the action of the catalyst through a fixed bed of a single catalyst in the reactor after mixing petroleum wax and hydrogen at a hydrogen partial pressure of 2 to 16 MPa and a temperature of 230 to 360 °C. . Compared with white clay refining, petrol...

Claims

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Application Information

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IPC IPC(8): C10G73/42
Inventor 王士新袁平飞刘慧青张忠清蔡立全辉赵启明李殿昭
Owner CHINA PETROLEUM & CHEM CORP
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