Benzothiadiazine derivative and application thereof in agriculture

A compound, nitrogen oxide technology, applied in the field of pesticides, can solve the problems of low selectivity, insufficient herbicidal effect, and no weed plants

Pending Publication Date: 2022-03-11
DONGGUAN HEC PESTICIDES R&D CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The active ingredients known from the documents cited above have disadvantages in use such as (a) no or only insufficient herbicidal action on weed plants, (b) excessive spectrum of weed plants to be controlled. Narrow or (c) too low selectivity in useful plant crops

Method used

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  • Benzothiadiazine derivative and application thereof in agriculture
  • Benzothiadiazine derivative and application thereof in agriculture
  • Benzothiadiazine derivative and application thereof in agriculture

Examples

Experimental program
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Embodiment 1

[0168] Example 1: 3-(2,6-dimethylphenyl)-6-(1-ethyl-5-hydroxyl-1H-pyrazole-4-carbonyl)-1-methyl-1H-benzo[ c] Synthesis of [1,2,6]thiadiazin-4(3H)-one 2,2-dioxide

[0169]

[0170] Step 1: Synthesis of 4-nitroisophthalic acid

[0171]

[0172] At room temperature, potassium hydroxide (12.39g, 662mmol), water (400mL) and 2-nitro-5-methylbenzoic acid (40g, 220mmol) were added to a 1L reaction flask, and heated to 90°C until the solid was completely After dissolving, potassium permanganate (104.69 g, 662 mmol) was added in batches, and the stirring reaction was continued at 90° C. for 3 hours. Filter the reaction solution while it is hot, rinse the filter residue with water (50mL×2), wait until the temperature of the obtained liquid is cooled to room temperature, adjust the pH value of the liquid to make it pH=1, stir at 0°C for 30 minutes, filter, and dry the filter cake , to obtain 43g of white solid, yield 92%.

[0173] MS(ES-API,pos.ion)m / z:209.9[M-H] - .

[0174] S...

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Abstract

The invention provides a benzothiadiazine derivative and application of the benzothiadiazine derivative in agriculture. Specifically, the invention provides a compound as shown in a formula (I) and a preparation method thereof, application of the compound as shown in the formula (I) and a composition containing the compound as shown in the formula (I) in prevention and control of weeds, and a method for preventing and controlling the weeds by using the compound as shown in the formula (I) and the composition containing the compound as shown in the formula (I). Wherein the definition of each group in the formula (I) is shown in the invention.

Description

technical field [0001] The present invention relates to the field of pesticides, in particular, the present invention relates to a benzothiadiazine derivative and a preparation method thereof, a composition containing the derivative, and the application of the derivative and the composition in controlling weeds . Background technique [0002] WO2017140612A1 and CN104557739A disclose the herbicidal activity of 2,4-quinazolinedione compounds. WO9742185 discloses that benzoxathiodioxide has certain herbicidal activity. The benzothiadiazine dioxide involved in the present invention has not been The prior art has been published. [0003] The active ingredients known from the documents cited above have disadvantages in use such as (a) no or only insufficient herbicidal action on weed plants, (b) excessive spectrum of weed plants to be controlled. Narrow or (c) too low selectivity in useful plant crops. [0004] Therefore, there is a need to provide chemically active ingredients...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07D417/06A01N43/88A01P13/00
CPCC07D417/06A01N43/88
Inventor 李义涛林健池伟林康维明陈俊禧胡晓云伍阳
Owner DONGGUAN HEC PESTICIDES R&D CO LTD
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