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A kind of preparation method of biomass fiberboard based on spherical polymer

A biomass fiber and polymer technology, applied in the direction of polymerization impregnation, manufacturing tools, flat products, etc., can solve the problems of low production efficiency of fiberboard, high pressure of fiberboard hot-pressing, hot-pressing time effect, etc., to improve the efficiency of hot-pressing forming , Easy to form under pressure, increase the effect of contact area

Active Publication Date: 2022-06-21
阜阳大可新材料股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Therefore, in the prior art, there are ubiquitous deficiencies in the hot-pressing pressure of fiberboard and the effect of hot-pressing time, resulting in lower production efficiency of fiberboard and greater energy consumption.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] The biomass fibers are selected from wood fibers, preferably eucalyptus fibers.

[0048]A preparation method of a spherical polymer-based biomass fiberboard, the specific preparation method comprises the following steps:

[0049] 1) Weigh 51.6g of diethylenetriamine and place it in a container, cool it in an ice-water bath, and slowly add a mixed solution of 43.0g of methyl acrylate and 100mL of methanol dropwise under nitrogen protection. The generated intermediate monomer is transferred to the reactor, the methanol is removed under reduced pressure, the temperature is raised to 150°C and the reaction under reduced pressure is continued for 4 hours, and the reaction is stopped to obtain a polyamide polymer;

[0050] 2) Take an appropriate amount of the above-mentioned polyamide polymer, dissolve it in deionized water to make 50 mL of mother liquor, add 0.5 mL of 0.1 mol / L silver nitrate aqueous solution dropwise to the mother liquor, and stir while dropping to form a m...

Embodiment 2

[0055] The biomass fibers are selected from wood fibers, preferably eucalyptus fibers.

[0056] A preparation method of a spherical polymer-based biomass fiberboard, the specific preparation method comprises the following steps:

[0057] 1) Weigh 61.9g of diethylenetriamine and place it in a container, cool it in an ice-water bath, and slowly add a mixed solution of 51.7g of methyl acrylate and 120mL of methanol dropwise under nitrogen protection. The generated intermediate monomer is transferred to the reactor, the methanol is removed under reduced pressure, the temperature is raised to 156°C and the reaction under reduced pressure is continued for 5 hours, and the reaction is stopped to obtain a polyamide polymer;

[0058] 2) Take an appropriate amount of the above-mentioned polyamide polymer, dissolve it in deionized water to make 65mL of mother liquor, add 0.65mL of 0.15mol / L silver nitrate aqueous solution dropwise to the mother liquor, and stir while dropping to form a m...

Embodiment 3

[0063] The biomass fibers are selected from wood fibers, preferably eucalyptus fibers.

[0064] A preparation method of a spherical polymer-based biomass fiberboard, the specific preparation method comprises the following steps:

[0065] 1) Weigh 82.5g of diethylenetriamine and put it in a container, cool it in an ice-water bath, and slowly add a mixed solution of 68.8g of methyl acrylate and 160mL of methanol dropwise under nitrogen protection. The generated intermediate monomer is transferred to the reactor, the methanol is removed under reduced pressure, the temperature is raised to 158°C and the reaction under reduced pressure is continued for 6 hours, and the reaction is stopped to obtain a polyamide polymer;

[0066] 2) Take an appropriate amount of the above-mentioned polyamide polymer, dissolve it in deionized water to make 80mL of mother liquor, add 0.8mL of 0.18mol / L silver nitrate aqueous solution dropwise to the mother liquor, and stir while dropping to form a mixe...

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PUM

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Abstract

The invention discloses a preparation method of a biomass fiber board based on a spherical polymer, and relates to the technical field of biomass fiber board processing. The specific preparation method is as follows: firstly, the polymer is made into a quasi-spherical structure, and then reduced on the surface of the quasi-spherical polymer Generate nano-silver, disperse the formed composite polymer in the emulsion, and impregnate it into the biomass fiber by vacuum pressure impregnation, and then form the fiberboard by hot pressing. In the fiberboard preparation method of the present invention, by treating the biomass fibers, the hot-pressing time and hot-pressing pressure in the hot-pressing process are reduced, thereby achieving the purpose of improving the production efficiency of the fiberboard and reducing energy consumption, and the obtained fiberboard performance data It is relatively excellent and meets the processing requirements in the current market.

Description

technical field [0001] The invention belongs to the technical field of biomass fiber board processing, and in particular relates to a preparation method of a biomass fiber board based on spherical polymers. Background technique [0002] my country is the largest producer of fiberboards in the world. Fiberboards are widely used in furniture, floor substrates and other fields due to their uniform and delicate material, excellent mechanical processing and finishing performance. Fiberboard is a man-made sheet made of wood fiber or other plant fiber and applying urea-formaldehyde resin or other suitable adhesives. Now as a new type of environmentally friendly materials, it is widely used in high-end shoe materials, automotive interiors, high-end packaging and other fields. Adhesives and / or additives may be applied during the manufacturing process. Fiberboard has the advantages of uniform material, small vertical and horizontal strength difference, not easy to crack, etc., and i...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B27N3/12B27N3/04B27N1/00B27K3/34B27K3/08B27K5/04C08J3/12C08L79/02
CPCB27N3/12B27N3/04B27N1/00B27K3/15B27K3/08B27K5/04C08J3/12B27K2200/15C08J2379/02
Inventor 刘池伟陆昌余郭海涛赵红阳吴淳生
Owner 阜阳大可新材料股份有限公司
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