A kind of preparation method of biomass fiberboard based on spherical polymer
A biomass fiber and polymer technology, applied in the direction of polymerization impregnation, manufacturing tools, flat products, etc., can solve the problems of low production efficiency of fiberboard, high pressure of fiberboard hot-pressing, hot-pressing time effect, etc., to improve the efficiency of hot-pressing forming , Easy to form under pressure, increase the effect of contact area
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Embodiment 1
[0047] The biomass fibers are selected from wood fibers, preferably eucalyptus fibers.
[0048]A preparation method of a spherical polymer-based biomass fiberboard, the specific preparation method comprises the following steps:
[0049] 1) Weigh 51.6g of diethylenetriamine and place it in a container, cool it in an ice-water bath, and slowly add a mixed solution of 43.0g of methyl acrylate and 100mL of methanol dropwise under nitrogen protection. The generated intermediate monomer is transferred to the reactor, the methanol is removed under reduced pressure, the temperature is raised to 150°C and the reaction under reduced pressure is continued for 4 hours, and the reaction is stopped to obtain a polyamide polymer;
[0050] 2) Take an appropriate amount of the above-mentioned polyamide polymer, dissolve it in deionized water to make 50 mL of mother liquor, add 0.5 mL of 0.1 mol / L silver nitrate aqueous solution dropwise to the mother liquor, and stir while dropping to form a m...
Embodiment 2
[0055] The biomass fibers are selected from wood fibers, preferably eucalyptus fibers.
[0056] A preparation method of a spherical polymer-based biomass fiberboard, the specific preparation method comprises the following steps:
[0057] 1) Weigh 61.9g of diethylenetriamine and place it in a container, cool it in an ice-water bath, and slowly add a mixed solution of 51.7g of methyl acrylate and 120mL of methanol dropwise under nitrogen protection. The generated intermediate monomer is transferred to the reactor, the methanol is removed under reduced pressure, the temperature is raised to 156°C and the reaction under reduced pressure is continued for 5 hours, and the reaction is stopped to obtain a polyamide polymer;
[0058] 2) Take an appropriate amount of the above-mentioned polyamide polymer, dissolve it in deionized water to make 65mL of mother liquor, add 0.65mL of 0.15mol / L silver nitrate aqueous solution dropwise to the mother liquor, and stir while dropping to form a m...
Embodiment 3
[0063] The biomass fibers are selected from wood fibers, preferably eucalyptus fibers.
[0064] A preparation method of a spherical polymer-based biomass fiberboard, the specific preparation method comprises the following steps:
[0065] 1) Weigh 82.5g of diethylenetriamine and put it in a container, cool it in an ice-water bath, and slowly add a mixed solution of 68.8g of methyl acrylate and 160mL of methanol dropwise under nitrogen protection. The generated intermediate monomer is transferred to the reactor, the methanol is removed under reduced pressure, the temperature is raised to 158°C and the reaction under reduced pressure is continued for 6 hours, and the reaction is stopped to obtain a polyamide polymer;
[0066] 2) Take an appropriate amount of the above-mentioned polyamide polymer, dissolve it in deionized water to make 80mL of mother liquor, add 0.8mL of 0.18mol / L silver nitrate aqueous solution dropwise to the mother liquor, and stir while dropping to form a mixe...
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