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Method for preparing composite flame retardant from ardealite

A composite flame retardant and phosphogypsum technology, which is applied in the field of flame retardant processing, can solve the problem of consumption of stockpiles and other issues

Inactive Publication Date: 2021-11-09
贵州贵诚环保科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In order to improve the utilization rate of phosphogypsum, the applicant is currently cooperating with scientific research institutions in Guizhou Province to process phosphogypsum into various PVC power pipes, communication pipes, various PE drainage and sewage pipes, road inspection manhole covers, water grates and other products. However, the consumption of phosphogypsum is still difficult to quickly consume the stockpile. In addition, with the continuous extension of the phosphate fertilizer industry, phosphogypsum is also constantly produced. Therefore, it is still necessary to further develop more Many phosphogypsum utilization channels

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] A kind of method utilizing phosphogypsum to prepare composite flame retardant comprises the following steps:

[0027] S1. Preparation of raw gypsum particles: remove impurities and purify phosphogypsum to prepare raw gypsum powder, then mix the raw gypsum powder with water to make raw gypsum particles with a particle size of 0.5-1.2 mm and a spherical rough surface.

[0028] S2. Slurry preparation: Mix magnesium hydroxide powder, clay powder, and water in a ratio of 10:5:16 to make a fluid slurry. The particle size of the magnesium hydroxide powder, aluminum hydroxide powder and clay powder is 200-600 mesh.

[0029] S3. Coating: immerse the raw gypsum particles in the slurry at 70-85°C for 15 seconds. Wrap (hang) the raw gypsum particles with a layer of slurry. Since the slurry contains clay, one or both of magnesium hydroxide powder and aluminum hydroxide powder can be well bonded and attached to the outside of the raw gypsum particles. . When the outer cladding lay...

Embodiment 2

[0036] A kind of method utilizing phosphogypsum to prepare composite flame retardant comprises the following steps:

[0037] S1. Preparation of raw gypsum particles: remove impurities and purify phosphogypsum to prepare raw gypsum powder, then mix the raw gypsum powder with water to make raw gypsum particles with a particle size of 0.5-1.2 mm and a spherical rough surface.

[0038] S2. Slurry preparation: Mix aluminum hydroxide powder, clay powder, and water in a ratio of 10:4:15 to make a fluid slurry. The particle size of the magnesium hydroxide powder, aluminum hydroxide powder and clay powder is 200-600 mesh.

[0039] S3. Coating: immerse the raw gypsum particles in the slurry at 70-85°C for 15 seconds. Wrap (hang) the raw gypsum particles with a layer of slurry. Since the slurry contains clay, one or both of magnesium hydroxide powder and aluminum hydroxide powder can be well bonded and attached to the outside of the raw gypsum particles. . When the outer cladding laye...

Embodiment 3

[0046] A kind of method utilizing phosphogypsum to prepare composite flame retardant comprises the following steps:

[0047] S1. Preparation of raw gypsum particles: remove impurities and purify phosphogypsum to prepare raw gypsum powder, then mix the raw gypsum powder with water to make raw gypsum particles with a particle size of 0.5-1.2 mm and a spherical rough surface.

[0048] S2. Slurry preparation: mix magnesium hydroxide and aluminum hydroxide mixed powder, clay powder, and water in a ratio of 10:7:19 to make a fluid slurry. Among them, in the mixed powder of magnesium hydroxide and aluminum hydroxide, the ratio of magnesium hydroxide to aluminum hydroxide is 1: (1-3); the particle size of the magnesium hydroxide powder, aluminum hydroxide powder and clay powder is 200- 600 mesh.

[0049] S3. Coating: immerse the raw gypsum particles in the slurry at 70-85°C for 20 seconds. Wrap (hang) the raw gypsum particles with a layer of slurry. Since the slurry contains clay, o...

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Abstract

The invention provides a method for preparing a composite flame retardant from ardealite. The method comprises the following steps: S1, preparing gypsum particles; S2, preparing slurry; S3, performing material wrapping; S4, filtering; S5, drying; S6, placing at low temperature; S7, performing circular treatment; and S8, obtaining the finished product. According to the invention, the composite flame retardant is prepared by compounding the mixed slurry outside the gypsum particles for multiple times, so that the phosphogypsum can be further utilized, the stockpiling amount of the phosphogypsum can be reduced, and the cost of the flame retardant can be effectively reduced on the premise of not reducing the flame retardance; and a wrapping layer outside the prepared composite flame retardant is decomposed when heated to absorb heat on the surface of comburent, the surface temperature of the synthetic material filled with the wrapping layer in flame is reduced, meanwhile, a large amount of water is released to dilute oxygen on the surface of the comburent, active oxide generated through decomposition is attached to the surface of the comburent, combustion is further prevented, and the temperature of the gypsum particles inside cannot be excessively increased and harmful substances cannot be generated.

Description

technical field [0001] The invention relates to the technical field of flame retardant processing, in particular to a method for preparing a composite flame retardant by using phosphogypsum. Background technique [0002] Phosphogypsum is a solid waste in the phosphate fertilizer industry. Generally, 4.5-5.0 tons of phosphogypsum is produced for every ton of phosphoric acid produced, and 2.5-5.0 tons of phosphogypsum is discharged for every ton of diammonium phosphate produced. The annual discharge of phosphogypsum in the country is more than 70 million tons, and the utilization rate is only about 40%. The current stockpiles have exceeded 300 million tons. The treatment and utilization of phosphogypsum is one of the major problems that the phosphorus chemical industry urgently needs at present. It has become a major bottleneck restricting the development of the phosphorus chemical industry in Guizhou. The multi-channel development and application of phosphogypsum resources is...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08K9/10C08K7/18C08K7/00C08K3/22C08K3/34C08L23/12C08L23/06
CPCC08K9/10C08K7/18C08K7/00C08K3/22C08K3/346C08L23/12C08L23/06C08K2003/2224C08K2003/2227C08L2201/02
Inventor 徐韦洪赵建波刘晓惠韦明志肖玉方朱东辉李贵汶朱国飞张艳
Owner 贵州贵诚环保科技有限公司
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