Method and product for preparing bionic structural color and mechanical properties dual response components regulated by magnetic field by using multi-material direct writing 3D printing
A magnetic field control and 3D printing technology, applied in manufacturing, additive processing, etc., can solve the problems of difficult shape, limited grain size, weak structure color, etc., and achieve the effect of low cost, long retention time and short time.
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Embodiment 1
[0032] The superparamagnetic nanoparticles are selected as ferric oxide coated with silica, the printing substrate is polydimethylsiloxane, and the non-volatile alcohol solvent is ethylene glycol. The experimental steps are as follows:
[0033] (1) Synthesize iron ferric oxide nanoparticles by high temperature hydrolysis method, take 40ml of ethylene glycol, 0.636g of trisodium citrate dihydrate, 3.6g of anhydrous sodium acetate, 3.7g of deionized water (1:1.03), 85°C Stir in a water bath for 1 hour to obtain solution A; take another 20ml of ethylene glycol solution and 1.638 g of ferric chloride hexahydrate and magnetically stir for 1 hour to obtain solution B; mix A and B and put them in a polytetrafluoroethylene reactor for high temperature reaction at 202°C 12 hours; obtain ferric oxide nanoparticles with an average particle size of 80 nm, and wash them several times with ultrasonic water.
[0034] (2) get the dispersed particle aqueous solution in 5 / 16 step (1), adopt the...
Embodiment 2
[0039] The superparamagnetic nanoparticles are selected as ferric oxide coated with silica, the printing substrate is polydimethylsiloxane, and the non-volatile alcohol solvent is ethylene glycol. The experimental steps are as follows:
[0040] (1) Use high-temperature hydrolysis to synthesize ferric oxide nanoparticles, take 40ml of ethylene glycol, 0.636g of trisodium citrate dihydrate, 3.6g of anhydrous sodium acetate, and 2.52g of deionized water (1:0.7), at 85°C Stir in a water bath for 1 hour to obtain solution A; take another 20ml of ethylene glycol solution and 1.638 g of ferric chloride hexahydrate and magnetically stir for 1 hour to obtain solution B; mix A and B and put them in a polytetrafluoroethylene reactor for high temperature reaction at 202°C 12 hours; obtain ferric oxide nanoparticles with an average particle size of 100 nm, and wash them several times with ultrasonic water.
[0041] (2) get the dispersed particle aqueous solution in the 5 / 16 step (1), adopt...
Embodiment 3
[0046] The superparamagnetic nanoparticles are selected as ferric oxide coated with silica, the printing substrate is polydimethylsiloxane, and the non-volatile alcohol solvent is ethylene glycol. The experimental steps are as follows:
[0047] (1) Synthesize iron ferric oxide nanoparticles by high temperature hydrolysis, take 40ml of ethylene glycol, 0.636g of trisodium citrate dihydrate, 3.6g of anhydrous sodium acetate, 1.8g of deionized water (1:0.5), 85°C Stir in a water bath for 1 hour to obtain solution A; take another 20ml of ethylene glycol solution and 1.638 g of ferric chloride hexahydrate and magnetically stir for 1 hour to obtain solution B; mix A and B and put them in a polytetrafluoroethylene reactor for high temperature reaction at 202°C 12h; obtain ferric oxide nanoparticles with an average particle size of 120nm, and wash them several times with ultrasonic water.
[0048] (2) get the dispersed particle aqueous solution in the 5 / 16 step (1), adopt the improved...
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