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Method and product for preparing bionic structural color and mechanical properties dual response components regulated by magnetic field by using multi-material direct writing 3D printing

A magnetic field control and 3D printing technology, applied in manufacturing, additive processing, etc., can solve the problems of difficult shape, limited grain size, weak structure color, etc., and achieve the effect of low cost, long retention time and short time.

Active Publication Date: 2022-05-17
NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, there are several methods for synthesizing photons: photolithography technology can produce precise photonic crystals, but special equipment is required and the cost is high; co-extrusion of multiple materials, fiber stretching or layer-by-layer deposition methods are used to synthesize Photonic crystals are usually limited by geometry, and complex shapes are difficult to shape; self-assembly of colloidal crystals requires uniform particles and controlled self-assembly conditions (prefabrication of templates or masks); another method is to convert colloidal particles from digital The stencil is printed directly onto the substrate so that steps such as stencil fabrication, masking, and etching can be omitted. Printing from digital stencils can be done by inkjet printing, but the size of the ink droplets limits the grain size of the resulting colloidal crystals. size, resulting in a weaker structural color

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] The superparamagnetic nanoparticles are selected as ferric oxide coated with silica, the printing substrate is polydimethylsiloxane, and the non-volatile alcohol solvent is ethylene glycol. The experimental steps are as follows:

[0033] (1) Synthesize iron ferric oxide nanoparticles by high temperature hydrolysis method, take 40ml of ethylene glycol, 0.636g of trisodium citrate dihydrate, 3.6g of anhydrous sodium acetate, 3.7g of deionized water (1:1.03), 85°C Stir in a water bath for 1 hour to obtain solution A; take another 20ml of ethylene glycol solution and 1.638 g of ferric chloride hexahydrate and magnetically stir for 1 hour to obtain solution B; mix A and B and put them in a polytetrafluoroethylene reactor for high temperature reaction at 202°C 12 hours; obtain ferric oxide nanoparticles with an average particle size of 80 nm, and wash them several times with ultrasonic water.

[0034] (2) get the dispersed particle aqueous solution in 5 / 16 step (1), adopt the...

Embodiment 2

[0039] The superparamagnetic nanoparticles are selected as ferric oxide coated with silica, the printing substrate is polydimethylsiloxane, and the non-volatile alcohol solvent is ethylene glycol. The experimental steps are as follows:

[0040] (1) Use high-temperature hydrolysis to synthesize ferric oxide nanoparticles, take 40ml of ethylene glycol, 0.636g of trisodium citrate dihydrate, 3.6g of anhydrous sodium acetate, and 2.52g of deionized water (1:0.7), at 85°C Stir in a water bath for 1 hour to obtain solution A; take another 20ml of ethylene glycol solution and 1.638 g of ferric chloride hexahydrate and magnetically stir for 1 hour to obtain solution B; mix A and B and put them in a polytetrafluoroethylene reactor for high temperature reaction at 202°C 12 hours; obtain ferric oxide nanoparticles with an average particle size of 100 nm, and wash them several times with ultrasonic water.

[0041] (2) get the dispersed particle aqueous solution in the 5 / 16 step (1), adopt...

Embodiment 3

[0046] The superparamagnetic nanoparticles are selected as ferric oxide coated with silica, the printing substrate is polydimethylsiloxane, and the non-volatile alcohol solvent is ethylene glycol. The experimental steps are as follows:

[0047] (1) Synthesize iron ferric oxide nanoparticles by high temperature hydrolysis, take 40ml of ethylene glycol, 0.636g of trisodium citrate dihydrate, 3.6g of anhydrous sodium acetate, 1.8g of deionized water (1:0.5), 85°C Stir in a water bath for 1 hour to obtain solution A; take another 20ml of ethylene glycol solution and 1.638 g of ferric chloride hexahydrate and magnetically stir for 1 hour to obtain solution B; mix A and B and put them in a polytetrafluoroethylene reactor for high temperature reaction at 202°C 12h; obtain ferric oxide nanoparticles with an average particle size of 120nm, and wash them several times with ultrasonic water.

[0048] (2) get the dispersed particle aqueous solution in the 5 / 16 step (1), adopt the improved...

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PUM

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Abstract

The invention discloses a method and a product for preparing a bionic structural color and mechanical performance dual response component regulated by a magnetic field by using multi-material direct writing 3D printing. The method includes: dispersing superparamagnetic nanoparticles in a non-volatile alcohol solvent to form a photonic crystal colloidal mixture, and then mechanically stirring and mixing it with a rubber-like elastomer; photonic crystals are embedded in the rubber-like elastomer to form microemulsion droplets to obtain rubber Shaped elastomer composite printing paste; supported by mineral oil-fumed silica nanoparticle suspension, using bioprinter direct writing 3D printing to obtain bionic structural color and mechanical properties dual response components regulated by magnetic field. The invention relies on direct writing 3D printing to form components of various shapes without being limited by templates; it relies on external magnetic field regulation to achieve double response, and can realize non-contact regulation; the preparation method is simple, the cost is low, the structural color lasts for a long time, and can be used repeatedly , which has obvious advantages in information encryption and commodity anti-counterfeiting.

Description

technical field [0001] The invention relates to the field of 3D printing multifunctional response components, in particular to a method and product for preparing bionic structural color and mechanical performance dual response components regulated by a magnetic field by using multi-material direct writing 3D printing. Background technique [0002] Inspired by nature, imitating and manufacturing biological structures, functions and biochemical processes and applying them to material design, realizing the integrated manufacturing of structures and functions has become an important research frontier in the field of materials and manufacturing. Inherently multiscale, multimaterial and multifunctional structures create new approaches. [0003] Inspired by bionic structures, the functional applications of 3D printing are divided into mechanically enhanced structures and deformable structures; structures with shape changes triggered by humidity, heat, and light; 3D printing of inte...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L83/04C08L89/00C08K9/10C08K3/22B29C64/10B33Y10/00
CPCC08K9/10C08K3/22B29C64/10B33Y10/00C08K2003/2275C08K2201/011C08K2201/005C08K2201/01C08L83/04
Inventor 孙爱华马思维叶震宇储成义张帝伟高青青李志祥程昱川郭建军许高杰
Owner NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI
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