Adhesive composition, adhesive film comprising adhesive composition, back plate film comprising adhesive film, and plastic organic light emitting display comprising adhesive film
A composition, adhesive technology, applied in the direction of adhesive types, ester copolymer adhesives, film/flake adhesives, etc., can solve the problems of panel damage, increase in bond strength, etc.
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[0154] Hereinafter, the present disclosure will be described in detail with reference to the embodiments so that those skilled in the art can easily implement the present disclosure. However, the present disclosure can be implemented in various forms, and is not limited to the embodiments described herein.
preparation example 1
[0156] Polymerization of (meth)acrylate-based resin
[0157] After introducing ethylhexyl acrylate (EHA) / methyl methacrylate (MMA) / N-vinylpyrrolidone (VP) / hydroxyethyl acrylate (HEA) into acetic acid at a weight ratio of 65 / 20 / 5 / 10 After ethyl ester (EA), azobisisobutyronitrile (AIBN) (thermal polymerization initiator) was introduced thereinto to prepare a (meth)acrylate-based resin having a weight average molecular weight of 1,000,000 g / mol.
preparation example 2
[0158] Polymerization of Polymer
[0159] Polymers having the compositions and melting temperatures of Table 1 below were prepared.
[0160] [Table 1]
[0161]
[0162] In Table 1, FM0721 is monofunctional polysiloxane and a product of Chisso Corporation is used, and FM0721 is (meth)acrylate in which polysiloxane exists.
[0163] The BHA, STA, and HDA monomers used in Preparations 1 to 4 are monomers that have only Tm characteristics when polymerized, and do not exhibit Tg characteristics.
[0164] In Table 1, BHA is behenyl acrylate, HAD is hexadecyl acrylate, and STA is stearyl acrylate.
[0165] - Manufacture of back sheet film
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