Polyimide composite material and preparation method and application thereof
A technology of composite materials and polyimide, which is applied in the direction of circuits, electrical solid state devices, semiconductor devices, etc., to achieve the effect of simple operation
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Embodiment 1
[0090] Embodiment 1: fluorinated graphene / polyimide composite material
[0091] (1) Preparation of graphene oxide
[0092] First, add 4 g of graphite and 120 mL of concentrated H to a glass bottle in an ice bath at 0 °C 2 SO 4 , then add 2 g of NaNO under constant stirring3 and 20 g of KMnO 4 And react for 1h. Then, it was kept in a 35°C water bath for 1 hour. Finally, deionized water was added up to 500 mL at 45 °C, followed by H 2 o 2 (30%) treatment, the solid matter (graphene oxide) obtained by centrifugation (9500 rpm) was washed successively with 5% hydrochloric acid and deionized water until the pH was adjusted to 7.
[0093] The above-mentioned graphene oxide is frozen by liquid nitrogen, and then thoroughly dried in a freeze dryer to obtain graphene oxide airgel powder.
[0094] (2) Preparation of fluorinated graphene
[0095] Take 1g of the above-mentioned graphene oxide airgel powder and add it to a reaction kettle of 500mL tetrafluoroethylene, add 5g XeF 2...
Embodiment 2
[0100] The only difference from Example 1 is that in step (3), the added amount of fluorinated graphene is 0.01 g, and the content of fluorinated graphene in the obtained composite material is 0.25%.
Embodiment 3
[0102] The only difference from Example 1 is that in step (3), the added amount of fluorinated graphene is 0.04g, and the content of fluorinated graphene in the obtained composite material is 1%.
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