A method for synergistic and efficient emission reduction of dioxin-like substances and NOx in the process of domestic waste incineration
A technology for dioxins and substances, which is applied in chemical instruments and methods, separation methods, and dispersed particle separation, etc., can solve problems such as large dioxins, and achieve the effects of increasing operating costs, simple and easy methods, and low prices.
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Embodiment 1
[0027] According to the mass ratio, mix 20% sodium carbonate and 80% sodium sulfide to prepare a sodium-based compound composition; transport the sodium-based compound composition together with the denitrification reducing agent urea into the dissolution tank of the SNCR system, and the sodium-based compound The usage amount of the composition is 20% of the mass of urea, and the mixture is dissolved with hot water. The mixture solution is sprayed into the flue at a temperature range of 950-1020°C through the atomizing nozzle of the SNCR system. Compared with the situation without adding the sodium-based compound composition, under the condition that the amount of urea is 12kg / hour, the chimney flue gas The concentration of dioxins is 0.048ng TEQ / Nm 3 , down 46%, NO X The average concentration is 107mg / m 3 , The denitrification efficiency (on an hourly basis) has increased by 15.8%.
Embodiment 2
[0029] According to the mass ratio, mix 80% sodium carbonate and 20% sodium sulfide to prepare a sodium-based compound composition; send this sodium-based compound composition together with denitrification reducing agent urea into the dissolution tank of the SNCR system, and the sodium-based compound The usage amount of the composition is 40% of the mass of urea, and the mixture is dissolved with hot water. The mixed solution is sprayed into the flue at a temperature range of 850-950°C through the atomizing nozzle of the SNCR system. Compared with the case where no sodium-based compound composition is added, under the condition that the amount of urea is 14kg / hour, the chimney flue gas The average concentration of dioxins is 0.052ng TEQ / Nm 3 , down 42%, NO X The average concentration is 100mg / m 3 , the denitrification efficiency (on an hourly basis) increased by 21%,
[0030] In order to further illustrate the combined use of sodium carbonate and sodium sulfide on the effec...
Embodiment 3
[0032] According to the mass ratio, mix 50% sodium carbonate and 50% sodium sulfide to prepare a sodium-based compound composition; transport this sodium-based compound composition together with denitrification reducing agent urea into the dissolution tank of the SNCR system, and the sodium-based compound The usage amount of the composition is 10% of the mass of urea, and the mixture is dissolved with hot water. The mixed solution is sprayed into the flue at a temperature range of 900-1000°C through the atomizing nozzle of the SNCR system. Compared with the situation where no sodium-based compound composition is added, under the condition that the amount of urea is 13kg / hour, the chimney flue gas The average concentration of dioxins is 0.025ng TEQ / Nm 3 , down 37%, NO X The average concentration is 82mg / m 3 , The denitrification efficiency (on an hourly basis) has increased by 15%.
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