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A method for synergistic and efficient emission reduction of dioxin-like substances and NOx in the process of domestic waste incineration

A technology for dioxins and substances, which is applied in chemical instruments and methods, separation methods, and dispersed particle separation, etc., can solve problems such as large dioxins, and achieve the effects of increasing operating costs, simple and easy methods, and low prices.

Active Publication Date: 2021-09-03
DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The purpose of the present invention is to solve the problem of producing a large amount of dioxins in the process of garbage incineration. Based on the SNCR system of a large-scale modern garbage incineration power plant, without adding new equipment, it provides a kind of dioxin in the process of domestic garbage incineration. Species and NO x Synergetic efficient emission reduction method, what the SNCR system of the present invention uses is the SNCR system reported in the literature (Research to application. Progress in Energy and Combustion Science, 1997,23 (3): 233~266)

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] According to the mass ratio, mix 20% sodium carbonate and 80% sodium sulfide to prepare a sodium-based compound composition; transport the sodium-based compound composition together with the denitrification reducing agent urea into the dissolution tank of the SNCR system, and the sodium-based compound The usage amount of the composition is 20% of the mass of urea, and the mixture is dissolved with hot water. The mixture solution is sprayed into the flue at a temperature range of 950-1020°C through the atomizing nozzle of the SNCR system. Compared with the situation without adding the sodium-based compound composition, under the condition that the amount of urea is 12kg / hour, the chimney flue gas The concentration of dioxins is 0.048ng TEQ / Nm 3 , down 46%, NO X The average concentration is 107mg / m 3 , The denitrification efficiency (on an hourly basis) has increased by 15.8%.

Embodiment 2

[0029] According to the mass ratio, mix 80% sodium carbonate and 20% sodium sulfide to prepare a sodium-based compound composition; send this sodium-based compound composition together with denitrification reducing agent urea into the dissolution tank of the SNCR system, and the sodium-based compound The usage amount of the composition is 40% of the mass of urea, and the mixture is dissolved with hot water. The mixed solution is sprayed into the flue at a temperature range of 850-950°C through the atomizing nozzle of the SNCR system. Compared with the case where no sodium-based compound composition is added, under the condition that the amount of urea is 14kg / hour, the chimney flue gas The average concentration of dioxins is 0.052ng TEQ / Nm 3 , down 42%, NO X The average concentration is 100mg / m 3 , the denitrification efficiency (on an hourly basis) increased by 21%,

[0030] In order to further illustrate the combined use of sodium carbonate and sodium sulfide on the effec...

Embodiment 3

[0032] According to the mass ratio, mix 50% sodium carbonate and 50% sodium sulfide to prepare a sodium-based compound composition; transport this sodium-based compound composition together with denitrification reducing agent urea into the dissolution tank of the SNCR system, and the sodium-based compound The usage amount of the composition is 10% of the mass of urea, and the mixture is dissolved with hot water. The mixed solution is sprayed into the flue at a temperature range of 900-1000°C through the atomizing nozzle of the SNCR system. Compared with the situation where no sodium-based compound composition is added, under the condition that the amount of urea is 13kg / hour, the chimney flue gas The average concentration of dioxins is 0.025ng TEQ / Nm 3 , down 37%, NO X The average concentration is 82mg / m 3 , The denitrification efficiency (on an hourly basis) has increased by 15%.

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PUM

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Abstract

The invention discloses a process of dioxin-like substances and NO x Synergistic and efficient emission reduction methods. The sodium-based compound composition is mixed with the denitrification reducing agent urea, and the aqueous solution of the mixture is atomized and sprayed into the flue at a temperature range of 850-1050°C through the SNCR system, and at the same time, it can suppress the formation of dioxins and increase NO x The purpose of removal efficiency. The sodium-based compound composition is composed of sodium carbonate and sodium sulfide; in the composition, the mass percentage of the sodium carbonate is 20% to 80%, and the mass percentage of the sodium sulfide is 20% to 80%. 80%. The usage amount of the sodium-based compound composition is 10%-40% of the mass of urea. The method is simple and easy to operate, and the operation cost is low, and it can be used for dioxin-like substances and NO in domestic waste incineration facilities. x Provide technical support for up-to-standard discharge.

Description

technical field [0001] The invention belongs to the field of incineration and disposal of solid waste in the field of environmental protection, and specifically relates to a method for simultaneously realizing the generation control of dioxins and the efficient removal of nitrogen oxides during the incineration process of domestic waste. Background technique [0002] Incineration has become the main way of domestic waste disposal in my country. During the incineration and disposal of domestic waste, highly toxic dioxin-like substances will be generated, and a large amount of nitrogen oxides (NO x )emission. In order to control the emission of dioxins, my country's large-scale modern waste incineration power generation facilities generally adopt "3T+E" technology (controlling incineration temperature, mixing degree, gas residence time, and excess air rate), flue gas quenching technology and activated carbon + bag filter technology, despite this, the emission level of dioxins...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D53/56B01D53/70B01D53/78B01D53/79
CPCB01D53/56B01D53/70B01D53/78B01D53/79B01D2251/2067B01D2251/304B01D2251/60B01D2251/606B01D2258/0291
Inventor 张海军吕杨振中张亦弛张宁倪余文高媛陈吉平
Owner DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI
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