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Edge-closed quantum dot enhanced film and preparation method thereof

A technology of quantum dot enhanced film and quantum dot film, which is applied in the direction of chemical instruments and methods, synthetic resin layered products, layered products, etc., can solve the problem of whitening of the edge of quantum dot film, loss of orange-yellow color, and inability to improve the effect and other issues, to achieve the effect of simple operation

Inactive Publication Date: 2020-04-21
NANJING BREADY ELECTRONICS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

During the process of forming and cutting the coil, the edge part is exposed to air and water vapor. After a long time of exposure, the air and moisture will penetrate into the inner layer of the quantum dot film and chemically interact with the quantum dots, making the quantum dots fluorescent The yield is reduced, causing the quantum dots to lose their original color, causing the edge of the quantum dot film to turn white and lose its original orange-yellow color
[0007] At present, some patents have begun to reduce the edge effect of quantum dot films by sealing the edges (Chinese patent CN 104501043 A, Chinese patent CN 106189826 A), but the above-mentioned edge-closed quantum dot films have some disadvantages: (1) In the quantum dot film Coating the adhesive layer on the edge of the film will greatly reduce the production efficiency; (2) the area where the adhesive layer is difficult to apply, such as the positioning hole of the membrane, will not be able to improve the effect; (3) the method of curing the liquid microcapsule at the edge means that There are liquid microcapsules in the whole quantum dot membrane. To ensure that the glue is cured but the liquid microcapsules are not cured, the curing and forming method is relatively difficult; (4) The liquid microcapsules will affect the optical and mechanical properties of the quantum dot film , it is difficult to ensure that the quantum dot film will not deform under the action of external force

Method used

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  • Edge-closed quantum dot enhanced film and preparation method thereof
  • Edge-closed quantum dot enhanced film and preparation method thereof
  • Edge-closed quantum dot enhanced film and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0046] (1) Preparation of quantum dot film

[0047] Green and red CdSe quantum dots with an average particle size of 3nm and 7nm dissolved in toluene with a mass fraction of 1% were mixed with the matrix resin polyacrylic acid resin and the scattering particles SiO 2 , the photoinitiator 1173 and the diluent acetic acid are mixed together by slit coating and bonded together with the PET base film 201 with the barrier layer 202 , and then subjected to 390nm UV light. At this time, the intermediate glue layer is cured into the quantum dot layer 203 under UV light to form a multi-layer structure with a total thickness of 350 μm, and the thickness of the quantum dot layer is 100 μm.

[0048] (2) Cutting of quantum dot film

[0049] According to the required size, the quantum dot film is cut into the required pattern and punched on the sheet as required.

[0050] (3) Wet coating encapsulation of quantum dot film

[0051] After the quantum dot film roll is cut and punched for pos...

Embodiment 2

[0053] Preparation of quantum dot film: the green and red CdSe quantum dots with an average particle size of 3 nm and 7 nm dissolved in n-hexane with a mass fraction of 1% and matrix resin polyacrylic acid resin, scattering particles CaO 2 , the thermal initiator and the diluent toluene are mixed together by slit coating and bonded together with the PET base film 201 with the barrier layer 202 , and then subjected to 390nm UV light. At this time, the intermediate glue layer is cured into the quantum dot layer 203 under UV light to form a multi-layer structure with a total thickness of 350 μm, and the thickness of the quantum dot layer is 100 μm.

Embodiment 3

[0055] Preparation of quantum dot film: the green and red CdSe quantum dots with an average particle size of 3 nm and 7 nm dissolved in isobornyl acrylate with a mass fraction of 1% were mixed with matrix resin polyacrylic acid resin, mercapto resin, and scattering particles TiO 2 , the photoinitiator 1173 and the diluent ethyl acetate are mixed together and bonded together with the PET base film 201 with the barrier layer 202 by slit coating. The total thickness of the barrier layer 202 and the PET base film 201 is 50 μm, and then passes through UV light and 80°C high temperature oven. At this time, the intermediate glue layer is cured into the quantum dot layer 203 under UV light and high temperature to form a multi-layer structure with a total thickness of 200 μm, wherein the thickness of the quantum dot layer is 100 μm.

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Abstract

The invention discloses an edge-closed quantum dot enhanced film. The quantum dot enhanced film has a multi-layer structure, and comprises two outer base films, two inner barrier layers and a middle quantum dot layer, wherein the two inner barrier layers are located on the outer sides of the middle quantum dot layer, the two outer base films are located on the outer sides of the two inner barrierlayers, the thickness of each outer base film is 50-125 [mu]m, the thickness of each inner barrier layer is 0.001-0.5 [mu]m, and the thickness of the middle quantum dot layer is 50-150 [mu]m; the quantum dot layer is composed of matrix resin, quantum dots, a quantum dot stabilizer, scattering particles, an initiator and a diluent. The invention also discloses a preparation method of the edge-closed quantum dot enhanced film. The method is easy to operate, and avoids the need of time-consuming and labor-consuming coating on a specific area, and only a step of immersing a whole quantum dot filmis needed. In addition, the method can be used for coating a plurality of layers of ultrathin films with the minimum thickness of 20 nm, and the optical performance of the product is hardly influenced.

Description

technical field [0001] The invention relates to an edge-closed quantum dot enhanced film. [0002] The invention also relates to a method for preparing an edge-closed quantum dot reinforced film. [0003] The invention also relates to a preparation method of the slurry of the quantum dot film, in particular to a preparation method of the slurry suitable for making the quantum dot film by the slit coating method. . Background technique [0004] Quantum Dots (QDs) are semiconductor nanoparticles with a size between 1-10nm. Due to their small physical structure, they can bind conductive particles, holes and excitons in three directions. So it has a quantum effect. Due to its structure, quantum dots can be used in many fields, such as light-emitting devices, solar cells, bioluminescent labels, etc., and have broad application prospects. [0005] At present, the most extensive and profound application field of quantum dots is in the field of optics. The quantum dot film made...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B32B27/00B32B27/06B32B33/00B32B27/18
CPCB32B27/00B32B27/06B32B27/18B32B33/00
Inventor 刘勇谢彬彬
Owner NANJING BREADY ELECTRONICS CO LTD
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