High-concentration general color paste as well as preparation method and application thereof
A high-concentration, color paste technology, used in pigment slurry, coating, epoxy resin coating, etc., can solve the problem of poor stability of ester bond, deep color of polyester resin, affecting the resistance of paint film, color retention and gloss retention. and other problems, to achieve the effect of excellent color retention and light retention, alkali resistance and water resistance, no floating color, and reducing the possibility of re-flocculation or aggregation.
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preparation example Construction
[0040] In a preferred example, the preparation method of the polyester modified acrylic resin comprises the following steps:
[0041] Mix lauric acid, isononanoic acid, isooctanoic acid, NPG, TMP, terephthalic anhydride, hexahydrophthalic anhydride, tetrahydrophthalic anhydride, butenedioic anhydride and heat up to 120°C. After dehydration, heat up to 225 within 4 hours. Keep at ℃ for 0.5 hours. When the acid value is less than 30mgKOH / g, add xylene to reflux. When the acid value is less than 6.5-10.5mgKOH / g and the viscosity is Z1-Z3, a polyester intermediate is obtained;
[0042] Heat the polyester intermediate and solvent to 150-160°C under nitrogen protection, add the mixture of acrylate monomer and 90wt% initiator dropwise within 3 hours, keep it warm for 1 hour, and then add the remaining initiator , kept warm for 3 hours, and diluted to a solid content of 70%, to obtain the polyester-modified acrylic resin.
[0043]The polyester-modified acrylic resin structure reduces...
Embodiment 1
[0066] Include in the highly concentrated universal environment-friendly color paste raw material of the present embodiment: 31kg mass percent is 70% polyester modified acrylic resin A, 9.5kg propylene glycol methyl ether acetate, 5kg S-100 solvent, iron yellow 48kg, polyurethane Dispersant 6.5kg.
[0067] Its preparation method is: (1) the polyester modified acrylic resin A of 31kg, 6.5kg polyurethane dispersant, 9.025kg propylene glycol methyl ether acetate, 4.75kg S-100 solvent is added in the container of suitable size, stirs (400 -600rpm) for 10-15 minutes; (2) Add 48kg of PY42 iron yellow pigment while stirring, after adding the pigment, stir (400-600rpm) for 10-15 minutes; (3) Add the remaining solvent propylene glycol methyl along the container wall while stirring Ether acetate and S-100 solvent, continue to stir for 30 minutes until uniform; (4) Start grinding and dispersing on the designated sand mill until the fineness meets the requirements;
[0068] The above-men...
Embodiment 2-5
[0070] The components of the highly concentrated universal environment-friendly color paste of each embodiment are shown in Table 1, the preparation method of each embodiment is basically the same as that of Example 1, and the technical indicators of the prepared coating are shown in Table 2.
[0071] The formula composition of table 1 embodiment 2-5 environment-friendly color paste
[0072]
[0073]
[0074] Table 2 embodiment 1-5 gained color paste performance
[0075]
[0076] The above-mentioned high-concentration universal colorants are used to replace the original low-concentration colorants of several product systems to prepare colored paints, and the key performance changes before and after the replacement are investigated.
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