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Strengthened microcrystalline glass with high-pressure stress layer depth and preparation method thereof

A technology of stress layer depth and glass-ceramics, which is applied in the field of glass strengthening, can solve the problems of low stress and restricting the drop resistance performance of lithium-aluminum-silicon chemically strengthened glass, achieve less stress relaxation and improve the intrinsic network structure strength , the effect of a wide range of applications

Active Publication Date: 2020-02-28
CHONGQING XINJING SPECIAL GLASS CO LTD
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

And due to the stress relaxation phenomenon, the stress of the deep compressive stress part is not high, which restricts the drop strength performance of lithium aluminum silicon chemically strengthened glass

Method used

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  • Strengthened microcrystalline glass with high-pressure stress layer depth and preparation method thereof
  • Strengthened microcrystalline glass with high-pressure stress layer depth and preparation method thereof
  • Strengthened microcrystalline glass with high-pressure stress layer depth and preparation method thereof

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Effect test

Embodiment 2-6

[0074] The preparation method is the same as in Example 1, and the recipes and test parameters are shown in Table 1 and Table 2.

[0075] Combining Table 1 and Table 2, the depth of the compressive stress layer of the strengthened glass-ceramics of Examples 1-5 of the present invention accounts for more than 20% of the total thickness of the glass, the CT-LD is more than 50000Mpa / mm, and the drop resistance height exceeds 1.7m. The strength of the glass-ceramics is improved through the above-mentioned ion exchange process, and the participation of lithium ions in the ion-exchange can make the high-pressure stress and stress relaxation resistance of the glass-ceramics resist the weakening effect of the lithium-containing salt bath on the deep compressive stress. It has high crystallinity, which improves the intrinsic network structure strength of glass-ceramics, which can accommodate high compressive stress and less stress relaxation at high temperature; the first step is to str...

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Abstract

The invention discloses strengthened microcrystalline glass with high stress layer depth and a preparation method of the strengthened microcrystalline glass. The strengthened microcrystalline glass isformed by carrying out chemical ion exchange on the microcrystalline glass in a salt bath for one time or multiple times; a pressure stress layer and a tensile stress layer corresponding to the pressure stress layer are sequentially formed on the two opposite sides of the strengthened microcrystalline glass from the surface to the interior respectively, and the depth of the single-face pressure stress layer of the strengthened microcrystalline glass is 18%-25% of the total thickness of the strengthened microcrystalline glass. The high crystallinity of the strengthened microcrystalline glass improves the intrinsic network structure strength of the strengthened microcrystalline glass, so that the microcrystalline glass can accommodate higher compressive stress, and the stress relaxation amount at high temperature is small; the exchange depth of the microcrystalline glass can be increased by adopting a lithium-containing salt bath, so that the depth of the pressure stress layer is remarkably increased; the depth of the stress layer of the strengthened microcrystalline glass accounts for more than 18% of the total thickness of the glass, and the strengthened microcrystalline glass hasvery high anti-falling strength; wide field of application.

Description

technical field [0001] The invention relates to the technical field of glass strengthening, in particular to a strengthened glass-ceramic with a high-pressure stress layer depth and a preparation method thereof. Background technique [0002] With the advent of the intelligent era, the intelligence of various products will be rapidly popularized, ranging from houses, cars, and furniture to small audio, remote controls, and drinking fountains. The screen control is the basic part of most intelligent equipment. In order to adapt to various use environments of the product, as a protective material for the screen, it is necessary to further improve its acid and alkali resistance, temperature shock resistance, mechanical shock resistance and other characteristics, and must meet Requirements for various shapes and certain transparency requirements. [0003] At present, most of the screen protection materials are glass, which has the advantages of high transmittance, good stability...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C21/00C03C10/14C03C10/12C03C10/04
CPCC03C21/002C03C10/0009C03C10/0027C03C10/00
Inventor 胡伟谈宝权覃文城张延起
Owner CHONGQING XINJING SPECIAL GLASS CO LTD
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