Inorganic particle composite polyurethane synthetic leather and preparation method and application thereof

A technology of composite polyurethane and inorganic particles, which is applied in the field of polyurethane synthetic leather, can solve the problem of high VOC volatilization, achieve the effects of reducing VOC emissions, simple and easy preparation method, and reducing photothermal cracking

Inactive Publication Date: 2020-01-07
ANHUI ANLI MATERIAL TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In view of this, it is necessary for the present invention to provide a kind of inorganic particle composite polyurethane synthetic leather and its preparation method, which can reduce the volatilization amount of its VOC, and meanwhile have excellent mechanical properties and excellent weather resistance, so as to solve the problem of the existing polyurethane synthetic leather used in automobile interiors. The problem of high VOC volatilization during processing and use of decorative materials

Method used

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  • Inorganic particle composite polyurethane synthetic leather and preparation method and application thereof
  • Inorganic particle composite polyurethane synthetic leather and preparation method and application thereof
  • Inorganic particle composite polyurethane synthetic leather and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] Composite material A comprises the component of following mass parts:

[0034]

[0035] After fully stirring the above-mentioned castor oil polyoxyethylene ether HEL-40, polytetrahydrofuran glycol THF2000, ethylene glycol EG, and catalyst BiCAT 8124, heat up to 60°C, add foaming agent water, and cool down after the moisture content is ≤300ppm to 40°C, and then ultrasonically disperse the surface-modified nano-silicon Si-50 and the modified inorganic retardant fuel ADP-3 evenly, stir evenly, then vacuum defoam, seal the package for use, and stand still to obtain the composite material A material.

[0036] Preparation of material B of the combination: Mix the liquid MDI-100 at a temperature of 60°C, fully stir to obtain material B, let it stand still, and set it aside.

[0037] Preparation of inorganic particle composite polyurethane synthetic leather: coating surface layer polyurethane slurry on release paper, drying at 130°C to obtain solvent-based surface layer.

...

Embodiment 2

[0041] Composite material A comprises following mass parts:

[0042]

[0043] After fully stirring the above-mentioned castor oil polyoxyethylene ether HEL-40, polytetrahydrofuran glycol THF2000, ethylene glycol EG, and catalyst BiCAT 8124, heat up to 60°C, add foaming agent water, and cool down after the moisture content is ≤300ppm to 40°C, and then ultrasonically disperse the surface-modified nano-silicon Si-50 and the modified inorganic retardant fuel ADP-3 evenly, stir evenly, then vacuum defoam, seal the package for use, and stand still to obtain the composite material A material.

[0044] Preparation of material B of the combination: Mix the liquid MDI-100 at a temperature of 60°C, fully stir to obtain material B, let it stand still, and set it aside.

[0045] The preparation of the inorganic particle-composite polyurethane synthetic leather: coating the polyurethane slurry of the surface layer on the release paper, drying and molding at 130°C to obtain the solvent-b...

Embodiment 3

[0049] Composite material A comprises following mass parts:

[0050]

[0051] After fully stirring the above-mentioned castor oil polyoxyethylene ether HEL-40, polytetrahydrofuran glycol THF2000, ethylene glycol EG, and catalyst BiCAT 8124, heat up to 60°C, add foaming agent water, and cool down after the moisture content is ≤300ppm to 40°C, and then ultrasonically disperse the surface-modified nano-silicon Si-50 and the modified inorganic retardant fuel ADP-3 evenly, stir evenly, then vacuum defoam, seal the package for use, and stand still to obtain the composite material A material.

[0052] Preparation of material B of the combination: Mix the liquid MDI-100 at a temperature of 60°C, fully stir to obtain material B, let it stand still, and set it aside.

[0053] The preparation of the inorganic particle-composite polyurethane synthetic leather: coating the polyurethane slurry of the surface layer on the release paper, drying and molding at 130°C to obtain the solvent-b...

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PUM

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Abstract

The invention discloses inorganic particle composite polyurethane synthetic leather and a preparation method and application thereof. The inorganic particle composite polyurethane synthetic leather isprepared from a composite material A and a composite material B according to a mass ratio of 100:(40-80) through solvent-free reaction. The composite material A is prepared from, by mass, 90-120 parts of biomass polyether polyol, 30-50 parts of polyether polyol, 5-12 parts of a chain extender, 2-5 parts of a foaming agent, 1-10 parts of a catalyst, 5-15 parts of an inorganic nano composite material and 10-30 parts of an inorganic flame retardant. The composite material B refers to cyanate ester organics. Organic solvent consumption is avoided in a manufacturing process, and the prepared inorganic particle composite polyurethane synthetic leather has excellent flame retardation and mechanical properties, high resistance to light and heat and long service life and has evident economic and environment-friendly advantages in application to automotive interior decorative materials.

Description

technical field [0001] The invention belongs to the field of polyurethane synthetic leather, and in particular relates to inorganic particle composite polyurethane synthetic leather and its preparation method and application. Background technique [0002] Polyurethane synthetic leather belongs to the category of polyurethane elastomers. It has soft and natural luster, soft touch, and a strong leather-like appearance. It has excellent mechanical properties such as excellent adhesion to substrates, wear resistance, flex resistance, and aging resistance. At the same time, it also has the advantages of good cold resistance, breathability, washability, convenient processing, and low price. It is the most ideal substitute for natural leather. [0003] As one of the pillar industries of my country's national economy, the automobile industry has been leading the world in production and sales for many years, and will continue to maintain a positive development trend in the future. Un...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06N3/14D06N3/00C08G18/67C08G18/66C08G18/48C08G18/42C08G18/32C08K9/06C08K9/04C08K3/36C08K3/34C08K3/22C08G101/00
CPCC08G18/4018C08G18/42C08G18/48C08G18/4854C08G18/6674C08G18/6795C08K3/2279C08K3/34C08K3/36C08K9/04C08K9/06C08K2201/011C08G2110/0083D06N3/0063D06N3/0097D06N3/14D06N2209/1692D06N2211/261D06N2211/263D06N2211/28
Inventor 邢高瞻陈绪珍赵伟栋沈宏武张彪程艳西黄万里
Owner ANHUI ANLI MATERIAL TECH
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