Preparation method of polymer-based composite energetic material-coated modified nano metal particles
A technology of nano metal particles and polymers, used in offensive equipment, explosives processing equipment, non-explosive/non-thermal agent components, etc., can solve problems such as poor practicability, and achieve easy oxidation, excellent mechanical properties, and good practicability. Effect
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Embodiment 1
[0030] The preparation method of polymer NC coated nano metal silicon powder particles comprises the following process steps:
[0031] Coating of nano-silica powder: 100mg NC was dried in an oven at 60°C for 1 hour to remove moisture. Afterwards, NC was dissolved in a mixed solvent of 12 ml acetone (AR) and 3 ml N,N-dimethylformamide (DMF) (volume ratio 4:1), and sonicated for 1 hour. 200 mg of nano-Si powder was added to the NC solution at a certain ratio (the mass ratio of NC and Si was 1:2), and magnetically stirred for 2 hours to obtain a NC / Si suspension.
[0032] Doping of the energetic oxidant AP: 200 mg of AP was ground in a mortar with acetone solvent for half an hour. At the same time, gently pour the ground AP into the NC / Si suspension in a certain ratio (the mass ratio of NC and AP is 1:2), and stir it magnetically for 2 hours to obtain the final precursor solution of NC / AP / Si .
[0033] Preparation of composite nanoparticles by electrostatic spraying method: put ...
Embodiment 2
[0038] Coating of nano silicon powder: 66.66mg NC was dried in an oven at 60°C for 1 hour to remove moisture. Afterwards, NC was dissolved in a mixed solvent of 8ml acetone (AR) and 2ml N,N-dimethylformamide (DMF) (AR:DMF=4:1), and sonicated for 1 hour. 300mg of nano-Si powder was added to the NC solution at a certain ratio (the mass ratio of NC and Si was 1:4.5), and magnetically stirred for 2 hours to obtain a NC / Si suspension.
[0039] Doping of the energetic oxidant AP: 133.34 mg AP was ground in a mortar with acetone solvent for half an hour. At the same time, gently pour the ground AP into the NC / Si suspension in a certain ratio (the mass ratio of NC and AP is 1:2), and stir it magnetically for 2 hours to obtain the final precursor solution of NC / AP / Si .
[0040] Preparation of composite nanoparticles by electrostatic spraying method: put the prepared NC / AP / Si precursor solution into a syringe (the inner diameter of the needle is 6.25mm), and the injection speed is 1.5...
Embodiment 3
[0045] Coating of nano silicon powder: 33.3mg NC was dried in an oven at 60°C for 1 hour to remove moisture. NC was dissolved in a mixed solvent of 4 ml acetone (AR) and 1 ml N,N-dimethylformamide (DMF) (volume ratio 4:1), and sonicated for 1 hour. 400 mg of nano-Si powder was added to the NC solution at a certain ratio (the mass ratio of NC and Si was 1:12), and magnetically stirred for 2 hours to obtain a NC / Si suspension.
[0046] Doping of the energetic oxidant AP: 66.7 mg AP was ground in a mortar with acetone solvent for half an hour. At the same time, gently pour the ground AP into the NC / Si suspension in a certain ratio (the mass ratio of NC and AP is 1:2), and stir it magnetically for 2 hours to obtain the final precursor solution of NC / AP / Si .
[0047] Preparation of composite nanoparticles by electrostatic spraying method: put the prepared NC / AP / Si precursor solution into a syringe (the inner diameter of the needle is 6.25mm), and the injection speed is 0.6mm min ...
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