Benzimidazole n-type dopant and application thereof in organic electroluminescent devices
A technology of benzimidazole and dopant, applied in the field of organic electroluminescent materials, can solve the problems of few co-evaporable mixed materials and difficult control of doping concentration, so as to improve the efficiency and stability of the device and facilitate long-term storage. , the effect of reducing costs
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Embodiment 1
[0091] The device 1 structure of the present embodiment is as follows:
[0092] ITO(150nm) / HATCN(40nm) / NPB(30nm) / TCTA(10nm) / CBP:5wt%Ir(ppy) 3 (30nm) / Bphen(30nm) / Bphen: 30wt% Formula (1-3)(20nm) / Al(150nm)
[0093] Wherein, the (o-MeO-DMBI-I) structural formula shown in formula (1-3) is as follows:
[0094]
[0095] The 30 wt% before o-MeO-DMBI-I in Device 1 represents the doping concentration of o-MeO-DMBI-I in the electron transport material.
[0096] The specific preparation method of the organic electroluminescent device is as follows:
[0097] First, the glass substrate is cleaned with detergent and deionized water, and dried under an infrared lamp, and a layer of anode material is sputtered on the glass with a film thickness of 150nm;
[0098] Then, the above-mentioned glass substrate with the anode is placed in a vacuum chamber, and the vacuum is evacuated to 1×10 -4 Pa, continue to vapor-deposit HATCN as a hole injection layer on the above-mentioned anode layer fi...
Embodiment 2-17
[0116] In order to test the influence of the host material of the present invention on the performance of the organic electroluminescent device, the organic electroluminescent device was prepared in the same method as in the above-mentioned Example 1 in this example, and the structure of the device 2-17 is as follows:
[0117] ITO(150nm) / NPB(40nm) / CBP: 3% phosphorescent dye (Ir(ppy) 3 )(30nm) / Bphen(20nm) / LiF(0.5nm) / Al(150nm).
[0118] In this embodiment and hereinafter, the doping concentrations of benzimidazole n-type dopants are all wt%, that is, 0.5, 1, 5, 10, 20, and 30 represent 0.5wt%, 1wt% respectively. %, 5wt%, 10wt%, 20wt%, 30wt%.
[0119] The properties of the organic electroluminescent device are shown in Table 4 below:
[0120] Table 4
[0121]
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