Ecological restoration method for black and odorous riverway
An ecological restoration and river channel technology, applied in chemical instruments and methods, biological water/sewage treatment, polluted waterway/lake/pond/river treatment, etc. To solve the problem of large amount of minerals, it can achieve the effect of thorough treatment efficiency, increase adsorption rate and adsorption stability, and complete treatment.
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Embodiment 1
[0049] (1) Calcinate the natural zeolite in a muffle furnace at 800°C for 12 hours.
[0050] (2) Mix the pretreated 100g natural zeolite with 2000g 20wt% silane coupling agent-toluene solution evenly, stir and reflux for 10 hours, then filter with suction, wash the filter cake several times with toluene, and then extract it with ethanol for 24 Hours later, vacuum-dry and grind to obtain organically modified natural zeolite or bentonite.
[0051] (3) Add 500g of the organically modified natural zeolite and 150g of sodium carboxymethylcellulose into 15kg of water, adjust the pH to 4, reflux for 10 hours, filter, wash the filter cake with water, dry in vacuum, and grind to obtain 562g of modified zeolite . Adopt the same method as step (1)~(3) to prepare 500g modified bentonite.
[0052] (4) After mixing 12 parts by weight of modified zeolite, 10 parts by weight of polyaluminum iron silicate, 40 parts by weight of modified bentonite and 38 parts by weight of pottery clay, grind...
Embodiment 2
[0061] (1) Calcinate the natural zeolite in a muffle furnace at 900°C for 10 hours.
[0062] (2) Mix the pretreated 100g natural zeolite with 2200g 18wt% silane coupling agent-toluene solution, stir and reflux for 10 hours, then filter with suction, wash the filter cake several times with toluene, and then extract it with ethanol for 24 Hours later, vacuum-dry and grind to obtain organically modified natural zeolite or bentonite.
[0063] (3) Add 500g of the prepared organically modified natural zeolite and 100g of sodium carboxymethylcellulose into 10kg of water, adjust the pH to 4, reflux for 10 hours, filter, wash the filter cake with water, dry in vacuum, and grind to obtain 556g of modified zeolite . Adopt the same method as step (1)~(3) to prepare 500g modified bentonite.
[0064] (4) After mixing 15 parts by weight of modified zeolite, 5 parts by weight of polyaluminum iron silicate, 30 parts by weight of modified bentonite and 50 parts by weight of pottery clay, grin...
Embodiment 3
[0073] (1) Calcinate the natural zeolite in a muffle furnace at 1000°C for 8 hours.
[0074] (2) Mix the pretreated 100g natural zeolite with 2500g 25wt% silane coupling agent-toluene solution, stir and reflux for 10 hours, then filter with suction, wash the filter cake several times with toluene, and then extract it with ethanol for 24 Hours later, vacuum-dry and grind to obtain organically modified natural zeolite or bentonite.
[0075] (3) Add 500g of the organically modified natural zeolite and 200g of sodium carboxymethylcellulose into 12.5kg of water, adjust the pH to 4, reflux for 10 hours, filter, wash the filter cake with water, dry in vacuum, and grind to obtain 547g of modified Zeolite. Adopt the method identical with step (1)~(3) to obtain 500g modified bentonite.
[0076] (4) After mixing 10 parts by weight of modified zeolite, 11 parts by weight of polyaluminum iron silicate, 50 parts by weight of modified bentonite and 29 parts by weight of pottery clay, grind...
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