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A tough formaldehyde-free soybean meal-based wood adhesive and its preparation method

The technology of wood adhesive and aldehyde soybean meal is applied in the field of tough aldehyde-free soybean meal-based wood adhesive and its preparation, which can solve the problems of free formaldehyde emission and poor water-resistant bonding performance of wood-based panels, and improve the bonding performance. , Improve water-resistant bonding performance, good uniformity

Active Publication Date: 2021-02-02
山东千森木业集团有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The use of biomass adhesives to prepare wood-based panels can solve the problem of free formaldehyde release from wood-based panels, which is an important way to solve the problem. However, most biomass adhesives have poor water resistance and bonding performance, which limits their industrial application.

Method used

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  • A tough formaldehyde-free soybean meal-based wood adhesive and its preparation method

Examples

Experimental program
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Effect test

Embodiment 1

[0033] This example provides a method for preparing a tough formaldehyde-free soybean meal-based wood adhesive, and the adhesive is prepared according to the following weight ratio:

[0034] Modified soybean meal based wood 30 kg

[0035] Branched long chain starch 3 kg

[0036] Polyacrylamide 0.1kg

[0037] Self-made polyfunctional epoxy compound 2kg

[0038] Sodium hydroxide solution 0.3kg

[0039] This embodiment also provides the preparation method of the above-mentioned adhesive, and the specific preparation steps are as follows:

[0040] (1) Weigh the components according to the weight ratio, add the branched long-chain starch into the dispersion medium water, ultrasonicate for 15 minutes, and then add half the weight of modified soybean meal-based wood, use a high-pressure homogenizer, under 30MPa pressure and 0.5 Under the emulsifying force of MPa, homogeneously emulsify for 20 minutes;

[0041] (2) Add the remaining modified soybean meal-based wood to the mixture...

Embodiment 2

[0043] This example provides a method for preparing a tough formaldehyde-free soybean meal-based wood adhesive, and the adhesive is prepared according to the following weight ratio:

[0044] Modified soybean meal based wood 33kg

[0045] Branched long chain starch 6kg

[0046] Polyacrylamide 0.2kg

[0047] Self-made multifunctional epoxy compound 4kg

[0048] Sodium hydroxide solution 0.6kg

[0049] The preparation method of the adhesive described in this embodiment is the same as that in Example 1.

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Abstract

The invention discloses a tough formaldehyde-free soybean meal-based wood adhesive and a preparation method thereof, comprising the following components in parts by weight: 30-33 parts by weight of main agent, 70 parts by weight of dispersion medium water, and 3-6 parts by weight of reinforcing agent , 0.1-0.2 parts by weight of a viscosity regulator, 2-4 parts by weight of a crosslinking agent, and 0.3-0.6 parts by weight of a catalyst; the preparation process is as follows: first weigh each component according to the weight ratio, and add the crosslinking agent to the dispersion medium water , then add the main agent and reinforcing agent, use a high-pressure homogenizer, under the action of 30MPa pressure and 0.5MPa emulsifying force, homogeneously emulsify for 20 minutes; then add the catalyst to the prepared mixture, and react at 80°C for 30min, Lower the temperature at 30°C and discharge; the adhesive of the present invention is easy to form a cross-linked structure, has a high cross-linking density, and a low reaction temperature. The performance of the prepared adhesive is stable, the weak interface layer is significantly reduced, the cost is reduced, the dry / wet strength is good, and the product quality Steady improvement.

Description

technical field [0001] The invention relates to the field of plywood preparation, in particular to a tough formaldehyde-free soybean meal-based wood adhesive and a preparation method thereof. Background technique [0002] my country's precious wood resources are relatively scarce, and artificial forest resources are abundant. Using artificial forest fast-growing wood to prepare wood-based panels through adhesives is the main raw material for furniture floors and interior decoration in the living environment. In 2017, the total output of my country's wood-based panels was 295 million cubic meters Rice, accounting for about 50% of the world's total output, of which more than 60% are plywood products. Based on the average production of 9 cubic meters of wood-based panels per ton of adhesive, the consumption of adhesives for plywood in my country in 2017 was about 18 million tons (solid content 50%), of which urea-formaldehyde resin and its modified products accounted for the tot...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J189/04C09J11/08C09J187/00C09J177/06C09J133/26C08G81/00C08G69/26C08G69/48C08B35/00
CPCC08B35/00C08G69/265C08G69/48C08G81/00C08L2205/035C09J11/08C09J189/04C08L87/005C08L77/06C08L33/26
Inventor 高强许超杰陈明松李建章周文瑞张伟
Owner 山东千森木业集团有限公司
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