Preparation method of NOx adsorbing material with HC catalytic oxidation function

An adsorption material and catalytic oxidation technology, which is applied to chemical instruments and methods, separation methods, molecular sieve catalysts, etc., can solve the problems of high temperature requirements, failure to meet temperature requirements, and inability to meet nitrogen oxide emission reduction requirements. Cost, improvement of adsorption capacity, effect of low temperature, efficient and fast adsorption storage

Inactive Publication Date: 2019-09-06
安徽纳蓝环保科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the upcoming National VI emission standards will greatly reduce the NOx emission concentration. The traditional SCR catalytic reduction of NOx has a high temperature requirement, which can no longer meet the NOx emission treatment during the engine cold start stage, resulting in excessive NOx emission during the cold start stage of motor vehicles.
[0004] Existing technologies for treating NOx in exhaust exhaust from motor vehicles are no longer suitable for the National VI standards, because the temperature requirements for SCR catalytic reduction of NOx (generally not lower than 200°C) cannot be met during the cold start stage of the motor vehicle engine, so the SCR catalyst is lower than 200°C. At ℃, it does not have a catalytic reduction effect on NOx, so it cannot meet the emission reduction requirements of the National VI standard for nitrogen oxides (NOx).

Method used

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  • Preparation method of NOx adsorbing material with HC catalytic oxidation function
  • Preparation method of NOx adsorbing material with HC catalytic oxidation function
  • Preparation method of NOx adsorbing material with HC catalytic oxidation function

Examples

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Effect test

Embodiment 1

[0033] A kind of preparation method that the present invention proposes has the NOx adsorption material of HC catalytic oxidation function, comprises the following steps:

[0034] S1. Molecular sieve pretreatment: roasting the zeolite molecular sieve at constant temperature, cooling, adding ammonium salt solution, stirring, washing, and drying to obtain ammonium-type zeolite molecular sieve;

[0035] S2, load precious metal: silver nitrate solution, palladium nitrate solution and distilled water are mixed, stir, then join in the ammonium type zeolite molecular sieve, stir, leave standstill, dry, obtain NOx adsorbent precursor;

[0036] S3. Roasting: roasting the NOx adsorbent precursor at a constant temperature to obtain a fresh NOx adsorbent;

[0037] S4. Hydrothermal aging: the fresh state NOx adsorbent undergoes hydrothermal aging treatment to obtain NOx adsorbent material with HC catalytic oxidation function.

Embodiment 2

[0039] A kind of preparation method that the present invention proposes has the NOx adsorption material of HC catalytic oxidation function, comprises the following steps:

[0040] S1. Molecular sieve pretreatment: Introduce air at a flow rate of 60ml / min, roast the Na-type zeolite molecular sieve at 530°C for 13h at a constant temperature, cool, add ammonium nitrate solution with a concentration of 0.5mol / L, stir in a water bath at 75°C for 21h, pump filter, then wash with distilled water, and then dry at 85°C to obtain an ammonium-type zeolite molecular sieve; wherein, the zeolite molecular sieve has a CHA-type framework structure, and the Si / Al molar ratio in the zeolite molecular sieve is 14;

[0041] S2. Mix silver nitrate solution, palladium nitrate solution and distilled water, stir, then dropwise add to ammonium-type zeolite molecular sieve, stir while adding dropwise, let stand at room temperature for 18h, and then dry at 115°C for 22h to obtain NOx adsorbent precursor ...

Embodiment 3

[0045] A kind of preparation method that the present invention proposes has the NOx adsorption material of HC catalytic oxidation function, comprises the following steps:

[0046]S1. Molecular sieve pretreatment: Introduce air at a flow rate of 70ml / min, roast the Na-type zeolite molecular sieve at a constant temperature of 550°C for 12h, cool, add ammonium nitrate solution with a concentration of 2.0mol / L, stir in a water bath at 80°C for 20h, pump filter, then wash with distilled water, and then dry at 80°C to obtain an ammonium-type zeolite molecular sieve; wherein, the zeolite molecular sieve has a CHA-type framework structure, and the Si / Al molar ratio in the zeolite molecular sieve is 14.5;

[0047] S2. Mix silver nitrate solution, palladium nitrate solution and distilled water, stir, then dropwise add to ammonium-type zeolite molecular sieve, stir while adding dropwise, let stand at room temperature for 20h, and then dry at 105°C for 24h to obtain NOx adsorbent precursor...

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Abstract

The invention discloses a preparation method of a NOx adsorbing material with an HC catalytic oxidation function. The method comprises the following steps of S1, molecular sieve pretreatment; S2, loading with precious metal; S3, roasting; S4, hydrothermal aging. The provided preparation method of the NOx adsorbing material with the HC catalytic oxidation function has the advantages that the obtained NOx adsorbing material has the functions of efficiently adsorbing and storing NOx at a low temperature and thermally desorbing the NOx at a high temperature, and also has a certain function catalytic oxidation function on the hydrocarbons.

Description

technical field [0001] The invention relates to the technical field of adsorption materials, in particular to a preparation method of a NOx adsorption material with HC catalytic oxidation function. Background technique [0002] As emissions regulations become more stringent, fuel efficiency increases, and engine exhaust temperatures decrease, engine cold-start emissions will become more difficult. [0003] During the implementation of China V emission standards for motor vehicles, SCR catalysts are usually used to reduce NOx to N 2 To achieve up-to-standard emission of motor vehicle exhaust. However, the upcoming National VI emission standards have greatly reduced the NOx emission concentration. The traditional SCR catalytic reduction of NOx has a high temperature requirement, which can no longer meet the NOx emission treatment during the cold start stage of the engine, resulting in excessive NOx emission during the cold start stage of motor vehicles. [0004] Existing tec...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/18B01J20/30B01J29/74B01D53/94B01D53/56B01D53/72
CPCB01D53/94B01D53/9413B01D2251/2062B01D2255/1023B01D2255/104B01D2255/50B01D2257/40B01D2257/404B01D2257/702B01J20/0233B01J20/0296B01J20/186B01J29/74B01J29/743B01J2220/42B01J2220/4806
Inventor 李超代瑞旗王治龙赵长艳田炜
Owner 安徽纳蓝环保科技有限公司
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