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Nay molecular sieve with regular meso-micropores and preparation method thereof

A molecular sieve and mesopore technology, applied in the field of molecular sieves, can solve problems affecting the synthesis of Y molecular sieves, affecting the formation of micropores and mesopores, etc.

Active Publication Date: 2020-10-27
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, if it is used in the hydrothermal synthesis of Y molecular sieve, it is easy to produce P-type heterocrystals, which affects the synthesis of Y molecular sieve, and then affects the formation of micropores and mesopores.

Method used

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  • Nay molecular sieve with regular meso-micropores and preparation method thereof
  • Nay molecular sieve with regular meso-micropores and preparation method thereof
  • Nay molecular sieve with regular meso-micropores and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0062] With 25.20g high alkali sodium metaaluminate solution (Sinopec Catalyst Changling Branch Company provides, Al 2 o 3 The content is 40.2g / L, Na 2 O content is 255g / L, specific gravity is 1.324) joins 32.78g water glass (Sinopec Catalyst Changling Branch provides, SiO 2 The content is 260.6g / L, Na 2 The O content is 81.6g / L, the specific gravity is 1.2655, and the modulus is 3.3), and the molar composition is 15Na 2 O: A1 2 o 3 :15SiO2 2 The first mixture was aged under dynamic stirring at room temperature for 48 hours, then stood and aged at 60°C for 5 hours, and finally added 7.5 g of deionized water under stirring conditions to obtain a final molar composition of 15Na 2 O: A1 2 o 3 :15SiO2 2 :320H 2 The second mixture of O is the directing agent.

[0063] Under the conditions of room temperature and high-speed stirring, follow the guide agent (prepared in the preceding steps), 84.13g water glass (same as above), 6.71g low-alkali sodium metaaluminate solution...

Embodiment 2

[0067] With 25.20g high alkali sodium metaaluminate solution (Sinopec Catalyst Changling Branch Company provides, Al 2 o 3 The content is 40.2g / L, Na 2 O content is 255g / L, specific gravity is 1.324) joins 32.78g water glass (Sinopec Catalyst Changling Branch provides, SiO 2 The content is 260.6g / L, Na 2 The O content is 81.6g / L, the specific gravity is 1.2655, and the modulus is 3.3), and the molar composition is 15Na 2 O: A1 2 o 3 :15SiO2 2 The first mixture was aged under dynamic stirring at 60°C for 5 hours, then stood and aged at 60°C for 5 hours, and finally added 7.5g of deionized water under stirring conditions to obtain the final molar composition: 15Na 2 O: A1 2 o 3 :15SiO2 2 :320H 2 The second mixture of O is the directing agent.

[0068] Under the conditions of room temperature and high-speed stirring, follow the guide agent (prepared in the preceding steps), 84.13g water glass (same as above), 6.71g low-alkali sodium metaaluminate solution (provided by...

Embodiment 3

[0072]82.27g high alkali sodium metaaluminate solution (provided by Sinopec Catalyst Changling Branch, Al 2 o 3 The content is 40.2g / L, Na 2 O content is 340g / L, specific gravity is 1.297) joins 145.68g water glass (Sinopec Catalyst Changling Branch provides, SiO 2 The content is 260.6g / L, Na 2 The O content is 81.6g / L, the specific gravity is 1.2655, and the modulus is 3.3), and the molar composition is 20Na 2 O: A1 2 o 3 :20SiO2 2 The first mixture was aged under dynamic stirring at 30°C for 20 hours, then stood and aged at 40°C for 15 hours, and finally added 30g of deionized water under stirring to obtain a final molar composition of 20Na 2 O: A1 2 o 3 :20SiO2 2 :380H 2 The second mixture of O is the directing agent.

[0073] Under the conditions of room temperature and high-speed stirring, according to the guide agent (prepared in the preceding steps), 54.63g water glass (same as above), 8.32 low alkali sodium metaaluminate solution (provided by Sinopec Catalys...

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Abstract

The present invention relates to a NaY molecular sieve having regular mesopore-micropore, and a preparation method thereof, wherein the molar ratio of the skeleton SiO2 / Al2O3 of the NaY molecular sieve is 5.0-6.0, the specific surface area of the mircopore is 400-800 m<2> / g, the pore volume of the micropore is 0.25-0.4 cm<3> / g, the specific surface area of the mesopore is 30-200 m<2> / g, the pore volume of the mesopore is 0.07-0.85 cm<3> / g, and the pore size of the mesopore is 2.0-6.0 nm. According to the present invention, the mesopore is introduced while the micropore of the NaY molecular sieve is retained, and the mesopore and the micropore have connectivity so as to easily achieve the macromolecule diffusion.

Description

technical field [0001] The present disclosure relates to the field of molecular sieves, in particular to a NaY molecular sieve with regular meso-micropores and a preparation method thereof. Background technique [0002] In the late 1950s, Milton and Breck successfully synthesized Y-type molecular sieves. Due to the SiO in the structure of the Y-type molecular sieve 2 with Al 2 o 3 The ratio is greater than that of X-type molecular sieve, so that the thermal stability and hydrothermal stability are improved. In the early 1970s, Grace Company developed the directing agent method to synthesize NaY molecular sieves. The raw material was water glass instead of expensive silica sol. The process was simplified and the growth cycle was shortened, so that NaY molecular sieves were rapidly and widely used in petrochemical industries Petroleum cracking catalysis field. So far, among the hundreds of molecular sieves that have been developed, Y-type molecular sieve is the most widel...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01B39/24
CPCC01B39/24C01P2002/72C01P2004/03C01P2006/12C01P2006/14C01P2006/16
Inventor 付强慕旭宏李永祥张成喜胡合新舒兴田
Owner CHINA PETROLEUM & CHEM CORP
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