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Petroleum coke preparation method and production equipment

A production equipment and petroleum coke technology, applied in the field of petroleum coking, can solve the problems of high cost, toxic organic solvents, high energy consumption, etc., and achieve the effect of low sulfur content

Active Publication Date: 2021-08-31
SINOPEC LUOYANG TECH CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The high-temperature calcination method is to calcine petroleum coke at a high temperature of 1600 ° C. The desulfurization rate exceeds 50%, but the energy consumption is large
The wet chemical oxidation method is to convert the water-insoluble organic sulfur in petroleum coke into water- or acid-soluble inorganic sulfur by chemical reagent oxidation to achieve the purpose of desulfurization, but this method will generate a large amount of waste water
Medium gas desulfurization refers to placing petroleum coke in the desulfurization medium gas at a constant temperature for a period of time, so that the sulfur in the petroleum coke interacts with the medium gas to achieve the purpose of desulfurization, but this method consumes a lot of energy and is dangerous
Solvent extraction method is to use organic solvent extraction method to extract the sulfur in petroleum coke into the solvent, so as to achieve the purpose of desulfurization, but the desulfurization rate of this method is low, and most of the organic solvents are toxic, flammable and explosive, and the cost is high
From the above analysis, it can be seen that using petroleum coke as a raw material to directly desulfurize petroleum coke is difficult and costly, and the effect is limited

Method used

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  • Petroleum coke preparation method and production equipment
  • Petroleum coke preparation method and production equipment
  • Petroleum coke preparation method and production equipment

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preparation example Construction

[0057] On the other hand, the present invention provides a kind of preparation method of petroleum coke, comprises the following steps:

[0058] The desulfurized residual oil obtained according to the above residual oil desulfurization method is subjected to coking treatment to obtain petroleum coke.

[0059] The preparation method of petroleum coke provided by the present invention starts from the raw material of petroleum coke, and the raw material residue oil used is the residue oil with low sulfur content after pretreatment and electrostatic coalescence adsorption to remove sulfur-containing compounds. Petroleum coke with low sulfur content is prepared from the residual oil, which provides a new idea for the preparation of low sulfur petroleum coke. Compared with the reprocessing desulfurization of traditional high-sulfur petroleum coke, the preparation method significantly reduces energy consumption, has a simple process, is easy to operate, can realize continuous product...

Embodiment 1

[0065] This embodiment is a preparation method of petroleum coke, the process flow diagram is as follows figure 2 shown, including the following steps:

[0066] S1) Pretreatment: Residual oil and sodium hydroxide are mixed in a pretreatment tank at a mass ratio of 90:10 for reaction, the reaction temperature is 350°C, and the reaction time is 1.5h;

[0067] S2) Electrostatic adsorption: the residual oil after the pretreatment reaction is cooled to 300°C by heat exchange, and then enters an electrostatic treatment tank with a DC electric field strength of 5000V / cm for desulfurization treatment;

[0068] S3) Coking reaction: the residual oil after desulfurization treatment is heated up to 490° C. through heat exchange, and then enters the coke tower for coking reaction. The coking reaction time is 4 hours, and petroleum coke with low sulfur content is obtained after the reaction.

Embodiment 2

[0070] Present embodiment is a kind of preparation method of petroleum coke, comprises the following steps:

[0071] S1) Pretreatment: Residual oil and sodium hydroxide are mixed in a pretreatment tank at a mass ratio of 99:1 for reaction, the reaction temperature is 350°C, and the reaction time is 1.5h;

[0072] S2) Electrostatic adsorption: the residual oil after the pretreatment reaction is heated to 150°C and then enters an electrostatic treatment tank with a DC electric field strength of 1500V / cm for desulfurization treatment;

[0073] S3) Coking reaction: the residual oil after desulfurization treatment is heated up to 490° C. through heat exchange, and then enters the coke tower for coking reaction. The coking reaction time is 4 hours, and petroleum coke with low sulfur content is obtained after the reaction.

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Abstract

The invention provides a residual oil desulfurization method, a petroleum coke preparation method and production equipment, and relates to the technical field of petroleum coking. The residual oil desulfurization method comprises the following steps: S1) providing residual oil as a reaction raw material, and combining the residual oil with the pre- Mixing the treatment agent to pretreat the residual oil; wherein, the pretreatment agent includes metal alkali and / or metal carbonate; S2) placing the pretreatment mixture obtained in step S1) in an electrostatic field for electrostatic adsorption desulfurization treatment, and then completing Desulfurization of residual oil to obtain residual oil with low sulfur content. The residual oil desulfurization method can alleviate the technical problems of high process difficulty, high cost and poor desulfurization effect in desulfurization of petroleum coke in the prior art, and desulfurization from raw materials can reduce the difficulty of desulfurization and improve the desulfurization effect.

Description

technical field [0001] The invention relates to the technical field of petroleum coking, in particular to a residual oil desulfurization method, a petroleum coke preparation method and production equipment. Background technique [0002] Petroleum coke is a kind of coke made from residual oil through delayed coking. At present, most of my country's petroleum coke products are high-sulfur petroleum coke (sulfur content is higher than 3%). The use of high-sulfur petroleum coke will not only cause corrosion of equipment, increase the production cost of enterprises, but also cause serious pollution to the environment. With the country's emphasis on environmental protection in recent years and the gradual upgrading of environmental protection levels, the demand for high-quality low-sulfur petroleum coke will increase in the future, so it is imperative to reduce the sulfur content in petroleum coke. [0003] At present, in order to obtain low-sulfur petroleum coke, high-sulfur pe...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G53/02C10G55/04C10B55/00
CPCC10B55/00C10G53/02C10G55/04C10G2300/107C10G2300/1077C10G2300/202
Inventor 于珊珊崔新安王洪彬
Owner SINOPEC LUOYANG TECH CO LTD
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