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Inorganic phase-change energy storing particles, floor heating mortar and preparation method thereof

A technology of inorganic phase change and inorganic phase change materials, which is applied in the field of floor heating mortar and its preparation, and inorganic phase change energy storage particles, can solve the problems of building material performance change, wall damage, phase separation, etc. The effect of preventing loss, avoiding flow and leakage

Active Publication Date: 2018-10-16
SOUTHWEAT UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

These types of materials have the advantages of suitable phase change temperature, high latent heat of phase change, non-combustibility, and low price. However, due to the phase change during the phase change process, they become liquid phases, phase separation occurs, and leakage occurs. It causes changes in the properties of building materials, precipitates white hairy crystalline salts, and damages the wall surface. Therefore, in order to prevent leakage, it needs to be coated to solve the technical problem of phase separation. However, no coated inorganic energy storage has been seen so far. Particles reported in the literature

Method used

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  • Inorganic phase-change energy storing particles, floor heating mortar and preparation method thereof
  • Inorganic phase-change energy storing particles, floor heating mortar and preparation method thereof
  • Inorganic phase-change energy storing particles, floor heating mortar and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0045] A method for preparing inorganic phase change energy storage particles and floor heating mortar, comprising the following steps:

[0046] 1. Preparation of phosphated starch glue:

[0047] A, the mass percent composition of this esterified starch glue comprises: 1.3% sodium dihydrogen phosphate, 9.0% starch, 79.3% water (comprising 7% in the first step of the preparation process and 72.3% in the third step ); 10.4% mass percent concentration is 20% NaOH aqueous solution (including 1‰ in the first step of the preparation process and 10.3% in the third step)

[0048] b. Preparation process:

[0049] The first step: esterification synthesis: add water to sodium dihydrogen phosphate, stir to dissolve, adjust the pH value to 5.5 with NaOH aqueous solution with a concentration of 20% by mass percentage, add starch, fully stir and disperse to make starch slurry, at 65 Heating and reacting at ℃ for 20 minutes to obtain esterified starch mixed slurry;

[0050] The second step...

Embodiment 2~8

[0064] It is mainly aimed at changing the dosage of sodium sulfate decahydrate, gypsum and cement in the preparation process of inorganic phase change energy storage particles, while the dosage of water-absorbing resin, phosphated starch glue and water remains unchanged.

[0065] 1. Preparation of phosphated starch glue:

[0066] A, the mass percentage composition of this phosphated starch glue is consistent with embodiment 1;

[0067] B, preparation procedure: the preparation procedure of this phosphated starch glue is consistent with embodiment 1;

[0068] 2. Preparation of inorganic phase change energy storage particles:

[0069] A, the component and the mass percentage example of batching in each embodiment are shown in Table 1;

[0070] b. Mixing, granulation and coating:

[0071]Mix sodium sulfate decahydrate with water, stir to dissolve part of sodium sulfate decahydrate, add phosphated starch glue, stir and disperse evenly, add water-absorbing resin after dispersion...

Embodiment 9~14

[0081] It is mainly aimed at changing the amount of water, water-absorbing resin, phosphated starch glue, gypsum and cement in the preparation process of inorganic phase change energy storage particles, while the amount of sodium sulfate decahydrate is fixed.

[0082] 1. Preparation of phosphated starch glue:

[0083] A, the mass percentage composition of this phosphated starch glue is consistent with embodiment 1;

[0084] B, preparation procedure: this phosphated starch glue preparation procedure is consistent with embodiment 1;

[0085] 2. Preparation of inorganic phase change energy storage particles:

[0086] A, the component and the mass percent example of batching in each embodiment are shown in Table 2;

[0087] B, mixing, granulation and coating: consistent with embodiment 1;

[0088] Table 2: Component and mass percentage of batching in each embodiment:

[0089]

[0090]

[0091] c. Envelope:

[0092] Its coating process is consistent with embodiment 1;

...

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Abstract

The invention provides inorganic phase-change energy storing particles, floor heating mortar and a preparation method thereof. The inorganic phase-change energy storing particles comprise the following components in percentage by mass: 20-50% of inorganic phase-change material, 10-25% of water, 0.1-1.5% of phosphorylated starch gum, 0.1-1.5% of water-absorbent resin, 10-35% of gypsum, and 15-35% of cement. The inorganic phase-change energy storing particles are prepared by the steps of preparing phosphorylated starch gum, preparing materials, mixing, pelletizing, coating, and covering with films. The floor heating mortar comprises 15-35% of cement, 10-25% of sand, 20-50% of inorganic phase-change energy storing particles, and 20-30% of water. The floor heating mortar is prepared by preparing materials, and mixing. According to the inorganic phase-change energy storing particles, the floor heating mortar and the preparation method thereof, the raw materials are wide in source; the chemical stability is high; the phase change temperature is low; leakage is avoided; the energy storing particles are good in energy storing effect, and high in stability; the floor heating mortar is highin strength, and the indoor temperature can be effectively conditioned, and the energy saving effect is good; and various buildings such as a house, a school and a hospital widely apply.

Description

technical field [0001] The invention belongs to phase change energy storage particles, floor heating mortar and preparation thereof, and relates to inorganic phase change energy storage particles, floor heating mortar and a preparation method thereof. The phase transition temperature of the energy storage particles of the invention is suitable for floor heating mortar, with good energy storage performance and no leakage after multiple cycles. The obtained floor heating mortar has high strength and good construction performance, and can be widely used in various buildings such as residences, schools, hospitals, etc. . Background technique [0002] With the development of industrial economy, the problems of energy crisis and environmental degradation have been aggravated, and more and more attention has been paid to improving energy efficiency. Thermal energy storage technology is very important for improving energy efficiency. [0003] Among many energy storage technologies,...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B24/38C04B28/02
CPCC04B28/02C04B40/0039C04B2111/00482C04B2111/00017C04B2103/0071C04B22/16C04B24/38C04B22/062C04B22/147C04B22/143C04B7/00C04B24/24C04B14/06
Inventor 邓跃全董发勤李光华郭李琴李霞胡豪王姚
Owner SOUTHWEAT UNIV OF SCI & TECH
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