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Surface treatment method for ABS plastic electroplating

A ABS plastic and surface treatment technology, which is applied in the surface treatment field of ABS plastic electroplating, can solve the problems of non-wear resistance, high price, non-pollution resistance, etc., achieve excellent conductivity and gloss, shorten the process flow and cost, and facilitate The effect of recycling

Active Publication Date: 2018-08-21
HUAQIAO UNIVERSITY +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, plastics also have certain disadvantages: non-conductive, non-thermal, non-wear-resistant, easy to deform, not resistant to pollution, lack of metallic luster and aesthetics, etc., thus limiting its application range to a certain extent
Although this process method avoids surface roughening, activation and other processes, and reduces the use of chromic acid, hydrochloric acid, etc., the steps are still too cumbersome, because the conductive black coating is easy to agglomerate, and its conductivity is far inferior to that of graphene materials. First, the carbon black particles are oxidized and loaded with metal nanoparticles. This process requires the use of expensive noble metal salts and insulating dispersive wetting agents, so that the cost cannot be optimally controlled, and the conductivity of the coating will also decrease. In addition, the process method described in the patent is to prepare the modified conductive carbon black into a slurry, and then coat the polymer adhesive on the surface of the ABS plastic, and then blacken the conductive carbon black. The slurry is sprayed on the surface of ABS plastic, and the polymer adhesive used only plays the role of double-sided tape, and the bonding force cannot be guaranteed, so that no chemical bond or physical riveting is formed between the coating and the plastic substrate, which will affect the entire Coating force and uniformity

Method used

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  • Surface treatment method for ABS plastic electroplating
  • Surface treatment method for ABS plastic electroplating
  • Surface treatment method for ABS plastic electroplating

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] like figure 1 Shown in b, the surface treatment method for ABS plastic electroplating of the present invention comprises the steps:

[0043] (1) Prepare degreasing lye, the original such as figure 2 The ABS product shown in a is soaked in the degreasing lye for constant temperature water bath treatment. The constant temperature is 70°C, and the degreasing treatment time is 30 minutes. After that, the lye on the surface of the ABS product is cleaned with distilled water and dried to obtain degreasing ABS. Product spare;

[0044] (2) Measure 200mL THF and 100mL H 2 O, weigh 1.5g GO (graphene oxide, prepared by the Hummers method, the sheet diameter is 1.3~150um, such as figure 2 As shown in b), the three are mixed and ultrasonically dissolved, and the solvent is THF:H 2 O=2:1, GO concentration is the graphene oxide preplating solution of 5mg / mL, such as image 3 as shown in a;

[0045] (3) Soak the above-mentioned degreasing ABS product in the above-mentioned grap...

Embodiment 2

[0048] like figure 1 Shown in b, the surface treatment method for ABS plastic electroplating of the present invention comprises the steps:

[0049] (1) Prepare degreasing lye, the original such as figure 2 The ABS product shown in a is soaked in the degreasing lye for constant temperature water bath treatment. The constant temperature is 70°C, and the degreasing treatment time is 30 minutes. After that, the lye on the surface of the ABS product is cleaned with distilled water and dried to obtain degreasing ABS. Product spare;

[0050] (2) Measure 400mL THF and 100mL H 2 O, weigh 2.5g GO (graphene oxide, prepared by the Hummers method, sheet diameter is 1.3 ~ 150um), mix the three and carry out ultrasonication and dissolution, and prepare the solvent as THF:H 2 O=4:1, GO concentration is the graphene oxide preplating solution of 5mg / mL, such as image 3 as shown in b;

[0051] (3) Soak the above-mentioned degreasing ABS product in the above-mentioned graphene oxide pre-pl...

Embodiment 3

[0054] like figure 1 Shown in b, the surface treatment method for ABS plastic electroplating of the present invention comprises the steps:

[0055] (1) Prepare degreasing lye, the original such as figure 2 The ABS product shown in a is soaked in the degreasing lye for constant temperature water bath treatment. The constant temperature is 70°C, and the degreasing treatment time is 30 minutes. After that, the lye on the surface of the ABS product is cleaned with distilled water and dried to obtain degreasing ABS. Product spare;

[0056] (2) Measure 200mL THF, 50mL cyclohexanone and 50mL H 2 O, weigh 1.5g GO (graphene oxide, prepared by the Hummers method, sheet diameter is 1.3 ~ 150um), mix the four and carry out ultrasonication and dissolution, and prepare the solvent as THF: cyclohexanone: H 2 O=4:1:1, GO concentration is the graphene oxide preplating solution of 5mg / mL, as image 3 as shown in c;

[0057](3) Soak the above-mentioned degreasing ABS product in the above-m...

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Abstract

The invention discloses a surface treatment method for ABS plastic electroplating. A one-step swelling-coating graphene oxide secondary-reduction process is adopted; a uniform and continuous conductive layer is directly formed on the surface of an ABS product; the using of heavy metal salts and precious metals is avoided, the technical process and cost are largely reduced; the surface treatment method is simple and efficient and is easy to perform; the operability is high, the cost is low, and the surface treatment method is suitable for industrial large-scale production and application and has an important application value.

Description

technical field [0001] The invention belongs to the technical fields of graphene technology and plastic surface treatment, and in particular relates to a surface treatment method for ABS plastic electroplating. Background technique [0002] In recent years, with the advancement of science and technology and the continuous emergence of new materials, non-metallic materials such as plastics, glass, ceramics, and gypsum have been more and more widely used in industry and daily life. Many products that were previously made of metal have now been replaced. These are replaced by products such as plastics, which greatly reduce the weight and cost of products. However, plastics also have certain disadvantages: non-conductive, non-thermal, non-wearable, easy to deform, not resistant to pollution, lack of metallic luster and aesthetics, etc., which limits its application range to a certain extent. If a layer of metal is coated on the plastic surface, it is possible to make up for its...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C25D5/56
CPCC25D5/56
Inventor 陈国华许传凯肖平生刘飞翔刘泉根
Owner HUAQIAO UNIVERSITY
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