Mirabilite gypsum capable of being used as cement retarder

A cement retarder and Glauber's salt technology, which is applied in the field of comprehensive utilization of Glauber's salt tailings, can solve problems such as unstable cement performance and unstable Glauber's salt gypsum content, so as to reduce mining, prolong the service life of development and utilization, and improve enterprise economics benefit effect

Inactive Publication Date: 2018-08-03
SICHUAN TONGQING NANFENG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The patent pointed out that the prepared dihydrate gypsum can be provided to cement production customers, reducing the dependence of cement production enterprises on natural gypsum. However, at present, there is no mature mirabilite gypsum product as a cement retarder. Unstable, resulting in unstable performance of the cement produced when it is used as a cement retarder

Method used

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  • Mirabilite gypsum capable of being used as cement retarder
  • Mirabilite gypsum capable of being used as cement retarder
  • Mirabilite gypsum capable of being used as cement retarder

Examples

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Effect test

Embodiment 1

[0020] A kind of Glauberite gypsum that can be used as a cement retarder. Glauberite ore powder with a particle size of less than 10mm is obtained by crushing and ball milling Glauberite ore, and then mixing it with water to form a slurry, and then leaching the slurry, and finally solidifying Liquid separation to obtain Glauber's salt gypsum with a particle size of less than 400mm, said Glauber's salt gypsum includes the following chemical components in weight percentage: 16.05% SiO 2 , 3.56%Al 2 o 3 , 2.45% Fe 2 o 3 , 23.62% CaO, 3.12% MgO, 0.22% P 2 o 5 , 25.09%SO 3 , 0.58%K 2 O, 0.63% Na 2 O; among them, the attached water is 12.1%, the crystal water is 12.58%, and the alkalinity is 1.01%, and the alkalinity is 0.658K 2 O and Na 2 Total amount of O.

Embodiment 2

[0022] The only difference between this embodiment and Example 1 is that the prepared Glauber's salt gypsum includes the following chemical composition in weight percentage: 11.69% SiO 2 , 3.89%Al 2 o 3 , 1.58% Fe 2 o 3 , 23.87% CaO, 2.15% MgO, 0.25% P 2 o 5 , 33.32%SO 3 , 0.56%K 2 O, 0.43% Na 2 O; Wherein, the attached water is 10.01%, the crystal water is 12.25%, and the alkalinity is 0.80%, and the alkalinity is 0.658K 2 O and Na 2 Total amount of O.

Embodiment 3

[0024] The difference between this example and Example 1 is that the prepared Glauber's salt gypsum includes the following chemical composition in weight percentage: 5.68% SiO 2 , 1.65%Al 2 o 3 , 0.58% Fe 2 o 3, 28.63% CaO, 1.39% MgO, 0.23% P 2 o 5 , 40.30%SO 3 , 0.64K 2 O, 0.54Na 2 O; among them, the attached water is 7.62%, the crystal water is 12.74%, and the alkalinity is 0.96%, and the alkalinity is 0.658K 2 O and Na 2 Total amount of O.

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Abstract

The invention discloses mirabilite gypsum capable of being used as a cement retarder. The mirabilite gypsum is prepared from the following chemical ingredients in percentage by weight: 5 to 18 percentof SiO2, 1.4 to 5.2 percent of Al2O3, 0.5 to 3.0 percent of Fe2O3, 15 to 35 percent of CaO, 0.5 to 3.5 percent of MgO, 0.2 to 0.35 percent of P2O5 and 25 to 43 percent of SO3, wherein the attached water content is less than or equal to 16 percent, the crystal water content is higher than or equal to 8 percent, and the alkalinity is 0.5 to 1.6 percent. The cement prepared by using the mirabilite gypsum as the cement retarder has qualified stability; the cement intensity is identical to the intensity of cement prepared from natural gypsum and ardealite; the initial setting time and the final setting time are shortened by one hour or above through being compared with that of the ardealite; the natural gypsum and the ardealite can be replaced; the relying degree of the cement production enterprise on the natural gypsum is reduced; in addition, the condensing time is normal; the modification treatment like the ardealite is not needed; the cost is reduced; the economic benefits are improved.

Description

technical field [0001] The invention belongs to the technical field of comprehensive utilization of glauberite tailings, and in particular relates to a kind of mirabilite gypsum which can be used as a cement retarder. Background technique [0002] Glauber's salt mineral resources widely exist in nature, and the reserves are extremely rich. It is known that more than 30 countries in the world have mineral resources of thenardite. By the end of 1996, China had proven 124 mirabilite mineral deposits, including 62 sites with reserves of 22.112 billion tons and Na 2 SO 4 A total of 62 places have reserves of 10.532 billion tons, and the total resources reach 30 billion tons (Na 2 SO 4 volume), the potential value of resources is 1,776 billion yuan. The provinces (regions) with the most abundant thenardite ore reserves in China are mainly Qinghai, Sichuan, Inner Mongolia, Yunnan, Xinjiang, Hubei and Hunan. [0003] The two main components of glauberite ore are sodium sulfate ...

Claims

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Application Information

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IPC IPC(8): C04B22/14C04B103/22
CPCC04B22/143C04B2103/22
Inventor 彭诗谷
Owner SICHUAN TONGQING NANFENG
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