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Modified calcium oxide expansion agent with controllable expansion process and preparation method thereof

A calcium oxide and expansion agent technology, applied in the field of building materials, can solve the problems of consumption, inability to form effective expansion, reduction, etc., achieve obvious technical and economic advantages, reduce expansion energy loss, and simple mixing method

Active Publication Date: 2020-07-24
NANJING HYDRAULIC RES INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0022] Aiming at the problem that the early hydration reaction of calcium oxide expansion agents is too rapid, and a large amount of expansion energy is consumed in the plastic stage of concrete and cannot form effective expansion, the present invention proposes a modified calcium oxide expansion agent for concrete with a controllable expansion process and its The preparation method can effectively control the expansion process of the calcium oxide expansion agent, increase the expansion energy reserve in the hardening stage of the concrete, and can better reduce or offset the unfavorable shrinkage deformation of the concrete

Method used

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  • Modified calcium oxide expansion agent with controllable expansion process and preparation method thereof
  • Modified calcium oxide expansion agent with controllable expansion process and preparation method thereof
  • Modified calcium oxide expansion agent with controllable expansion process and preparation method thereof

Examples

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Effect test

Embodiment 1

[0052] Limestone with a mass ratio of 90:10 is mixed with mineral fillers and ground together by a ball mill until the specific surface area is 250m 2 / kg of raw meal powder, where the mineral fillers are gypsum, alumina and aluminum sulfate (mass ratio is 80:10:10). The ground raw meal was calcined at 1280°C for 150min, then the sample was taken out and immediately quenched in the air, and ground to a specific surface area of ​​300m 2 / kg to obtain calcium oxide clinker. As the benchmark group of unmodified calcium oxide clinker, the number is 1.

Embodiment 2

[0054] Dissolve rosin resin acid and absolute ethanol at a mass ratio of 1:50, and stir until uniform. Control the mixing mass ratio of calcium oxide clinker and rosin resin acid to be 990:8, mix the calcium oxide clinker prepared in Example 1 with the rosin resin acid dissolved in ethanol until uniform (stir for about 5min), then Dry at ℃ for about 3 hours, remove the absolute ethanol, and grind the obtained solid until the specific surface area is 300m 2 / kg. The number is 2 as the comparison group of single rosin resin acid coating modification.

Embodiment 3

[0056] The calcium oxide clinker prepared in Example 1 is directly mixed with boric acid (powder) in a mass ratio of 990:2. As a comparison group representing the modification of the compound coagulation adjustment component, the number is 3.

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Abstract

The invention discloses a modified calcium oxide type expanding agent with a controllable expansion course and a preparation method thereof. The specific surface area of the modified calcium oxide type expanding agent is 300m<2> / kg to 500m<2> / kg; the modified calcium oxide type expanding agent is prepared by coating calcium oxide clinker with rosin resin acid and uniformly mixing the calcium oxideclinker with a coagulation regulation component; the mass ratio of the calcium oxide clinker to the rosin resin acid to the coagulation regulation component is (990 to 996) to (2 to 8) to 2. When themodified calcium oxide type expanding agent is applied, the expansion course of the calcium oxide type expanding agent can be remarkably regulated and expansion energy loss of the calcium oxide typeexpanding agent at a concrete plastic stage is reduced; more beneficial expansion is generated in a concrete hardening process and a shrinkage compensating effect of the calcium oxide type expanding agent is efficiently expressed.

Description

technical field [0001] The invention belongs to the field of building materials, in particular to a modified calcium oxide expansion agent with controllable expansion history and a preparation method thereof. Background technique [0002] Concrete cracking often shortens the service life of engineering structures, reduces the safety of structures, and seriously threatens people's lives and property safety. Concrete self-shrinkage, drying shrinkage, temperature shrinkage and other shrinkage deformations will form tensile stress under constraint conditions, which is an important cause of cracking. In order to improve the crack resistance of concrete, an expansive agent can be added to the concrete to produce expansion deformation, reduce or offset the unfavorable shrinkage deformation, that is, to compensate for shrinkage. At present, this shrinkage compensation technology has been widely used in waterproof concrete and thin-walled structural concrete. [0003] Calcium oxide...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B24/34
CPCC04B40/0039C04B24/34C04B22/082C04B22/06C04B22/148
Inventor 王子龙宁逢伟白银丁建彤蔡跃波陈波张丰贾海磊
Owner NANJING HYDRAULIC RES INST
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