Special composite antibacterial coating and composite antibacterial agent for children bicycle and preparation method of composite antibacterial agent
A compound antibacterial agent and compound antibacterial technology are applied in the field of coatings to achieve the effects of good stability, stable performance, and harmless to human body and environment.
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Embodiment 1
[0029] (1) Weigh 100 parts of microcrystalline kaolinite powder and add 350 parts of deionized water to prepare mixed solution A; mix (1+1) hydrochloric acid, (1+1) sulfuric acid and (1+1) phosphoric acid according to 1 : Prepare a mixed acid solution with a pH of 5-6 at a ratio of 1:2; add the mixed solution A dropwise to the mixed acid solution at a rate of 5mL / min, heat to 50°C, and stir at a constant speed for 4 hours to obtain a mixed solution B;
[0030] (2) Add 100 parts of nano-titanium dioxide to the above mixed solution B, and after stirring at a constant speed for 5 hours at 60°C, add 0.007 parts of bromochlorohydantoin and 100 parts of dodecyl-dimethyl-benzyl chloride ammonium chloride, 50 parts of fluorosilane coupling agent, 30 parts of 2,6-di-tert-butyl-4-methylphenol and 10 parts of thiodiacrylate, heated to 80°C, stirred at a constant speed for 5 hours, and mixed Liquid C;
[0031] (3) Suction filter the above mixture C, discard the filtrate, wash the filter ...
Embodiment 2
[0033] (1) Weigh 200 parts of microcrystalline kaolinite powder and add 800 parts of deionized water to prepare a mixed solution A; mix (1+1) hydrochloric acid, (1+1) sulfuric acid and (1+1) phosphoric acid according to 1 : Prepare a mixed acid solution with a pH of 5-6 at a ratio of 1:3; add the mixed solution A dropwise to the mixed acid solution at a rate of 5 mL / min, heat to 70° C., and stir at a constant speed for 6 hours to obtain a mixed solution B;
[0034] (2) Add 200 parts of nano-zinc-loaded hydroxyapatite to the above mixture B, and after stirring at a constant speed for 8 hours at a temperature of 70°C, add 0.014 parts of bromochlorohydantoin and 150 parts of dodecyl-di Methyl-benzyl ammonium chloride, 80 parts of fluorosilane coupling agent, 50 parts of 2,6-di-tert-butyl-4-methylphenol and 20 parts of thiodiacrylate, heated to 90°C, Stir at a constant speed for 8 hours to obtain a mixed solution C;
[0035] (3) Suction filter the above mixture C, discard the fil...
Embodiment 3
[0037] (1) Weigh 150 parts of microcrystalline kaolinite powder and add 500 parts of deionized water to prepare a mixed solution A; mix (1+1) hydrochloric acid, (1+1) sulfuric acid and (1+1) phosphoric acid according to 1 : Prepare a mixed acid solution with a pH of 5-6 at a ratio of 1:2; add the mixed solution A dropwise to the mixed acid solution at a rate of 5 mL / min, heat to 60° C., and stir at a constant speed for 5 hours to obtain a mixed solution B;
[0038] (2) Add 150 parts of inorganic antibacterial agent to the above mixed solution B, and after stirring at a constant speed for 7 hours at 65°C, add 0.010 parts of bromochlorohydantoin and 130 parts of dodecyl-dimethyl-benzyl ammonium chloride, 60 parts of fluorosilane coupling agent, 40 parts of 2,6-di-tert-butyl-4-methylphenol and 15 parts of thiodiacrylate, the temperature was raised to 85 ° C, and stirred at a constant speed for 6 hours, Obtain mixed solution C;
[0039] (3) Suction filter the above mixture C, dis...
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