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Preparation method of a temperature-sensitive chelating gel concrete internal curing agent

An internal and curing agent technology for concrete, applied in the field of building material admixtures, can solve problems such as poor release performance, reduced concrete work performance, and can not meet construction requirements, etc. The effect of early cracking

Active Publication Date: 2019-04-05
GUIZHOU TIEJIANHENGFA NEW MATERIAL TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the water-absorbing resins on the market are generally synthesized from acrylic acid. This type of product has strong water absorption capacity, too fast water absorption rate, and poor water release performance. When used as an internal curing agent, it absorbs too much mixing water in the early stage, which significantly reduces the work of concrete. Performance, can not meet the actual construction requirements, thereby limiting the application of superabsorbent resin in the field of concrete admixture

Method used

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  • Preparation method of a temperature-sensitive chelating gel concrete internal curing agent
  • Preparation method of a temperature-sensitive chelating gel concrete internal curing agent
  • Preparation method of a temperature-sensitive chelating gel concrete internal curing agent

Examples

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Effect test

Embodiment 1

[0025] A preparation method of temperature-sensitive chelating gel concrete internal curing agent, comprising the following steps:

[0026] (1) Dissolve 36g of acrylic acid in 180g of distilled water, stir and mix evenly, add 20g of sodium hydroxide three times under the condition of ice water cooling to adjust the pH to neutral, add 12g of chelating functional monomer, 11g of propylene in sequence under stirring Stir the amide to dissolve completely, and then slowly add 12g of temperature-sensitive macromonomer several times under the action of strong stirring. For N,N-methylenebisacrylamide, continue to pass nitrogen gas for 30-60 minutes, seal, and keep the temperature at 20-50°C for 8-24h.

[0027] (2) Cut the product obtained above into pieces, then put it into an oven, and heat it at 85~90 o C Dry at constant temperature for 6~8h, crush the dried product with a pulverizer, and then sieve it with a sieve until the granular temperature-sensitive chelating gel concrete int...

Embodiment 2

[0030] A preparation method of temperature-sensitive chelating gel concrete internal curing agent, comprising the following steps:

[0031] (1) Dissolve 48g of sodium methacrylsulfonate in 180g of distilled water and stir to dissolve, then add 12g of chelating functional monomer and 19g of N-methacrylamide to dissolve completely under stirring, and then divide under strong stirring Slowly add 12g of temperature-sensitive macromonomer several times to dissolve completely, and then add 3g of potassium persulfate and 3g of sodium sulfite composite initiator, 3g of N,N-methylenebisacrylamide in sequence after passing nitrogen gas for 30 minutes, and continue Blow nitrogen for 30-60 minutes, seal, and keep the temperature at 20-50°C for 8-24h.

[0032] (2) Cut the product obtained above into pieces, then put it into an oven, and heat it at 85~90 o C Dry at constant temperature for 6~8h, crush the dried product with a pulverizer, and then sieve it with a sieve until the granular te...

Embodiment 3

[0034] Embodiment 3 A preparation method of temperature-sensitive chelating gel concrete internal curing agent, comprising the following steps:

[0035] (1) Dissolve 36g of 2-acrylamido-2-methylpropanesulfonic acid in 180g of distilled water, stir and mix evenly, add 7g of sodium hydroxide under ice water cooling condition to adjust the pH to neutral, then add Stir 12g of chelating functional monomer and 21g of acrylamide to completely dissolve, and then slowly add 12g of temperature-sensitive macromonomer several times under the action of strong stirring. Ammonium and 3g ascorbic acid composite initiator, 6g ethylene glycol bisacryloyl ester, continue to pass nitrogen gas for 30-60 minutes, seal, and keep the temperature at 20-50°C for 8-24h.

[0036] (2) Cut the product obtained above into pieces, then put it into an oven, and heat it at 85~90 o C Dry at constant temperature for 6~8h, crush the dried product with a pulverizer, and then sieve it with a sieve until the granul...

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Abstract

The invention discloses a method for preparing a temperature-sensitive chelating gel concrete internal curing agent. The method steps are as follows: raw materials are selected: 10-25 parts of temperature-sensitive macromolecular monomers, 5-15 parts of chelating functional monomers, 20~45 parts of nonionic monomer, 25~40 parts of anionic monomer, 1~10 parts of crosslinking agent, 1~10 parts of initiator, 10~25 parts of sodium hydroxide; stir and dissolve the anionic monomer and add hydrogen to oxidize Adjust the sodium to neutral, add the chelating functional monomer and non-ionic monomer in sequence and stir to dissolve, add the temperature-sensitive macromer while stirring, add the initiator and cross-linking agent in sequence after passing nitrogen for 30 minutes, and continue to pass nitrogen for 30‑ 60min, sealed, kept at 20-50°C for 8-24h; dried, pulverized, and sieved. The internal curing agent of the invention can adjust and control the release rate of water according to the temperature change in the cement hydration process, has moderate water absorption rate and low water absorption multiple, and can effectively improve the strength of concrete.

Description

technical field [0001] The invention belongs to the technical field of building material admixtures, and in particular relates to a preparation method of a temperature-sensitive chelating gel concrete internal curing agent. Background technique [0002] In recent years, with the continuous expansion of the scale of civil engineering and the continuous improvement of the level of science and technology, some important buildings with high-rise and long-span and special functional requirements have emerged continuously. The main trend, the use of low water-binder ratio, mineral admixtures, chemical admixtures, etc. are the main means to achieve the above properties. The rapid growth of lower water bands from shrinkage is the main cause of early cracking in high-strength concrete. In addition, due to the dense structure and low permeability of high-strength concrete and self-compacting concrete, conventional external water curing, continuous spraying, spraying curing agents, et...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08F290/04C08F220/06C08F220/36C08F220/56C08F220/34C08F220/54C08F220/20C08F220/58C04B40/04
CPCC04B40/04C08F290/046C08F220/585C08F220/36C08F220/34
Inventor 李本秀陈凯罗秀平陈娟刘先勇彭守军蒋天福
Owner GUIZHOU TIEJIANHENGFA NEW MATERIAL TECH CO LTD
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