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Vanadium extraction solvent impregnating resin, as well as preparation method and application thereof

A technology for impregnating resin and solvent, applied in the field of vanadium extraction solvent impregnating resin and its preparation, can solve the problems of long impregnation equilibrium time, low impregnation rate, low adsorption capacity, etc., so as to shorten the impregnation equilibrium time, improve the impregnation rate, and promote adsorption and in-depth effects

Active Publication Date: 2017-08-18
WUHAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The present invention aims to overcome the problems of long impregnation equilibrium time, low impregnation rate and low adsorption capacity when the vanadium extraction solvent impregnation resin is applied to the vanadium-containing solution in the existing preparation method of vanadium extraction solvent impregnation resin. The purpose is to develop a A new impregnation method with short impregnation equilibrium time and high impregnation rate can improve the adsorption capacity of vanadium extraction solvent impregnation resin when it is applied to the adsorption of vanadium-containing solution

Method used

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  • Vanadium extraction solvent impregnating resin, as well as preparation method and application thereof
  • Vanadium extraction solvent impregnating resin, as well as preparation method and application thereof
  • Vanadium extraction solvent impregnating resin, as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] An ultrasonic preparation method and application of vanadium-extracting solvent impregnated resin, the flow chart of its specific preparation scheme is as follows figure 1 Shown:

[0024] (1) Macroporous adsorption resin pretreatment

[0025] Take 20g of XAD-7HP macroporous adsorption resin (matrix is ​​acrylate), mix ethanol solution and macroporous adsorption resin with a liquid-solid ratio of 2:1mL / g and soak for 2 hours, then wash the soaked macroporous resin with 100-130mL deionized water Pore ​​adsorption resin, and then put the washed macroporous adsorption resin into a vacuum drying oven and dry at 50°C for 4 hours to obtain the pretreated macroporous adsorption resin;

[0026] (2) Preparation of organic extraction solvent

[0027] P204 is mixed with ethanol with a volume ratio of 3:7 to obtain an organic extraction solvent;

[0028] (3) Preparation of Vanadium Extraction Solvent Impregnated Resin

[0029] Get the pretreated macroporous adsorption resin that...

Embodiment 2

[0034] An ultrasonic preparation method and application of vanadium-extracting solvent impregnated resin, the flow chart of its specific preparation scheme is as follows figure 1 Shown:

[0035] (1) Macroporous adsorption resin pretreatment

[0036] Take 20g of XAD-4 macroporous adsorption resin (the matrix is ​​styrene-divinylbenzene copolymer), mix and soak the ethanol solution and macroporous adsorption resin at a liquid-solid ratio of 2.5:1mL / g for 4 hours, and then use 130-160mL to remove Wash the soaked macroporous adsorption resin with ion water, then put the washed macroporous adsorption resin into a vacuum drying oven and dry at 55°C for 5 hours to obtain the pretreated macroporous adsorption resin;

[0037] (2) Preparation of organic extraction solvent

[0038] Mix P507 and ethanol with a volume ratio of 2:5 to obtain an organic extraction solvent;

[0039] (3) Preparation of Vanadium Extraction Solvent Impregnated Resin

[0040] Get the pretreated macroporous ad...

Embodiment 3

[0045] An ultrasonic preparation method and application of vanadium-extracting solvent impregnated resin, the flow chart of its specific preparation scheme is as follows figure 1 Shown:

[0046] (1) Macroporous adsorption resin pretreatment

[0047] Take 20g of XAD-16HP macroporous adsorption resin (the matrix is ​​polyethylene-divinylbenzene copolymer), mix and soak the ethanol solution and macroporous adsorption resin at a liquid-solid ratio of 3:1mL / g for 6 hours, and then use 160-200mL to remove Wash the soaked macroporous adsorption resin with ion water, then put the washed macroporous adsorption resin into a vacuum drying oven and dry at 60°C for 6 hours to obtain the pretreated macroporous adsorption resin;

[0048] (2) Preparation of organic extraction solvent

[0049] Mix N235 and petroleum ether with a volume ratio of 1:1 to obtain an organic extraction solvent;

[0050] (3) Preparation of Vanadium Extraction Solvent Impregnated Resin

[0051] Get the macroporous...

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Abstract

The invention relates to a supersonic preparation method and application of a vanadium extraction solvent impregnating resin. The technical scheme adopted by the invention lies in that the supersonic preparation method comprises the following steps of performing mixing and soaking on certain volume of macroporous resin and certain volume of anhydrous ethanol, and performing preprocessing; and mixing the preprocessed macroporous resin with an organic extraction solvent, performing ultrasonic immersing, performing washing and filtering by deionized water, performing vacuum drying to obtain the vanadium extraction solvent impregnating resin prepared by an ultrasonic immersing method, and enabling the vanadium extraction solvent impregnating resin prepared by the ultrasonic immersing method to be used for separation and enrichment of a vanadium-containing solution. Compared with a method of preparing the vanadium extraction solvent impregnating resin by a constant-temperature oscillation method, the preparation method disclosed by the invention has the advantages that on the basis of keeping a higher balancing immersing rate, the immersing balance time is greatly shortened, the adsorption quantity of the solvent impregnating resin to vanadium is increased, and the preparation method has the characteristics of being easy to operate, low in energy cost, high in efficiency and the like.

Description

technical field [0001] The invention belongs to the field of separation and enrichment of rare metals, and in particular relates to a solvent-impregnated resin for vanadium extraction and its preparation method and application. Background technique [0002] Vanadium is an important strategic resource, widely used in metallurgy, national defense, aviation, chemical industry and other fields. Stone coal is a kind of vanadium-containing resource unique to my country, and its reserves are very rich (Bao Shenxu et al., Global Vanadium Production, Consumption and Market Analysis [J]. China Mining. 2009, 18:12-15.). To extract vanadium from vanadium resources, vanadium needs to be leached from raw materials. During the leaching process, a large number of impurity ions will be leached together with vanadium. Therefore, the obtained vanadium-containing liquid needs to be separated and enriched. At present, the separation and enrichment technologies of vanadium-containing liquid main...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B34/22C22B3/24C22B3/38C22B3/28C08J9/40C08L23/08
CPCC08J9/40C08J2323/08C22B3/24C22B34/22C22B3/28C22B3/3844C22B3/3846Y02P10/20
Inventor 包申旭陈波张一敏刘涛黄晶
Owner WUHAN UNIV OF TECH
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