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Polylactic acid fresh-keeping film containing natural antibacterial ingredients and preparation method thereof

A natural antibacterial and polylactic acid technology, which is applied to biocide-containing paints, coatings, antifouling/underwater coatings, etc., can solve the problems of loss of antibacterial materials, white pollution, waste, etc., and achieve coating drying time is small, The processing method is simple, and the effect of solving white pollution

Active Publication Date: 2017-06-13
INST OF AGRO PROD PROCESSING SCI & TECH SICHUAN ACAD OF AGRI SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The reason is that the antibacterial fresh-keeping film material prepared by the first method mainly has a contact sterilization mechanism, that is to say, the antibacterial agent on the film material can only be sterilized after being in contact with the wrapped object; the second method, Due to the long film forming period of the material, the mechanical strength of the material after film formation is not ideal, which limits its application; the third method, due to the low boiling point of the volatile antibacterial material, will be lost during the process of processing by the usual thermal processing method. A large amount of antibacterial materials will generate huge waste and affect the effect
Therefore up to the present, the product of the second and the 3rd mode also does not have the report that product promotes in the market
There is another problem worthy of attention. The packaging film materials used in large quantities in the storage and transportation of fruits and vegetables are all disposable non-degradable products. The problem of white pollution caused by direct discarding after use has always been a social problem that needs to be solved.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] To prepare the ethyl acetate extract of fig branches, take the naturally dried fig branches, crush them through a 40-mesh sieve, use the Soxhlet extraction method, use ethyl acetate as the extractant and reflux at 60°C for 6 hours, take the ethyl acetate extract, and medium-speed Filter through filter paper, evaporate the ethyl acetate to dryness under vacuum at 35°C, and the remaining viscous substance is the ethyl acetate extract of fig branches.

[0031] A kind of polylactic acid protective film containing natural antibacterial composition prepared by the present invention is divided into three steps:

[0032] The first step is to prepare the modified polylactic acid film

[0033] 99% by weight of polylactic acid particles (REVODE110) and 1% by weight of nano-copper (CW-Cu-001) were mixed uniformly by a high-speed mixer, and blown by a film blowing machine to form a modified polylactic acid film.

[0034] The second step is to prepare antibacterial coating

[0035]...

Embodiment 2

[0045] A kind of polylactic acid protective film containing natural antibacterial composition prepared by the present invention is divided into three steps:

[0046] The first step is to prepare the modified polylactic acid film

[0047] 99.5% by weight of polylactic acid particles (REVODE110) and 0.5% by weight of nano-copper (CW-Cu-001) were mixed uniformly by a high-speed mixer, and blown by a blown film machine to form a modified polylactic acid film.

[0048] The second step is to prepare antibacterial coating

[0049] The weight percentages of each component are as follows:

[0050] Fig branch ethyl acetate extract 2%;

[0051] Acrylic acid-hydroxypropyl acrylate copolymer 95%;

[0052] Hydroxypropyl Acrylate 2%;

[0053] Initiator BP1173 1%

[0054] Add the above components into a high-speed mixer at a speed of 600r / min and stir evenly, and seal it for later use.

[0055] The third step, coating

[0056] The sealed antibacterial coating is passed through a roller...

Embodiment 3

[0059] A kind of polylactic acid protective film containing natural antibacterial composition prepared by the present invention is divided into three steps:

[0060] The first step is to prepare the modified polylactic acid film

[0061] 99.8% by weight of polylactic acid particles (REVODE110) and 0.2% by weight of nano-copper (CW-Cu-001) were mixed uniformly by a high-speed mixer, and blown by a blown film machine to form a modified polylactic acid film.

[0062] The second step is to prepare antibacterial coating

[0063] The weight percentages of each component are as follows:

[0064] Fig branch ethyl acetate extract 1.5%;

[0065] Acrylic acid-hydroxypropyl acrylate copolymer 80%;

[0066] Multifunctional acrylate monomer 16.5%;

[0067] Initiator BP1173 2%

[0068] Add the above components into a high-speed mixer at a speed of 600r / min and stir evenly, and seal it for later use.

[0069]The third step, coating

[0070] Pass the sealed antibacterial coating on the ...

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PUM

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Abstract

The invention relates to a polylactic acid fresh-keeping film containing natural antibacterial ingredients and a preparation method thereof, is used for solving the problems that a conventional antibacterial fresh-keeping film has complex processing, volatile antibacterial materials have large loss in the processing process and white pollution of a packaging film is serious. A single face or double faces of a modified polylactic acid thin film are coated with an antibacterial coating layer containing a fig branch extract, wherein the modified polylactic acid thin film is prepared by taking polylactic acid resin REVODE110 as a base material, adding nano copper CW-Cu-001 and blowing; the antibacterial coating layer is preapred by adding an acrylic acid-hydroxypropyl acrylate copolymer, hydroxypropyl acrylate and an initiator BP1173 to the fig branch ethyl acetate extract and mixing; the modified polylactic acid thin film is coated with the antibacterial coating layer, then the coated modified polylactic acid thin film is irradiated and cured by an ultraviolet light, and thus the polylactic acid fresh-keeping film is obtained .

Description

[0001] Technical field: [0002] The invention relates to an antibacterial fresh-keeping film and a preparation method thereof. [0003] Background technique: [0004] At present, there are three main methods of antibacterial fresh-keeping film developed at home and abroad: first, the film material is mixed with antibacterial agents before forming, such as nano-silver, nano-zinc and other antibacterial agents as antibacterial materials; The molecular material is used as the base material, and the antibacterial agent is mixed to form a film; thirdly, the natural volatile antibacterial material is mixed into the resin, and the film is extruded and blown at high temperature. Among these three methods, the first one has been popularized and used in a small range of small-scale products, and the second and third methods are mainly studied in the laboratory. The reason is that the antibacterial fresh-keeping film material prepared by the first method mainly has a contact sterilizati...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J7/04C08L67/04C08K3/08C09D4/02C09D4/06C09D5/14
CPCC08J5/18C08J7/0427C08J2367/04C08K3/08C08K2003/085C08K2201/011C08L67/04C09D4/06C09D5/14
Inventor 曾晓丹朱永清贺红宇王自鹏刘培
Owner INST OF AGRO PROD PROCESSING SCI & TECH SICHUAN ACAD OF AGRI SCI
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