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Inferior diesel pour-point depressing modification method

A low-quality diesel oil upgrading technology, applied in the petroleum industry, processing hydrocarbon oil, hydrocarbon oil treatment products, etc., can solve the contradiction between the depressing effect and the yield of diesel fractions, reduce the service life of the hydrogen depreciating catalyst, diesel oil Distillate yield and the limitation of pour point depressing effect, etc., to achieve the effect of improving reaction heat utilization efficiency, improving pour point depressing effect, and strong adaptability of raw materials

Active Publication Date: 2017-05-17
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In this method, the temperature drop in the bed of the hydrodepreciation catalyst is relatively large, and the yield of the diesel fraction and the improvement of the depreciation effect are limited to a certain extent, which reduces the service life of the hydrodecondensation catalyst.
[0006] CN102051232A introduces a method for diesel hydrotreating decondensation, which has the characteristics of good diesel decondensation effect and high yield of diesel fractions by adjusting the properties of the catalyst. Combined process, conflict between pour point depressing effect and diesel fraction yield still exists
[0008] The reaction temperature at the outlet of each bed layer is still relatively high, and the cycle is limited to a certain extent

Method used

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  • Inferior diesel pour-point depressing modification method
  • Inferior diesel pour-point depressing modification method
  • Inferior diesel pour-point depressing modification method

Examples

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Effect test

Embodiment 1~4

[0037] This example is an ebullating-bed hydrogenation test using a hydrogenation depreciation catalyst, a diesel hydromodified isomerization depreciation catalyst and a powdered hydrorefining catalyst. See attached for specific operation procedure figure 1 . In Examples 1 to 2, the volume ratio of the powdered hydrorefining catalyst to the hydrodepreciation catalyst and diesel hydromodified isomerization depreciation catalyst is 1:4. The volume ratio of the structural depreciation catalyst is 1:1; in Example 3, the volume ratio of the powdered hydrofinishing catalyst to the hydrogenation depreciation catalyst and the diesel hydromodification isomerization depreciation catalyst is 3:1, where the hydrogenation The volume ratio of the pour point depressing catalyst and the diesel hydromodified isomerized pour point depressing catalyst is 2:1; The volume ratio is 1:3, among which the volume ratio of the hydrogenation depreciation catalyst and the diesel hydromodification isomer...

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Abstract

The invention discloses an inferior diesel pour-point depressing modification method, which comprises the following contents: (1) an inferior diesel material and a powdery hydrofining catalyst are fully mixed in a mixer to obtain a mixed feed of the catalyst and the raw oil; (2) the mixed feed and hydrogen enter a boiling-bed reactor from the bottom of a reactor filled with a mixture of a hydrodewaxing catalyst and a hydro-upgrading catalyst to undergo a hydrogenation reaction; (3) the reaction product is charged out of the top of the boiling-bed reactor and then enters a stable reactor to supplement hydrofining; and (4) the material undergoes solid-liquid separation, and a liquid phase enters a fractionating system so as to obtain a diesel product with high quality, low pour point, low sulfur content and high cetane number. According to the method, the backmixing characteristic of the boiling-bed reactor is fully utilized, and cooling and hydrofining of the hydrodewaxing process and temperature rising of the hydro-upgrading process are reasonably utilized. Therefore, the diesel with low pour point and ultra-low sulfur content is produced, cetane number is raised, hot-spot temperature of the device is reduced, running period is prolonged, and operation expenses are saved.

Description

technical field [0001] The invention relates to a method for depressing and upgrading low-quality diesel oil, in particular to a production method for producing high-quality low-condensation and low-sulfur diesel oil through an ebullated bed reactor. Background technique [0002] Diesel, as a fuel for compression ignition engines, plays an irreplaceable role as a non-renewable resource in modern production and life, and can be used as vehicles, tanks, airplanes, tractors, railway vehicles and other vehicles or other machinery Fuel can also be used for power generation, heating, etc. Depending on the industry and environment in which it is used, the quality requirements of users for diesel products are also very different. For people living in alpine regions or in winter, the demand for low-condensing-point diesel has always been high. The traditional choice The cracking process can process waxy heavy diesel fractions, and the pour point depressing range can reach 20-50°C. W...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G67/02
CPCC10G67/02C10G2400/04
Inventor 彭冲方向晨曾榕辉王仲义吴子明白振民崔哲孙士可
Owner CHINA PETROLEUM & CHEM CORP
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