Novel adsorption composite material and preparation method thereof
A composite material and a new type of technology, applied in chemical instruments and methods, adsorption water/sewage treatment, other chemical processes, etc., can solve the problems of poor adsorption performance, high removal rate, poor adsorption effect of heavy metal ions in water, etc., to achieve good results The effect of the adsorption effect
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Embodiment 1
[0023] S1: Mix 30 parts of activated carbon, 11 parts of 4-chloro-2-aminophenol-6-sulfonic acid and 10 parts of pyridoxal phosphate, stir and react at a temperature of 150°C at a rate of 400r / min for 1h, and filter the reaction The activated carbon was dried and roasted at 300°C for 10 minutes to obtain the modified activated carbon;
[0024] S2: Mix 25 parts of ion exchange resin, 8 parts of aliphatic epoxy resin and 15 parts of diethylene glycol monobutyl ether, the ion exchange resin is a mixture of ion exchange resin XAD-4 and ion exchange resin XAD-10, The mixing ratio of the two is 1-3:1; and at a temperature of 140°C, stirring and reacting at a rate of 500r / min for 1.5h to obtain a modified ion exchange resin;
[0025] S3: Mix the modified activated carbon described in step S1 with the modified ion exchange resin described in step S2, add 7 parts of glycerol phosphate and react at a temperature of 70° C. for 20 minutes;
[0026] S4: Then add 4 parts of 2,6-dimethoxyphe...
Embodiment 2
[0030] S1: Mix 45 parts of activated carbon, 16 parts of 4-chloro-2-aminophenol-6-sulfonic acid and 15 parts of pyridoxal phosphate, stir and react at a temperature of 180°C at a rate of 500r / min for 2h, and filter the reaction The activated carbon was dried and roasted at 350°C for 15 minutes to obtain the modified activated carbon;
[0031] S2: Mix 35 parts of ion exchange resin, 12 parts of aliphatic epoxy resin and 20 parts of diethylene glycol monobutyl ether, the ion exchange resin is a mixture of ion exchange resin XAD-4 and ion exchange resin XAD-10, The mixing ratio of the two is 1-3:1; and at a temperature of 160°C, stirring and reacting at a rate of 600r / min for 2h to obtain a modified ion exchange resin;
[0032] S3: Mix the modified activated carbon described in step S1 with the modified ion exchange resin described in step S2, add 13 parts of glycerol phosphate and react at a temperature of 80° C. for 30 minutes;
[0033] S4: Then add 7 parts of 2,6-dimethoxyphe...
Embodiment 3
[0037] S1: Mix 35 parts of activated carbon, 13 parts of 4-chloro-2-aminophenol-6-sulfonic acid and 12 parts of pyridoxal phosphate, stir and react for 1 hour at a temperature of 160°C at a rate of 400r / min, and filter the reaction The activated carbon was dried and roasted at 300°C for 10 minutes to obtain the modified activated carbon;
[0038] S2: Mix 27 parts of ion exchange resin, 9 parts of aliphatic epoxy resin and 17 parts of diethylene glycol monobutyl ether, the ion exchange resin is a mixture of ion exchange resin XAD-4 and ion exchange resin XAD-10, The mixing ratio of the two is 1-3:1; and at a temperature of 140°C, stirring and reacting at a rate of 500r / min for 1.5h to obtain a modified ion exchange resin;
[0039]S3: Mix the modified activated carbon described in step S1 with the modified ion exchange resin described in step S2, add 8 parts of glycerol phosphate and react at a temperature of 70° C. for 20 minutes;
[0040] S4: Then add 5 parts of 2,6-dimethoxy...
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