LED-UV (light-emitting diode-ultraviolet) anti-doodling pollution-resisting coating and preparation method as well as use method thereof

An anti-graffiti and coating technology, applied in anti-fouling/underwater coatings, fire-resistant coatings, polyester coatings, etc., can solve the problems of oil-based anti-graffiti coatings with long drying time, poor VOC emission and environmental protection, and can not be used for outdoor construction. Achieve the effects of fast UV curing rate, excellent weather resistance and thermal stability, and low film-forming surface tension

Active Publication Date: 2017-04-26
SHENZHEN GRANDLAND ENVIRONMENTAL COATING CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For example: water-based anti-graffiti coatings have poorer film fullness than oil-based ones, and at the same time have the disadvantage of insufficient film hardness; PU two-component oil-based anti-graffiti coatings take a long time to dry, and are prone to dust during the drying process of the paint film. It needs to be mixed with curing agent and diluent for construction, and VOC emission is poor in environmental protection; although traditional UV light-cured coatings have the advantages of high film hardness, good wear resistance, and high curing efficiency, high-pressure mercury lamps must be used to emit light during the drying process. Drying equipment to complete the cross-linking and curing reaction, to complete the film-forming and curing of the paint. Due to the high power (generally 80W / cm), the high-pressure mercury lamp has strong light intensity and brightness, and strong heat radiation (irradiated on the surface of the workpiece to increase the surface temperature of the workpiece) 20 degrees) and ozone will be generated during work, and a matching cooling system is required, so it cannot be used for outdoor construction

Method used

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  • LED-UV (light-emitting diode-ultraviolet) anti-doodling pollution-resisting coating and preparation method as well as use method thereof
  • LED-UV (light-emitting diode-ultraviolet) anti-doodling pollution-resisting coating and preparation method as well as use method thereof
  • LED-UV (light-emitting diode-ultraviolet) anti-doodling pollution-resisting coating and preparation method as well as use method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] The LED-UV anti-graffiti antifouling coating of the present embodiment is made up of the component of following weight:

[0041] 25kg of 4.5-functional fluorine siliconized acrylate resin; 25kg of special functional acrylic resin cured by low energy; 19.7kg of 8-functional hyperbranched polyester acrylic resin; 25kg of monomer; 4kg of photoinitiator; Foaming agent 0.4kg Anti-graffiti aid 0.6kg;

[0042] Get each component by the weight shown in embodiment 1 in table 1, and preparation method is according to the following steps:

[0043] Step 1, under the condition of avoiding sunlight or ultraviolet light, add 4.5-functional fluorine siliconized acrylate resin, low-energy curing special functional acrylic resin, 8-functional hyperbranched polyester acrylic resin and monomers according to the above weight Put it in the paint container and disperse it evenly, then add photoinitiator and wetting dispersant in sequence and stir at a stirring speed of 500-800 rpm for more tha...

Embodiment 2

[0048] 28kg of 4.5-functional fluorosilicified acrylate resin; 28kg of special functional acrylic resin; 15kg of 8-functional hyperbranched polyester acrylic resin; 22.3kg of monomer; 5kg of photoinitiator; 0.5kg of wetting and dispersing agent; 0.5kg of defoamer ; Anti-graffiti aid 0.7kg;

[0049] Get each component by the weight shown in Example 2 in Table 1, repeat the preparation method described in Example 1, wherein the stirring speed is 600 rev / min in the step 1, and the stirring speed in the step 2 is 900 rev / min, then Obtain the LED-UV anti-graffiti and anti-fouling coating of the present invention, and carry out the performance detection of the paint solution.

[0050] The LED-UV anti-graffiti and anti-fouling coating is brushed or sprayed, according to 60g / m 2 The amount of coating is applied to the surface of the object to be coated (decorative exterior wall, bus stop sign, communication power facility, etc.) that has been polished and dedusted in advance. Immedia...

Embodiment 3

[0052] Get each component by the weight shown in Example 3 in Table 1, repeat the preparation method described in Example 1, wherein the stirring speed in step 1 is 700 rpm, and the stirring speed in step 2 is 1000 rpm, then Obtain the LED-UV anti-graffiti and anti-fouling coating of the present invention, and carry out the performance detection of the paint solution.

[0053] The LED-UV anti-graffiti and anti-fouling coating is applied by brushing or spraying at 70g / m 2 The amount of coating is applied to the surface of the object to be coated (decorative exterior wall, bus stop sign, communication power facility, etc.) that has been polished and dedusted in advance. Immediately after the coating is completed, the LED-UV lamp is used to irradiate and light-cure for 7 seconds. The LED-UV anti-graffiti and anti-fouling coating film in Example 3 can be obtained. The performance testing results are shown in the corresponding data of Example 3 in Table 2.

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PUM

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Abstract

The invention discloses an LED-UV (light-emitting diode-ultraviolet) anti-doodling pollution-resisting coating, which can be used to coat the surface, which is polished and cleanly dedusted in advance, of a to-be-coated object through brush coating or spray coating according to the coating weight to 80g / m<2>; photocuring is performed immediately through illuminating by a portable LED-UV lamp for 5 to 8 seconds after the brush coating is finished; the LED-UV anti-doodling pollution-resisting coating is prepared from the following components in parts by weight: 25 to 35 parts of 4.5 functional silicofluoride acrylate resin, 21 to 30 parts of low-energy cured special functional acrylic resin, 10 to 20 parts of 8 functional hyperbranched polyester acrylic resin, 20 to 25 parts of monomer, 4 to 5 parts of photoinitiator, 0.3 to 0.5 part of wetting dispersant, 0.3 to 0.5 part of defoamer and 0.6 to 0.8 part of anti-doodling additive; a paint film has excellent properties of anti-doodling, pollution prevention, easiness in cleaning, water proofing, oil resistance and chemical resistance; the paint film is compact and smooth, and is high in hardness and good in pollution tolerance.

Description

technical field [0001] The invention relates to an LED-UV functional paint, in particular to a composition of an LED-UV anti-graffiti and anti-fouling paint, a preparation method and an application method thereof. Background technique [0002] In daily life, exterior surfaces such as decorative exterior walls, bus stop signs, and communication and power facilities are often scribbled with water-based or oil-based pens or pasted with various small advertisements, which seriously affects the appearance of the equipment and the overall environment, requiring sanitation workers It is time-consuming and labor-intensive to eradicate the small advertising paper with a spatula, and to clean the graffiti and dirt with a water-based or oil-based pen with a wet towel, but it cannot be completely removed. [0003] In order to solve this phenomenon, many companies have successively developed various anti-graffiti and anti-fouling coatings such as water-based, oil-based, traditional light...

Claims

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Application Information

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IPC IPC(8): C09D133/00C09D167/06C09D5/16C09D7/12
CPCC08L2201/08C09D5/1668C09D5/1687C09D5/18C09D133/00C08L67/06
Inventor 王双胡基如吴勇王红梅刘云飞
Owner SHENZHEN GRANDLAND ENVIRONMENTAL COATING CO LTD
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