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Fly ash modification agent and modified low-quality fly ash active mixing material thereof

A technology of fly ash and modifier, applied in the direction of climate sustainability, sustainable waste treatment, solid waste management, etc., can solve the problems of limited effect, insufficient output of high-quality fly ash, high cost, etc., to improve early and Late strength, improving the effect of increasing shortage of resources, improving impermeability

Active Publication Date: 2017-02-22
中建西部建设西南有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the output of high-quality fly ash that can be used for concrete in my country is insufficient, and there are few power plants that can supply high-quality fly ash. Class I and Class II fly ash only account for about 5%, and most of them are class III ash or other-grade ash, while class III Low early strength of ash or other ash hinders its application in concrete
[0003] At present, the modification methods of low-quality fly ash mainly include physical modification and chemical modification. Although physical modification through grinding can improve its activity, the effect is limited and it is difficult to improve the quality of a grade; and through alkali excitation or Modification of low-quality fly ash by means of sulfate excitation, the effect is not obvious, and the cost is high
At present, there is no perfect solution or way to maximize the use of low-quality fly ash

Method used

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  • Fly ash modification agent and modified low-quality fly ash active mixing material thereof
  • Fly ash modification agent and modified low-quality fly ash active mixing material thereof
  • Fly ash modification agent and modified low-quality fly ash active mixing material thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] A fly ash modifier, which comprises the following components in parts by mass: 75 parts of red mud, 25 parts of phosphogypsum, and 0.1 part of a grinding aid strengthening component; the grinding aid strengthening component is polyether alcohol 5-15 parts of amine, 5-15 parts of sugar ether, 30-50 parts of triethanolamine, 30-50 parts of triisopropanolamine. The specific components are shown in Table 1. Dry the above-mentioned red mud and phosphogypsum at 105°C and mix them evenly to obtain a mixture; then, according to the ratio of the grinding-aiding strengthening components in Table 1, respectively mix the grinding-aiding strengthening components 0 to 4 (the grinding-aiding strengthening component 0 corresponds to In the case of not mixing the grinding aid strengthening component in Table 2) into the obtained mixture, then place them in a ball mill respectively, grind for 20-60min, and measure the specific surface area in different grinding time, see Table 2.

[0033...

Embodiment 2

[0039] A fly ash modifier, which comprises the following components in parts by mass: 75 parts of red mud, 25 parts of phosphogypsum, and 0.1 part of a grinding aid strengthening component; both the red mud and phosphogypsum are baked The mass after drying: the grinding aid reinforcing component is composed of 10wt% polyetherolamine, 10wt% sugar ether, 45wt% triethanolamine and 35wt% triisopropanolamine according to mass percentage.

[0040] The preparation method of above-mentioned fly ash modifier, it comprises the steps:

[0041] (1) After drying red mud and phosphogypsum, set aside;

[0042](2) According to the mass fraction of each raw material, take the following components: 75 parts of red mud, 25 parts of phosphogypsum, and 0.1 part of grinding aid strengthening component; Ether alcohol amine 10wt%, sugar ether 10wt%, triethanolamine 45wt% and triisopropanolamine 35wt%; wherein, the quality of red mud and phosphogypsum is based on the mass after drying;

[0043] (3) ...

Embodiment 3

[0057] A fly ash modifier, which comprises the following components in parts by mass: 80 parts of red mud, 20 parts of phosphogypsum, and 0.2 part of a grinding aid strengthening component; both the red mud and phosphogypsum are baked The mass after drying: the grinding aid strengthening component is composed of 10wt% polyetherolamine, 10wt% sugar ether, 40wt% triethanolamine and 40wt% triisopropanolamine according to mass percentage.

[0058] Above-mentioned fly ash modifier preparation method, it comprises the steps:

[0059] (1) After red mud and phosphogypsum are dried, set aside;

[0060] (2) According to the mass fraction of each raw material, the following components are weighed: 80 parts of red mud, 20 parts of phosphogypsum, and 0.2 part of grinding aid strengthening component; 10wt% ether alcohol amine, 10wt% sugar ether, 40wt% triethanolamine and 40wt% triisopropanolamine; wherein, the quality of red mud and phosphogypsum is based on the mass after drying;

[0061...

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Abstract

The invention relates to a fly ash modification agent and a modified low-quality fly ash active mixing material thereof. Firstly, 75 to 80 parts of red mud, 20 to 25 parts of phosphogypsum and 0.1 to 0.3 part of grinding aiding enhancing ingredients are uniformly mixed; then, grinding is performed until the surface area is not smaller than 6000 cm<2> / g to obtain the fly ash modification agent; the obtained fly ash modification agent is sufficiently and uniformly mixed with grade III fly ash; then, the modified low-quality fly ash active mixing material is obtained. Through being metered in parts by mass of all raw materials, the stage III fly ash accounts for 75 to 81 parts, and the fly ash modification agent accounts for 19 to 25 parts. The fly ash modification agent and the modified low-quality fly ash active mixing material solve the problem of application of low-quality stage III fly ash to C30 or higher premixed reinforced concrete. In addition, the industrial waste slag of the red mud, the phosphogypsum and the like can be consumed; 100 weight percent of stage II fly ash can be replaced in an equal mass in concrete; the workability of the concrete and the anti-seeping performance of the concrete can be improved.

Description

technical field [0001] The invention relates to a fly ash modifier and a modified low-quality fly ash active admixture thereof, belonging to the field of building materials. Background technique [0002] Concrete is one of the most used construction materials in the world today. As we all know, the concrete industry is an energy and resource-consuming industry. Whether it is the ore used in the production of cement or the sand and gravel materials used in concrete, it is gradually consuming the precious resources of the earth. With the development of modern concrete technology, when preparing concrete, some industrial waste residues (such as fly ash, slag, phosphorus slag, etc.) are often used to replace part of the cement as auxiliary cementitious materials. With the development of concrete technology, high-quality fly ash has been more and more accepted and widely used in concrete. At present, the output of high-quality fly ash that can be used for concrete in my country...

Claims

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Application Information

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IPC IPC(8): C04B24/32C04B18/08C04B20/02
CPCC04B18/08C04B20/02C04B40/0039C04B18/0409C04B22/144C04B24/32C04B24/10C04B24/122Y02W30/91
Inventor 刘其彬温超凯余祥镖陈景林喜华
Owner 中建西部建设西南有限公司
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