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Pearlescent embossed pigment on ceramic glaze, pearlescent embossed paper on ceramic glaze and production method

A production method and technology of ceramic glaze, applied in printing, printing of special varieties of printed matter, technology for producing decorative surface effects, etc., can solve the problems of washing resistance, loss of metal feeling, pastel color relief color effect is not obvious, etc. Problems, to achieve excellent stain resistance, low lead and cadmium dissolution, excellent metal pearlescent color effect

Active Publication Date: 2019-04-09
福建省德化铭丰金花纸有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The traditional pearlescent relief pigment is mainly composed of artificially synthesized titanium oxide mica flakes, and its firing melting point is about 1500°C. Although the cost of titanium oxide mica flakes is low, it has the following disadvantages: first, poor adhesion; second , the surface is rough and glossy; third, the stain resistance is poor and not resistant to washing; the current solution is to print a transparent cover layer on the printed pearlescent pattern, so as to improve the gloss and abrasion resistance of the surface of ceramic products , but due to the poor match between pearlescent pigment and transparent cover layer, it brings new problems: the surface of ceramic products not only loses the metallic feeling that pearlescent pigment should have, but also affects the color of pearlescent pigment itself
[0003] And although there are many reports of relief on the relevant ceramic glaze in the prior art, there is no report of pearlescent relief, and the current relief paper has only single colors such as transparency and milky white, and the limitations are relatively large, and the above-mentioned many deficiencies are mainly It is caused by the limitation of relief pigment formula and production process, and the relief pigment of many flower papers will be unevenly distributed after being pasted on ceramic products and dried, which will affect the appearance of ceramic products, because the relief on the glaze has a great influence on the relief pigment. The composition and production process requirements are higher than those of pigments in glaze
The Chinese patent application No. 201410243698.X submitted by the applicant in 2014 discloses a manufacturing process of overglaze pastel relief printed products. Although it fills the gap in the color system of overglaze relief, the applicant is In the follow-up research, it was found that the pastel relief color effect of this decal paper is not obvious in the actual use process, the firing temperature is relatively high, and its color matching is also cumbersome, which still needs further improvement

Method used

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  • Pearlescent embossed pigment on ceramic glaze, pearlescent embossed paper on ceramic glaze and production method
  • Pearlescent embossed pigment on ceramic glaze, pearlescent embossed paper on ceramic glaze and production method
  • Pearlescent embossed pigment on ceramic glaze, pearlescent embossed paper on ceramic glaze and production method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Pearlescent relief pigments on ceramic glazes, including the following components in terms of mass percentages: 35% potassium feldspar, 20% borax, 10% kaolin, 35% low-temperature lead-free frit, wherein the total percentage of each component is 100% .

[0028] The preparation method of pearly embossed colored flower paper on ceramic glaze comprises the following steps:

[0029] Step 1, preparation of pearlescent powder: according to mass percentage, mix 80% of pearlescent powder and 20% of low-temperature lead-free frit, add ethanol of the same quality, ball mill at 1500r / min for 3h, dry and pulverize for 200 Mesh sieve spare;

[0030] Step 2, preparation of the pearlescent relief pigment: according to the mass percentage, mix feldspar, borax, kaolin and low-temperature lead-free frit evenly, and then calcining, ball milling, drying and pulverizing to obtain the pearlescent relief pigment;

[0031] Step three, printing:

[0032] a: Use a 250-mesh screen printing of l...

Embodiment 2

[0037] Pearlescent relief pigments on ceramic glazes, including the following components in terms of mass percentages: 30% albite feldspar, 15% borax, 5% kaolin, and 50% low-temperature lead-free frit, wherein the total percentage of each component is 100% .

[0038] The preparation method of pearly embossed colored flower paper on ceramic glaze comprises the following steps:

[0039] Step 1, preparation of pearlescent powder: according to mass percentage, mix 70% of pearlescent powder and 30% of low-temperature lead-free frit, add ethanol of the same quality, ball mill at 1500r / min for 2 hours, dry and pulverize for 200 Mesh sieve spare;

[0040] Step 2, preparation of the pearlescent relief pigment: according to the mass percentage, mix feldspar, borax, kaolin and low-temperature lead-free frit evenly, and then calcining, ball milling, drying and pulverizing to obtain the pearlescent relief pigment;

[0041] Step three, printing:

[0042] a: Use a 250-mesh screen printing...

Embodiment 3

[0047]Pearlescent relief pigments on ceramic glazes, including the following components in terms of mass percentages: 40% orthoclase, 25% borax, 15% kaolin, and 20% low-temperature lead-free frit, wherein the total percentage of each component is 100% .

[0048] The preparation method of pearly embossed colored flower paper on ceramic glaze comprises the following steps:

[0049] Step 1, preparation of pearlescent powder: according to mass percentage, mix 90% of pearlescent powder and 10% of low-temperature lead-free frit, add ethanol of the same quality, ball mill at 1500r / min for 4h, dry and pulverize for 200 Mesh sieve spare;

[0050] Step 2, preparation of pearlescent relief pigment: according to the mass percentage, mix feldspar, borax, kaolin and low-temperature lead-free frit frit evenly, and then obtain the pearlescent relief pigment through calcination, ball milling, drying and crushing ;

[0051] Step three, printing:

[0052] a: Use a 250-mesh screen printing of...

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Abstract

The invention relates to a ceramic overglazed pearlescent relief pigment, a ceramic overglazed pearlescent relief color decal paper and a manufacturing method thereof and belongs to the technical field of ceramic overglazed color printing. The ceramic overglazed pearlescent relief pigment comprises the following components in percentage by mass: 30-40% of feldspar, 15-25% of borax, 5-15% of kaoline and 20-50% of low-temperature lead-free frits, wherein the percentage sum of all the components is 100%. After a ceramic product is decaled by using the ceramic overglazed pearlescent relief color decal paper prepared by the manufacturing method, an overglazed pearlescent relief has a relatively strong adhesive force and favorable glossiness, the ceramic product is enabled to have excellent stain resistance, scrubbing resistance and wear resistance and is also enabled to have an excellent metal pearlescent colorating effect, and the ceramic product can show pearlescent metal effects with different degrees under rays with different angles; in addition, the manufactured decal paper is attractive in appearance, environment-friendly and extremely low in lead and cadmium dissolution quantity and conforms to the standards of China and each of Europe and America.

Description

technical field [0001] The invention belongs to the technical field of ceramic overglaze color printing, and in particular relates to a ceramic overglaze pearlescent embossed pigment, ceramic overglaze pearlescent embossed colored flower paper and a production method. Background technique [0002] Ceramic pearlescent embossed pigments are embossed overcoat pigments specially used for ceramic glaze decals. It is characterized in that it can achieve a strong metallic feeling after production and firing, and can display different metallic effects under different angles of light. Its color The transformation is rich, basically close to the hair color of organic pigments. The traditional pearlescent relief pigment is mainly composed of artificially synthesized titanium oxide mica flakes, and its firing melting point is about 1500°C. Although the cost of titanium oxide mica flakes is low, it has the following disadvantages: first, poor adhesion; second , the surface is rough and ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B44C1/16
CPCB44C1/16
Inventor 吕素妹
Owner 福建省德化铭丰金花纸有限公司
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