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Guerbet alcohol cyclopentane carboxylic acid ester lubricant and preparation method thereof

A technology of alcohol cyclopentane carboxylate and Guerbet alcohol, applied in the field of Guerbet alcohol cyclopentane carboxylate lubricant and its preparation, can solve the problem of weak substrate adsorption and easy boundary lubricant film To solve problems such as damage and weak extreme pressure performance, achieve the effects of short reaction time, wide liquidus temperature range, and excellent high and low temperature performance

Active Publication Date: 2016-12-07
LANZHOU INST OF CHEM PHYSICS CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, since these compounds are non-polar compounds, the adsorption force to the substrate is weak, and the boundary lubricant film is easily destroyed during the friction process, so its extreme pressure performance is relatively weak.

Method used

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  • Guerbet alcohol cyclopentane carboxylic acid ester lubricant and preparation method thereof
  • Guerbet alcohol cyclopentane carboxylic acid ester lubricant and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Add 1mol (130.0g) 2-ethylhexanol, 8.0g [HSO 3 -pmim] HSO 4 , 0.5mol (57.0g) cyclopentanecarboxylic acid and 232.0g toluene, heat up, and reflux to react until no more water comes out of the system. After cooling, transfer to a separatory funnel, let it stand, separate the lower ionic liquid, wash the organic layer three times with water, dry over anhydrous magnesium sulfate, filter, and evaporate unreacted raw materials under reduced pressure to obtain 2-ethylhexanol cyclopentane Formate, the yield is 65% (wt%).

Embodiment 2

[0029] Synthesis of 2-Butyloctanol Cyclopentanecarboxylate. Replace 2-ethylhexanol with 2-butyloctanol, [HSO 3 -pmim ]H 2 PO 4 Alternative to [HSO 3 -pmim] HSO 4 as a catalyst. 1mol (158.3g) 2-butyl octanol, 8.5g [HSO 3 -pmim ]H 2 PO 4 , 0.45mol (51.3g) cyclopentanecarboxylic acid and 240.0g toluene, all the other are with embodiment 1. Yield 60% (wt%).

Embodiment 3

[0031] Synthesis of 2-Hexyldecyl Cyclopentanecarboxylate. Replace 2-ethylhexanol with 2-hexyldecanol, [HSO 3 -pmim ]H 2 PO 4 Alternative to [HSO 3 -pmim] HSO 4 as a catalyst. 1mol (242.5g) 2-hexyldecanol, 9.5g [HSO 3 -pmim ]H 2 PO 4 , 0.45mol (51.3g) cyclopentanecarboxylic acid and 252.0 g toluene, all the other are with embodiment 1. Yield 55% (wt%).

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Abstract

The invention discloses a guerbet alcohol cyclopentane carboxylic acid ester lubricant and a preparation method thereof. The preparation method includes: taking cyclopentane-carboxylic acid and guerbet alcohol as raw materials, acidic ionic liquid as a catalyst and methylbenzene as a solvent and subjecting the compound to reaction for 2-4 hours under condition of reflux to obtain a target product. The compound serving as basic oil for the lubricant and lubricating grease is suitable for lubrication of various friction pairs such as steel / steel and ceramic / steel and can be applied to liquid lubrication under harsh conditions (high speed, high low temperature, high vacuum and the like) of space mechanisms.

Description

technical field [0001] The invention relates to a Guerbet alcohol cyclopentane carboxylate lubricant and a preparation method thereof. The compound can be used for lubrication under harsh conditions of space machinery. Background technique [0002] Polyalkylated cyclopentanes (MACs) have low volatility, high thermal and chemical stability, and have great application potential in the lubrication of space machinery, and practical experience in space applications has been obtained. (D. J. Carre, C. G. Kalogeras, S. V. Didziulis, R. Bauer. Recent experience with synthetichydrocarbon lubricants for spacecraft applications. Aerospace Corp., report TR (5935)-3 , June 1995; W. R. Jones, Jr., A. K. Poslowski. Evaluation of several space lubricants using a vacuum four-ball tribometer. NASA TM-1998- 208654 , October 1998.). [0003] The core five-membered ring of polyalkylated cyclopentanes gives this class of compounds high thermal and chemical stability. However, since these c...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07C67/08C07C69/74C10M105/34C10N30/06C10N30/08
CPCC07C67/08C10M105/34C10N2030/06C10N2030/08C07C69/74Y02P20/54
Inventor 高平刘维民冯大鹏孙晓军
Owner LANZHOU INST OF CHEM PHYSICS CHINESE ACAD OF SCI
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