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High-temperature adhesive for adhesion of engineer boots and preparation method and application thereof

An adhesive and engineering technology, applied in the direction of polymer adhesive additives, non-polymer adhesive additives, adhesive types, etc., can solve the problem of difficult to meet the needs of long-term use of shoes, poor compatibility of matrix resin, It is difficult to achieve high filling amount and other problems, to achieve the effect of improving heat resistance, heat resistance and adhesion performance, and improving overall heat resistance

Inactive Publication Date: 2016-11-16
东莞爱的合成材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Graphene and carbon nanotubes, as new carbon materials developed in recent years, have high specific surface area, high thermal conductivity, and high temperature resistance, and have become a "new favorite" in the field of heat resistance and heat conduction. However, they are not compatible with matrix resins. Poor compatibility, difficult to achieve high filling content limits its use
[0003] In the process of shoe production, many places such as the sole and the upper need to be bonded with adhesives, but the most easily damaged part of the shoe is the bonding part. Under high temperature conditions, due to the poor heat resistance of the adhesive, the bonding force drops significantly. , common shoe adhesives are difficult to meet the needs of long-term use of high-temperature engineering shoes

Method used

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  • High-temperature adhesive for adhesion of engineer boots and preparation method and application thereof

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Embodiment Construction

[0021] The principles and features of the present invention are described below, and the examples given are only used to explain the present invention and are not intended to limit the scope of the present invention.

[0022] Vulcanized carboxylated nitrile rubber 1: First, 10 parts by weight of multi-walled carbon nanotubes, 5 parts by weight of thiophosphoric acid disulfide, and 2 parts by weight of N-oxydiethylene-2-benzothiazole sulfenamide are fully mixed , further added to 83 parts by weight of vulcanized nitrile rubber, heated and vulcanized, and granulated.

[0023] Vulcanized carboxylated nitrile rubber 2: first 5 parts by weight of thiophosphoric acid disulfide, 2 parts by weight of N-oxydiethylene-2-benzothiazole sulfenamide are fully mixed, and further added to 83 parts by weight of carboxylated nitrile rubber part, heat vulcanization, further add 10 parts by weight of multi-walled carbon nanotubes, mix uniformly and then granulate.

[0024] Acrylic rubber 1: Copo...

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Abstract

The invention discloses a high-temperature adhesive for adhesion of engineer boots with excellent high temperature resistance and high adhesive strength and provides a preparation method and application thereof. The adhesive comprises 100 weight parts of vulcanized carboxyl butadiene acrylonitrile rubber, 50-80 weight parts of vulcanized acrylic rubber, 30-50 weight parts of thermal conducting filler, 3-8 weight parts of a coupling agent, 2-10 weight parts of an antioxidant and 18-30 weight parts of a tackifier. By selecting the carboxyl butadiene acrylonitrile rubber and acrylic rubber with excellent high thermal property, compounding graphene, carbon nano tubes and spherical aluminum oxide and selecting the tackifier, the high temperature resistance and adhesive strength are balanced, and the high-temperature adhesive for adhesion of engineer boots with excellent high temperature resistance is obtained.

Description

Technical field: [0001] The invention relates to the field of adhesives for shoes, in particular to the field of adhesives for high-temperature engineering bonding. Background technique: [0002] Nitrile rubber and acrylic rubber are two kinds of rubber commonly used in the prior art. They have the characteristics of high temperature resistance, oil resistance, friction resistance and excellent adhesion, and are widely used in various industrial fields. Graphene and carbon nanotubes, as new carbon materials developed in recent years, have high specific surface area, high thermal conductivity, and high temperature resistance, and have become a "new favorite" in the field of heat resistance and heat conduction. However, they are not compatible with matrix resins. Poor compatibility and difficulty in achieving high filling limits its use. [0003] In the process of shoe production, many places such as the sole and the upper need to be bonded with adhesives, but the most easily...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J113/00C09J133/12C09J11/04C09J11/06C09J11/08C08J3/24C08L13/00
CPCC08J3/24C08J2313/00C08K2201/011C08L2201/08C08L2205/03C09J11/04C09J11/06C09J11/08C09J113/00C08L33/12C08L75/04C08K13/06C08K9/04C08K9/06C08K7/24C08K3/04C08K7/18
Inventor 马爱芬
Owner 东莞爱的合成材料科技有限公司
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