Composition for purifying tail gas of grain dryer based on activated alumina modification and its preparation method and application
An activated alumina and dryer technology, applied in chemical instruments and methods, separation methods, gas treatment and other directions, can solve problems such as the effect of exhaust gas treatment is not very ideal, the dust particles are difficult to be completely clear, and the exhaust gas has not been solved. Achieve the effect of excellent purification ability, excellent absorption capacity and easy promotion
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[0015] The invention provides a method for preparing a composition for purifying tail gas of a grain dryer based on activated alumina modification, the preparation method comprising:
[0016] 1) In the presence of protective gas, the bentonite is calcined to obtain bentonite powder;
[0017] 2) placing activated carbon powder, wheat bran powder, fly ash and bentonite powder in an acid solution for activation treatment to obtain an activation mixture;
[0018] 3) MDI (4,4,-diphenylmethane diisocyanate), TDI (toluene diisocyanate), polyether polyol, activated alumina, potassium titanium oxalate and the activated mixture are contacted in the presence of ultrasonic waves to produce Get foaming resin;
[0019] 4) Pulverizing the foaming resin to obtain foaming resin powder, and then mixing anionic surfactant, water and foaming resin powder to prepare a composition for purifying grain dryer exhaust gas modified based on activated alumina.
[0020] In step 1) of the above-mentioned...
Embodiment 1
[0036] 1) In the presence of protective gas (nitrogen), the bentonite was calcined at 430° C. for 5 hours to obtain bentonite powder (particle size below 10 μm);
[0037] 2) Mix activated carbon powder (below 10 μm in particle size), wheat bran powder (below 10 μm in particle size), fly ash (below 10 μm in particle size), bentonite powder and acid solution (pH 4) according to the ratio of 100:24:15:39 : mixed at a weight ratio of 400, and activated at 48°C for 1.2h to obtain an activated mixture;
[0038] 3) MDI, TDI, polyether polyol (brand L61), activated alumina, potassium titanium oxalate and the activation mixture according to the weight ratio of 100:20:120:19:1.2:34 in the presence of ultrasonic waves with a frequency of 25MHz And carry out a contact reaction at 75°C for 8 hours to obtain a foaming resin;
[0039] 4) Pulverize the foaming resin to obtain foaming resin powder (below 10 microns), then mix anionic surfactant (sodium lauryl sulfate), water and foaming resin...
Embodiment 2
[0041]1) In the presence of protective gas (neon gas), calcining bentonite at 420°C for 4 hours to obtain bentonite powder (particle size below 10 μm);
[0042] 2) Mix activated carbon powder (below 10 μm in particle size), wheat bran powder (below 10 μm in particle size), fly ash (below 10 μm in particle size), bentonite powder and acid solution (pH 3.5) according to 100:20:12:35 : mixed at a weight ratio of 300, and activated at 45°C for 1 hour to obtain an activated mixture;
[0043] 3) MDI, TDI, polyether polyol (brand L64), activated alumina, potassium titanium oxalate and the activation mixture are in the presence of ultrasonic waves with a frequency of 20MHz according to the weight ratio of 100:15:110:15:0.5:30 And carry out a contact reaction at 60°C for 6 hours to obtain a foaming resin;
[0044] 4) Pulverize the foaming resin to obtain foaming resin powder (below 10 microns), then mix anionic surfactant (sodium lauryl sulfate), water and foaming resin powder in a we...
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