Porous carbon-graphene-metal oxide composite material and preparation method and application thereof
A composite material and porous material technology, applied in porous carbon-graphene-metal oxide composite materials and their preparation and application fields, can solve the problem of reducing the performance and product quality of supercapacitor devices, affecting the electrical conductivity of electrode materials, and the inconsistency of porous structures. Continuity and other problems, to achieve the effect of maintaining continuity and continuity, solving the discontinuity of specific surface area and structure, and improving specific surface area and electrical conductivity
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Embodiment 1
[0043] A method for preparing a porous carbon-graphene-metal oxide composite material, specifically comprising the following steps:
[0044] (1) After cleaning the loofah, freeze-dry at -50°C for 48 hours;
[0045] (2) The configuration concentration is 5mg. ml -1 The graphene oxide suspension, vigorously stirred to obtain a stable graphene oxide suspension;
[0046] Put the freeze-dried loofah into the graphene oxide solution, soak it for 2 hours, and then dry it at 60°C; repeat the above steps 5 times to ensure that the graphene completely enters the porous material of the loofah and adheres to the porous material surface, forming a porous-graphene composite;
[0047] In the above-mentioned steps, the mass ratio of graphene oxide and loofah is 1:40.
[0048] (3) Put the porous-graphene composite material into a tube furnace for heat treatment. The heat treatment temperature is 900°C and the treatment time is 2h. The porous material is carbonized and the graphene is reduced...
Embodiment 2
[0052] A method for preparing a porous carbon-graphene-metal oxide composite material, specifically comprising the following steps:
[0053] (1) After washing the aloe vera, freeze-dry it at -40°C for 24 hours;
[0054] (2) The configuration concentration is 10mg. ml -1 The graphene oxide suspension, vigorously stirred to obtain a stable graphene oxide suspension;
[0055] Put the freeze-dried loofah into the graphene oxide solution, soak it for 4 hours, and then dry it at 100°C; repeat the above steps 10 times to ensure that the graphene completely enters the aloe porous material and adheres to the surface of the porous material , forming a porous-graphene composite;
[0056] In the above steps, the mass ratio of graphene oxide to aloe is 1:30.
[0057] (3) Put the porous-graphene composite material into a tube furnace for heat treatment. The heat treatment temperature is 1000°C and the treatment time is 4h. The porous material is carbonized and graphene oxide is reduced ...
Embodiment 3
[0061] A method for preparing a porous carbon-graphene-metal oxide composite material, specifically comprising the following steps:
[0062] (1) Sand the shells first to remove the protein and pearl layer, after cleaning, decalcify the shells with EDTA decalcification solution, wash and dry;
[0063] (2) The configuration concentration is 8 mg. ml -1 The graphene oxide suspension, vigorously stirred to obtain a stable graphene oxide suspension;
[0064] Put the treated shells into the graphene oxide solution, soak them for 3 hours, and then dry them at 70°C; repeat the above steps 8 times to ensure that the graphene completely enters the shell porous material and adheres to the surface of the porous material to form a porous- Graphene composite materials;
[0065] In the above steps, the mass ratio of graphene oxide to shell is 1:50.
[0066] (3) Put the porous-graphene composite material into a tube furnace for heat treatment. The heat treatment temperature is 950°C and t...
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