A preparation method of expanded particles and the prepared expanded particles and application thereof
A technology of foaming particles and foaming agent, which is applied in the field of polymer material preparation, can solve the problems of no industrial application, complex process, and difficulty in controlling the production of foamed particles with stable quality.
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Embodiment 1
[0092] The ratio is made according to the following mass percentage composition: thermoplastic polyurethane elastomer (AH-650 from Taiwan Xinshun), pellets, 95.5%; manganese dioxide 0.5%; foaming agent selected water, acetone, propylene glycol (all commercially available analysis Pure) mixture, the mass ratio between the three is 4:1:0.25, the foaming agent mixture is 3%; the foaming enhancer is a mixture of butyl acetate and ethyl acetate (the mixing ratio is 1:2 by mass ), foam penetration enhancer mixture 0.3%; talc (commercially available), 0.1%, glycerol monoglyceride 0.1%; zinc stearate 0.2%; antioxidant 168 0.3%.
[0093] Kneading the components other than the foaming agent and the foaming penetration enhancer in the above formula through a twin-screw extruder, extruding and granulating, and fully drying to obtain pretreated particles;
[0094] Mix the pretreated particles with the foaming agent and the foaming penetration enhancer, fully stir, place in a closed container, a...
Embodiment 2
[0097] The ratio is made according to the following mass percentage composition: thermoplastic polyurethane elastomer (Taiwan Baoxuan A853), pellets, 92.5%; manganese dioxide 0.01%; foaming agent selected water, acetone, propylene glycol (all commercially available analytically pure) The mass ratio between the three is 4:1:0.25, and the foaming agent mixture is 5%; the foaming penetration enhancer is a mixture of butyl acetate and ethyl acetate (the mixing ratio is 3:1 by mass), Foam penetration enhancer mixture 0.5%; Talc (commercially available), 0.8%, glycerol monoglyceride 0.49%; Calcium stearate 0.2%, Zinc stearate 0.2%; Antioxidant 168 0.3%.
[0098] Kneading and granulating the components other than the foaming agent and foaming penetration enhancer in the above formula through an internal mixer, and fully air-dry to obtain pretreated particles;
[0099] Mix the pretreated particles with the foaming agent and the foaming penetration enhancer, fully stir, place in a closed co...
Embodiment 3
[0102] The ratio is made according to the following mass percentage composition: thermoplastic polyurethane elastomer (KT-890 of Bayer, Germany), pellets, 96%; manganese dioxide 2%; foaming agent selected water, acetone, propylene glycol (all commercially available analysis Pure) mixture, the mass ratio between the three is 4:1:0.25, and the foaming agent mixture is 1%; the foaming penetration enhancer is a mixture of butyl acetate and ethyl acetate (mixing ratio is 1:1), Foaming penetration enhancer mixture 0.3%; Talc (commercially available) 0.1%; Glycerin monoglyceride 0.1%; Zinc stearate 0.2%; Antioxidant 168 0.3%.
[0103] Except for the foaming agent and the foaming penetration enhancer, the components in the above formula are smelted and granulated by a two-roller, and fully dried to obtain pretreated particles;
[0104] Mix the pretreated particles with the foaming agent and the foaming penetration enhancer, fully stir, place in a closed container, and stand for 24 hours to...
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