Processless thermal sensitive plate used for direct printing on printer
A treatment-free, heat-sensitive technology, which is applied in the direction of photosensitive materials used in optomechanical equipment, and can solve the problems of poor developing ability and printing durability of plates
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Embodiment 1
[0074] Example 1 (copolymer P01)
[0075] Add 333.3g of methyl ethyl ketone and 10g (10% by weight) of example compound D2 (n about 60) into a 1000ml four-necked flask equipped with temperature-controlled heating, mechanical stirring, reflux and nitrogen protection device, heat and stir evenly, and add dropwise at 90°C 70g (70% by weight) St (styrene), 10g (10% by weight) AN (acrylonitrile), 10g (10% by weight) example compound C2, 0.7g benzoyl peroxide BPO, adding time 20 minutes, and then After 7.5 hours of reaction, add 0.3g of benzoyl peroxide BPO, and continue to react for another 12 hours before ending. See attached table 1 for performance.
Embodiment 2
[0076] Embodiment 2 (copolymer P02)
[0077] Add 344.8g of methyl ethyl ketone and 10g (10% by weight) of the exemplary compound D4 (n about 50) into a 1000ml four-necked flask with temperature-controlled heating, mechanical stirring, reflux and nitrogen protection device, heat and stir evenly, and add dropwise at 80°C 60g (60% by weight) St (styrene), 20g (20% by weight) AN (acrylonitrile), 10g (10% by weight) of example compound C3, 0.7g of AIBN (azobisisobutyronitrile), and the addition time was 20 minutes After another 7.5 hours of reaction, 0.3g of AIBN (azobisisobutyronitrile) was added, and the reaction was continued for another 12 hours.
Embodiment 3
[0078] Embodiment 3 (copolymer P03)
[0079] Add 384.6g of methyl ethyl ketone and 10g (10% by weight) of example compound D4 (n about 40) into a 1000ml four-necked flask equipped with temperature-controlled heating, mechanical stirring, reflux and nitrogen protection device, heat and stir evenly, and add dropwise at 80°C 50g (50% by weight) St (styrene), 30g (30% by weight) AN (acrylonitrile), 10g (10% by weight) of example compound C2, 0.7g of AIBN (azobisisobutyronitrile), adding time 20 minutes After another 7.5 hours of reaction, 0.3g of AIBN (azobisisobutyronitrile) was added, and the reaction was continued for another 12 hours.
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